Dechlorination of chlorinated ethenes and acetylenes by palladized iron

Environmental Technology (United Kingdom)

Volumn 24, Issue 7, 2003, Pages 809-819

  Kim, Y H ^a,b   Carraway, E R ^a  

^a CLEMSON UNIVERSITY   (United States)

^b Kyungpook National University   (South Korea)

Author keywords

Dechlorination; Palladium; Pce; Reduction; Tce; Zero valent metals

Indexed keywords

ACETYLENE; CHLORINE; CHLORINE COMPOUNDS; DECHLORINATION; ENERGY DISPERSIVE SPECTROSCOPY; ETHYLENE; IRON; LIGHTING; PALLADIUM; REACTION RATES; REDUCTION;

CARBON MASS BALANCE; CHLORINATED ETHENES; DECHLORINATION PRODUCTS; DECHLORINATION RATE; ENERGY DISPERSIVE X RAY SPECTROSCOPY; PALLADIUM CONTENTS; SEQUENTIAL REACTION; ZERO-VALENT METALS;

IRON METALLOGRAPHY;

ACETYLENE; ACETYLENE DERIVATIVE; CARBON; CHLORINE; ETHANE; ETHYLENE; ETHYLENE DERIVATIVE; IRON DERIVATIVE; METAL; PALLADIUM; TETRACHLOROETHYLENE; TRICHLOROETHYLENE; VINYL CHLORIDE; VINYLIDENE CHLORIDE;

CHLORINATED HYDROCARBON; DEGRADATION;

ABSORPTION; ARTICLE; CHEMICAL REACTION; CHLORINATION; COATED PARTICLE; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; DECHLORINATION; DEGRADATION; X RAY SPECTROMETRY;

EID: 0041743100     PISSN: 09593330     EISSN: 1479487X     Source Type: Journal    
DOI: 10.1080/09593330309385618     Document Type: Article

References (33)

1. Grittini G, Malcomson M., Fernando Q. and Korte N., Rapid dechlorination of polychlorinated biphenyls on the surface of a Pd/Fe bimetallic system. Environ. Sci. Technol., 29,2898-2900 (1995)
2. Muftikian R., Fernando Q. and Korte N., A method for the rapid dechlorination of low molecular weight chlorinated hydrocarbons in water. Water Res., 29,2434-2439 (1995)
3. Fennelly J.P. and Roberts A.L., Reaction of 1,1,1-trichloroethane with zero-valent metals and bimetallic reductants. Environ. Sci. Technol., 32,1980-1988 (1998)
4. Roberts A.L., Totten L.A., Arnold W.A. and Campbell T.J., Reductive elimination of chlorinated ethylenes by zero-valent metals. Environ. Sci. Technol., 30,2654-2659 (1996)
5. Matheson L.J. and Tratnyek P.G., Reductive dehalogenation of chlorinated methanes by iron metal. Environ. Sci. Technol., 28,2045-2053(1994)
6. Li W. and Klabunde K.J., Ultrafine zinc and nickel, palladium, silver coated zinc particles used for reductive dehalogenation of chlorinated ethylenes in aqueous solution. Croat. Chem. Acta., 71,863-872 (1998)
7. Tratnyek P.G., Johnson T.L., Scherer M.M. and Eykholt G.R., Remediating ground water with zero-valent metals: chemical considerations in barrier design. Ground Water Monitoring Remediation, FALL, 108-114 (1997)
8. Li T. and Farrell J., Reductive dechlorination of trichloroethene and carbon tetrachloride using iron and palladized-iron cathodes. Environ. Sci. Technol., 34,173-179 (2000)
9. Kim Y.-H., Reductive dechlorination of chlorinated aliphatic and aromatic compounds using zero valent metals: modified metals and electron mediators. Ph. D. Dissertation. Civil Engineering, Texas A & M University, College Station, Texas, USA. pp. 17-71 (1999)
10. Sivavec T.M., Mackenzie P.D. and Homey D.P. Effect of site groundwater on reactivity of bimetallic media: deactivation of nickel-plated granular iron. In: 213th Natl Meet., Am. Chem. Soc., Div. Environ. Chem. San Francisco, CA. pp. 83-85 (1997)
11. OKazaki S., Sasaki H. and Asakura S., Reduction of nitrate ions by iron powder coated with copper in neutral solutions. Denki Kagaku, 66,620-624 (1998)
12. March J., Advanced Organic Chemistry. 3rd ed. McGraw-Hill, New York, USA. pp. 432-445 (1985)
13. Hudlicky M., Reductions in Organic Chemistry. 2nd ed. American Chemical Society, Washington, DC., USA. pp. 151-152 (1996)
14. Schreier C.G. and Reinhard M., Catalytic hydrodehalogenation of chlorinated ethylenes using palladium and hydrogen for the treatment of contaminated water. Chemosphere, 31,3475-3487 (1995)
15. Lowry G.V. and Reinhard M., Hydrodehalogenation of 1-to 3-carbon halogenated organic compounds in water using a palladium catalyst and hydrogen gas. Environ. Sci. Technol, 33,1905-1910 (1999)
16. Rajagopal S. and Spatola A.F., Mechanism of palladium-catalyzed transfer hydrogenolysis of aryl chlorides by formate salts. J. Org. Chem., 60,1347-1355 (1995)
17. Ukisu Y. and Miyadera T., Hydrogen-transfer hydrohalogenation of aromatic halides with alcohols in the presence of noble metal catalysts. J. Molec. Catal. A: Chem., 125,135-142 (1997)
18. Arnold W.A. and Roberts A.L., Pathways of chlorinated ethylene and chlorinated acetylene reaction with Zn(0). Environ. Sci. Technol., 32,3017-3025 (1998)
19. Wan C., Chen Y.H. and Wei R., Dechlorination of chloromethanes on iron and palladium-iron bimetallic surface in aqueous systems. Environ. Toxicol. Chem., 18,1091-1096 (1999)
20. Denis J., Moyano A. and Greene A.E., Practical synthesis of dichloroacetylene. J. Org. Chem., 52,3461-3462 (1987)
21. Clark W.M., Oxidation-Reduction Potentials of Organic Systems. The Williams & Wilkins Company, Baltimore, MA., USA. pp. 112-113 (1960)
22. th ed. American Public Health Association, Washington, D.C., pp. 1-10 (1995)
23. Mackay D. and Shiu W.Y., A critical review of Henry's constants for chemicals of environmental interest. J. Phys. Chem. Ref. Data, 10,1175-1199 (1981)
24. Lee R.E., Scanning Electron Microscopy and X-ray Microanalysis. PTR Prentice Hall, Englewood Cliffs, New Jersey, USA. 221-223 (1993)
25. Johnson T.L., Scherer M.M. and Tratnyek P.G., Kinetics of halogenated organic compound degradation by iron metal. Environ. Sei. Technol., 30,2634-2640 (1996)
26. Orth W.S. and Gillham R.W., Dechlorination of trichloroethene in aqueous solution using FeO. Environ. Sei. Technol., 30,66-71 (1996)
27. Deng B., Burris D.R. and Campbell T.J., Reduction of vinyl chloride in metallic iron-water systems. Environ. Sei. Technol., 33,2651-2656 (1999)
28. Lapierre R.B., Wu D., Kranich W.L. and Weiss A.H., Hydrodechlorination of l, l-Bis(p-chlorophenyl)-2,2-dichloroethylene (p, p’-DDE) in the vapor phase. J. Catal., 52,59-71 (1978)
29. Schwarzenbach R.P., Gschwend P.M. and Imboden D.M., Environmental Organic Chemistry. 1st ed. John Wiley & Sons, Inc., New York, USA. 423-427 (1993)
30. Mukhopadhyay S., Rothenberg G., Gitis D. and Sasson Y., On the mechanism of palladium-catalyzed coupling of haloaryls to biaryls in water with zinc Org. Lett., 2,211-214 (2000)
31. Cheng I.F., Fernando Q. and Körte N., Electronchemical dechlorination of 4-chlorophenol to phenol. Environ. Sei. Technol., 31,1074-1078 (1997)
32. Neurath S.A., Ferguson W.J., Dean S.B., Foose D. and Agrawal A. Rapid and complete dehalogenation of chlorinated phenols by Fe-Pd bimetallic reductants in bench-scale reactors: implications for soil and ground water remediation. In: 213th Natl Meet., Am. Chem. Soc., Div. Environ. Chem. San Francisco, CA, 159-161 (1997)
33. Valden M., Lai X. and Goodman D.W., Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties. Science., 281,1647-1650 (1998)