Reduction by bimetallic reactive materials containing zero-valent iron

Zero-Valent Iron Reactive Materials for Hazardous Waste and Inorganics Removal

Volumn , Issue , 2007, Pages 206-223

  Song, Hocheol ^a   Kim, Young Hun ^b   Carraway, Elizabeth R ^a  

^a CLEMSON UNIVERSITY   (United States)

^b Andong National University   (South Korea)

Author keywords

Chemical reactions; Copper; Halogen organic compounds; Hydrogen; Iron; Metals

Indexed keywords

CHEMICAL REACTIONS; COPPER; COPPER COMPOUNDS; HALOGEN COMPOUNDS; HYDROGEN; IMPURITIES; METALS;

HALOGEN ORGANIC COMPOUNDS; RATE ENHANCEMENT; REACTION PATHWAYS; REACTIVE MATERIALS; REACTIVE METALS; ZERO-VALENT IRON;

IRON;

EID: 82555169438     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1061/9780784408810.ch12     Document Type: Chapter

References (76)

1. Bockris, J.O.M., Bonciocat, N., and Gutmann, F. (1974). An introduction to electrochemical science, Springer-Verlag, New York.
2. Carraway, E., and Song, H. (2004). “Reduction of chlorinated ethenes by nano-sized zero-valent iron.” In Extended Abstract of National Meeting, Div. Environ. Chem, ACS, Philadelphia, PA, 44(2), 397-401.
3. Cheng, I. F., Fernando, Q., and Korte, N. (1997). “Electrochemical dechlorination of 4-chlorophenol to phenol.” Environ. Sci. & Technol., 31(4), 1074-1078.
4. Cheng, S. F., and Wu, S. C. F. (2000). “The enhancement methods for the degradation of TCE by zero-valent metals.” Chemosphere, 41(8), 1263-1270.
5. Coq, B., Hub, S., Figueras, F., and Toumigant, D. (1993). “Conversion under hydrogen of dichlorodifluoromethane over bimetallic palladium catalysts.” App. Catal. A., 101(1), 41-50.
6. Davenport, A. J., and Sansone, M. (1995). “High-resolution in-situ XANES investigation of the nature of the passive film on iron in a pH 8.4 borate buffer.” J. Electrochem. Soc., 142(3), 725-730.
7. Doyle, J. G., Mile, T.-A., Parker, E., and Cheng, I. F. (1998). “Quantification of total polychlorinated biphenyl by dechlorination to biphenyl by Pd/Fe and Pd/Mg bimetallic particles.” Microchem. J., 60, 290-295.
8. Elliott, D. W., and Zhang, W. X. (2001). "Field assessment of nanoscale bimetallic particles for groundwater treatment." Environ. Sci. & Technol., 35(24), 4922-4926.
9. Filipek, L. B., Coon, C. C., Geiger, C. L., Clausen, C. A., Quinn, J., and DeVor, R. (2003). “Dechlorination of polychlorinated biphenyls in solution by Pd/Fe bimetallic emulsions.” In Extended Abstract of National Meeting, Div. Environ. Chem, ACS, New Orleans, LA.
10. Fogelberg, J., and Petersson, L. G. (1996). “Kinetic modelling of the H2O2 reaction on Pd and of its influence on the hydrogen response of a hydrogen sensitive Pd metal-oxide-semiconductor device.” Surf. Sci., 350(1-3), 91-102.
11. Fung, S. C., and Sinfelt, J. H. (1987). “Hydrogenolysis of methyl chloride on metals.” J. Catal., 103(1), 220-223.
12. Grenier, A. C., McGuire, M. M., Fairbrother, D. H., and Roberts, A. L. (2004). “Treatment of vapor-phase organohalides with zero-valent iron and Ni/Fe reductants.” Environ. Eng. Sci., 21(4), 421-435.
13. Grittini, C., Malcomson, M., Fernando, Q., and Korte, N. (1995). "Rapid dechlorination of polychlorinated-biphenyls on the surface of a Pd/Fe bimetallic system." Environ. Sci. & Technol., 29(11), 2898-2900.
14. Guasp, E., and Wei, R. (2003). “Dehalogenation of trihalomethanes in drinking water on Pd-Fe bimetallic surface.” J. Chem. Tech. Biotech., 78(6), 654-658.
15. Gui, L., and Gillham, R. W. (2003). “Preparation and regeneration of nickel-iron for reduction of organic contaminants.” In Chlorinated Solvent and DNAPL Remediation. ACS Symposium Series, 837, 206-216.
16. Gui, L., Gillham, R. W., and Odziemkowski, M. S. (2000). "Reduction of N-nitrosodimethylamine with granular iron and nickel enhanced iron. 1. Pathways and kinetics." Environ. Sci. & Technol., 34(16), 3489-3494.
17. Hughes, R. (1984). Deactivation of catalysts, Academic Press, London.
18. Kim, Y. H. (1999). Dechlorination of chlorinated aliphatic and aromatic compounds using zero valent metals: Modified metals and electron mediators. Ph.D. dissertation, Texas A&M University, College Station, TX.
19. Kim, Y. H., and Carraway, E. R. (2000). “Dechlorination of pentachlorophenol by zero valent iron and modified zero valent irons.” Environ. Sci. & Technol., 34(10), 2014-2017.
20. Kim, Y. H., and Carraway, E. R. (2003a). “Dechlorination of chlorinated ethenes and acetylenes by palladized iron.” Environ. Technol., 24(7), 809-819.
21. Kim, Y. H., and Carraway, E. R. (2003b). "Reductive dechlorination of TCE by zero valent bimetals." Environ. Technol., 24(1), 69-75.
22. Kim, Y. H., Shin, W. S., and Ko, S. O. (2004). “Reductive dechlorination of chlorinated biphenyls by palladized zero-valent metals.” J. Environ. Sci. Heal. A, 39(5), 1177-1188.
23. Klausen, J., Vikesland, P. J., Kohn, T., Burris, D. R., Ball, W. P., and Roberts, A. L. (2003). “Longevity of granular iron in groundwater treatment processes: Solution composition effects on reduction of organohalides and nitroaromatic compounds.” Environ. Sci. & Technol., 37(6), 1208-1218.
24. Kopinke, F-D., Mackenzie, K., Koehler, R., and Georgi, A. (2004). “Alternative sources of hydrogen for hydrodechlorination of chlorinated organic compounds in water on Pd catalysts.” Appl. Catal. A-Gen., 271,119-128.
25. Korte, N. E., West, O. R., Liang, L., Gu, B., Zutman, J. L., and Fernando, Q. (2002). “The effect of solvent concentration on the use of palladized-iron for the stepwise dechlorination of polychlorinated biphenyls in soil extracts.” Waste Manage., 22(3), 343-349.
26. Korte, N. E., Zutman, J. L., Schlosser, R. M., Liang, L., Gu, B., and Fernando, Q. (2000). “Field application of palladized iron for the dechlorination of trichloroethene.” Waste Manage., 20(8), 687-694.
27. Kramer, H., Levy, M., and Warshawsky, A. (1995). “Hydrogen storage by the bicarbonate formate reaction - Studies on the activity of Pd catalysts.” Int. J. Hydrogen Energ., 20(3), 229-233.
28. Kulkami, P. P., Deshmukh, S. S., Kovalchuk, V. I., and D'ltri, J. L. (1999). “Hydrodechlorination of dichlorodifluoromethane on carbon-supported Group VIII noble metal catalysts.” Catal. Lett., 61(3-4), 161-166.
29. Lawson, D. R., Tierney, M. J., Cheng, I. F., Vandyke, L. S., Espenscheid, M. W., and Martin, C. R. (1991). “Use of a coulometric assay technique to study the variables affecting deuterium loading levels within palladium electrodes.” Electroch. Acta., 36(9), 1515-1522.
30. Li, T., and Farrell, J. (2000). “Reductive dechlorination of trichloroethene and carbon tetrachloride using iron and palladized-iron cathodes.” Environ. Sci. & Technol. 34(1), 173-179.
31. Liang, L. Y., Korte, N., Goodlaxson, J. D., Clausen, J., Fernando, Q., and Muftikian, R. (1997). “Byproduct formation during the reduction of TCE by zero-valence iron and palladized iron.” Ground Water Monit. R., 17(1), 122-127.
32. Lien, H. L., and Zhang, W. X. (1999). “Transformation of chlorinated methanes by nanoscale iron particles.” J. Environ. Eng. ASCE, 125(11), 1042-1047.
33. Lien, H. L., and Zhang, W. X. (2001). “Nanoscale iron particles for complete reduction of chlorinated ethenes.” Colloid. Surface. A., 191(1-2), 97-105.
34. Lien, H. L., and Zhang, W. X. (2005). “Hydrodechlorination of chlorinated ethanes by nanoscale Pd/Fe bimetallic particles.” J. Environ. Eng. ASCE, 131(1), 4-10.
35. Lin, C. J., Lo, S. L., and Liou, Y. H. (2004). “Dechlorination of trichloroethylene in aqueous solution by noble metal-modified iron.” J. Hazard. Mater., 116(3), 219-228.
36. Liu, Y. H., Yang, F. L., Chen, J. W., Gao, L. N., and Chen, G. H. (2003). “Linear free energy relationships for dechlorination of aromatic chlorides by Pd/Fe.” Chemosphere, 50(10), 1275-1279.
37. Liu, Y. H., Yang, F. L., Yue, P. L., and Chen, G. H. (2001). “Catalytic dechlorination of chlorophenols in water by palladium/iron.” Water Res., 35(8), 1887-1890.
38. Liu, Y. Q., Majetich, S. A., Tilton, R. D., Sholl, D. S., and Lowry, G. V. (2005). “TCE dechlorination rates, pathways, and efficiency of nanoscale iron particles with different properties.” Environ. Sci. & Technol., 39(5), 1338-1345.
39. Lowry, G. V., and Reinhard, M. (2000). “Pd-catalyzed TCE dechlorination in groundwater: Solute effects, biological control, and oxidative catalyst regeneration.” Environ. Sci. & Technol., 34(15), 3217-3223.
40. Lowry, G. V., and Reinhard, M. (2001). “Pd-catalyzed TCE dechlorination in water: Effect of H2 (aq) and FL-utilizing competitive solutes on the TCE dechlorination rate and product distribution.” Environ. Sci. & Technol., 35(4), 696-702.
41. Ma, L. M, Ding, Z. G, Gao, T. Y, Zhou, R. F, Xu, W. Y., and Liu, J. (2004). “Discoloration of methylene blue and wastewater from a plant by a Fe/Cu bimetallic system.” Chemosphere, 55(9), 1207-1212.
42. March, J. (1985). Advanced organic chemistry, McGraw-Hill, New York.
43. Matheson, L. J., and Tratnyek, P. G. (1994). “Reductive dehalogenation of chlorinated methanes by iron metal.” Environ. Sci. & Technol., 28(12), 2045-2053.
44. McNab, W. W., and Ruiz, R. (1998). “Palladium-catalyzed reductive dehalogenation of dissolved chlorinated aliphatics using electrolytically-generated hydrogen.” Chemosphere, 37(5), 925-936.
45. McNab, W. W., Ruiz, R., and Pray, L. (2000). “In-situ destruction of chlorinated hydrocarbons in groundwater using catalytic reductive dehalogenation in a reactive well: Testing and operational experiences.” Environ. Sci. & Technol., 34(1), 149-153.
46. Miyabe, K., Taniguchi, N., Imura, A., and Tezuka, T. (2003). “Kinetic study of the hydrodechlorination of trichloroethene in water using a platinum catalyst and hydrazine.” Water Environ. Res., 75(5), 472-477.
47. Morales, J., Hutcheson, R., and Cheng, I. F. (2002). “Dechlorination of chlorinated phenols by catalyzed and uncatalyzed Fe(0) and Mg(0) particles.” J. Hazard. Mater., 90(1), 97-108.
48. Muftikian, R., Fernando, Q., and Korte, N. (1995). “A Method for the rapid dechlorination of low-molecular-weight chlorinated hydrocarbons in water.” Wat. Res., 29(10), 2434-2439.
49. Muftikian, R., Nebesny, K., Fernando, Q., and Korte, N. (1996). “X-ray photoelectron spectra of the palladium-iron bimetallic surface used for the rapid dechlorination of chlorinated organic environmental contaminants.” Environ. Sci. & Technol., 30(12), 3593-3596.
50. Mukhopadhyay, S., Rothenberg, G., Wiener, H., and Sasson, Y. (1999). “Palladium-catalyzed aryl-aryl coupling in water using molecular hydrogen: Kinetics and process optimization of a solid-liquid-gas system.” Tetrahedron, 55, 14763-14768.
51. Mukhopadhyay, S., Rothenberg, G., Gitis, D., and Sasson, Y. (2000). “On the mechanism of palladium-catalyzed coupling of haloaryls to biaryls in water with zinc.” Org. Lett., 2(2), 211-214.
52. Navarro, R. M., Pawelec, B., Trejo, J. M., Mariscal, R., and Fierro J. L (2000). “Hydrogenation of aromatics on sulfur-resistant PtPd bimetallic catalysts.” J. Catal., 189, 184-194.
53. Neurath, S. A., Ferguson, W. J., Dean, S. B., Foose, D., and Agrawal, A. (1997). “Rapid and complete dehalogenation of chlorinated phenols by Fe-Pd bimetallic reductants in bench-scale reactors: Implications for soil and ground water remediation.” In Extended Abstract of National Meeting, Div. Environ. Chem, ACS, San Fransico, CA.
54. Odziemkowski, M. S., Gui, L, and Gillham, R. W. (2000). “Reduction of N-nitrosodimethylamine with granular iron and nickel-enhanced iron. 2. Mechanistic studies.” Environ. Sci. & Technol., 34(16), 3495-3500.
55. O’Hannesin, S. F., and Gillham, R. W. (1998). “Long-term performance of an in situ 'iron wall' for remediation ofVOCs.” Ground Water, 36(1), 164-170.
56. Orth, W. S., and Gillham, R. W. (1996). “Dechlorination of trichloroethene in aqueous solution using Fe.” Environ. Sci. & Technol., 30(1), 66-71.
57. Pemg, T. P., and Wu, J. K. (2003). “A brief review note on mechanisms of hydrogen entry into metals.” Mater. Lett., 57(22-23), 3437-3438.
58. Perrone, L., Prati, L., and Rossi, M. (1998). “Removal of chlorinated organic compounds from water by catalytic dehydrohalogenation.” Appl. Catal. B-Environ., 15(3-4), 241-246.
59. Prati, L., and Rossi, M. (1999). “Reductive catalytic dehalogenation of light chlorocarbons.” Appl. Catal. B-Environ., 23(2-3), 135-142.
60. Puls, R. W., Blowes, D. W., and Gillham, R. W. (1999). “Long-term performance monitoring for a permeable reactive barrier at the US Coast Guard Support Center, Elizabeth City, North Carolina.” J. Hazard. Mater., 68(1-2), 109-124.
61. Rajagopal, S., and Spatola, A. F. (1995). “Mechanism of palladium-catalyzed transfer hydrogenolysis of aryl chlorides by formate salts.” J Org. Chem., 60, 1347-1355.
62. Rylander, P. N. (1979). Catalytic hydrogenation in organic synthesis, Academic Press, New York.
63. Scherer, M. M., Balko, A. D., and Tratnyek, P. G. (1998). “The role of oxides in the reduction reaction at the metal-water interface.” In Mineral-Water Interfacial Reactions: Kinetics and Mechanisms. American Chemical Society, Washington, DC, 301-322.
64. Schreier, C. G., and Reinhard, M. (1995). “Catalytic hydrodehalogenation of chlorinated ethylenes using palladium and hydrogen for the treatment of contaminated water.” Chemosphere, 31(6), 3475-3487.
65. Schrick, B., Blough, J. L., Jones, A. D., and Mallouk, T. E. (2002). “Hydrodechlorination of trichloroethylene to hydrocarbons using bimetallic nickel-iron nanoparticles.” Chem. Mater., 14(12), 5140-5147.
66. Swaddle, T. W. (1997). Inorganic Chemistry: An industrial and environmental perspective, Academic Press, San Diego, California.
67. Vikesland, P. J., Klausen, J., Zimmermann, H., Roberts, A. L., Ball, W. P. (2003). “Longevity of granular iron in groundwater treatment processes: Changes in solute transport properties over time.” J. Contam. Hydro!, 64(1-2), 3-33.
68. Vogan, J. L., Focht, R. M., Clark, D. K., and Graham, S. L. (1999). “Performance evaluation of a permeable reactive barrier for remediation of dissolved chlorinated solvents in groundwater.” J. Hazard. Mater., 68(1-2), 97-108.
69. Wan, C. H., Chen, Y. H., and Wei, R. (1999). “Dechlorination of chloromethanes on iron and palladium-iron bimetallic surface in aqueous systems.” Environ. Toxicol. Chem., 18(6), 1091-1096.
70. Wang, J. K., Blowers, P., and Farrell, J. (2004). “Understanding reduction of carbon tetrachloride at nickel surfaces.” Environ. Sci. & Technol., 38(5), 1576-1581.
71. Wang, C. B., and Zhang, W. X. (1997) “Synthesizing nanoscale iron particles for rapid and complete dechlorination of TCE and PCBs.” Environ. Sci. & Technol., 31(7), 2154-2156.
72. Wu, J. K. (1992). “Electrochemical method for studying hydrogen in iron, nickel and palladium.” Int. J. Hydrogen Energ., 17(12), 917-921.
73. Xu, X. H., Zhou, H. Y., He, P., and Wang, D. H. (2005a). “Catalytic dechlorination kinetics of p-dichlorobenzene over Pd/Fe catalysts.” Chemosphere, 58(8), 1135-1140.
74. Xu, X. H., Zhou, H. Y., and Wang, D. H. (2005b). “Structure relationship for catalytic dechlorination rate of dichlorobenzenes in water.” Chemosphere, 58(11), 1497-1502.
75. Xu, Y., and Zhang, W. X. (2000). “Subcolloidal Fe/Ag particles for reductive dehalogenation of chlorinated benzenes.” Ind. Eng. Chem. Res., 39(7), 2238-2244.
76. Zhang, W. X., Wang, C. B., and Lien, H. L. (1998). “Treatment of chlorinated organic contaminants with nanoscale bimetallic particles.” Catal. Today, 40(4), 387-395.