Cooperative thiourea-Brønsted acid organocatalysis: Enantioselective cyanosilylation of aldehydes with TMSCN

Journal of Organic Chemistry

Volumn 76, Issue 23, 2011, Pages 9764-9776

  Zhang, Zhiguo ^a   Lippert, Katharina M ^a   Hausmann, Heike ^a   Kotke, Mike ^a   Schreiner, Peter R ^a  

^a JUSTUS LIEBIG UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACHIRAL ACIDS; ASYMMETRIC INDUCTION; BIFUNCTIONAL; CATALYTIC SPECIES; COOPERATIVE CATALYTIC SYSTEMS; COOPERATIVE INTERACTIONS; CYANOSILYLATION; DENSITY FUNCTIONALS; ENANTIOSELECTIVE; HYDROGEN BONDINGS; ORGANOCATALYSIS; SOLVENT CORRECTION;

ALDEHYDES; ENANTIOSELECTIVITY; HYDROGEN; ORGANIC COMPOUNDS; REACTION KINETICS; THIOUREAS;

DENSITY FUNCTIONAL THEORY;

ALDEHYDE DERIVATIVE; BRONSTED ACID; NITRILE; THIOUREA; TRIMETHYLSILYL DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHIRALITY; DENSITY FUNCTIONAL THEORY; ELECTROSPRAY MASS SPECTROMETRY; ENANTIOSELECTIVITY; HYDROGEN BOND; MOLECULAR INTERACTION; NITROGEN NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM YIELD; REACTION ANALYSIS; SILYLATION; THEORETICAL STUDY;

ACIDS; ALDEHYDES; CATALYSIS; CYANIDES; MOLECULAR STRUCTURE; NITRILES; STEREOISOMERISM; THIOUREA; TRIMETHYLSILYL COMPOUNDS;

EID: 82255170729     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo201864e     Document Type: Article

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