Analysis of hydrogen in olivine by SIMS: Evaluation of standards and protocol

American Mineralogist

Volumn 96, Issue 11-12, 2011, Pages 1725-1741

  Mosenfelder, Jed L ^a   Voyer, Marion Le ^a   Rossman, George R ^a   Guan, Yunbin ^a   Bel, David R ^a,b,c   Asimow, Paul D ^a   Eiler, John M ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b ARIZONA STATE UNIVERSITY   (United States)

^c ARIZONA STATE UNIVERSITY   (United States)

Author keywords

Calibration; Infrared; Mantle; Olivine; Secondary ion mass spectrometry; Spectroscopy; Water

Indexed keywords

CALIBRATION; ERROR STATISTICS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROGEN; INFRARED RADIATION; MICROMETERS; NUCLEAR REACTIONS; OLIVINE; SECONDARY EMISSION; SECONDARY ION MASS SPECTROMETRY; SERPENTINE; SILICON COMPOUNDS; SPECTROSCOPY; WATER;

CALIBRATION LINES; CORRELATION COEFFICIENT; COUNTING STATISTICS; HYDROGEN CONCENTRATION; IR ABSORPTION COEFFICIENT; MANTLE; NUCLEAR REACTION ANALYSIS; SEQUENTIAL ANALYSIS;

UNCERTAINTY ANALYSIS;

CALIBRATION; CONCENTRATION (COMPOSITION); ERROR ANALYSIS; FLUID INCLUSION; FTIR SPECTROSCOPY; HYDROGEN; IONIZATION; KIMBERLITE; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; OLIVINE;

EID: 81855183735     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2011.3810     Document Type: Article

References (64)

1. Aines, R.D. and Rossman, G.R. (1984) Water in minerals? A peak in the infrared. Journal of Geophysical Research, 89, 4059-4071.
2. Andersen, T. and Neumann, E.-R. (2001) Fluid inclusions in mantle xenoliths. Lithos, 55, 301-320. (Pubitemid 32169425)
3. Aubaud, C., Withers, A.C., Hirschmann, M., Guan, Y., Leshin, L.A., Mackwell, S., and Bell, D.R. (2007) Intercalibration of FTIR and SIMS for hydrogen measurements in glasses and nominally anhydrous minerals. American Mineralogist, 92, 811-828. (Pubitemid 46851766)
4. Bai, Q. and Kohlstedt, D.L. (1993) Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine. Physics and Chemistry of Minerals, 19, 460-471. (Pubitemid 23389895)
5. Balan, E., Ingrin, J., Delattre, S., Kovács, I., and Blanchard, M. (2011) Theoretical infrared spectrum of OH-defects in forsterite. European Journal of Mineralogy, 23, 285-292, DOI: 10.1127/0935-1221/2011/0000-2090.
6. Bell, D.R. and Rossman, G.R. (1992) Water in the Earth's mantle: The role of nominally anhydrous minerals. Science, 255, 1391-1397.
7. Bell, D.R., Ihinger, P.D., and Rossman, G.R. (1995) Quantitative analysis of trace OH in garnet and pyroxene. American Mineralogist, 80, 465-474.
8. Bell, D.R., Rossman, G.R., Maldener, J., Endisch, D., and Rauch, F. (2003) Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum. Journal of Geophysical Research, 108, 2105, DOI: 10.1029/2001JB000679.
9. Bell, D.R., Rossman, G.R., and Moore, R.O. (2004) Abundance and partitioning of OH in a high-pressure magmatic system: Megacrysts from the Monastery Kimberlite, South Africa. Journal of Petrology, 45, 1539-1564. (Pubitemid 39051970)
10. Beran, A. and Putnis, A. (1983) A model of the OH positions in olivine, derived from infrared-spectroscopic investigations. Physics and Chemistry of Minerals, 9, 57-60.
11. Berry, A., Hermann, J., O'Neill, H.St.C., and Foran, G.J. (2005) Fingerprinting the water site in mantle olivine. Geology, 33, 869-872. (Pubitemid 41623129)
12. Berry, A., O'Neill, H.St.C., Hermann, J., and Scott, D.R. (2007) The infrared signature of water associated with trivalent cations in olivine. Earth and Planetary Science Letters, 261, 134-142. (Pubitemid 47324161)
13. Bromiley, D.W. and Kohn, S.C. (2007) Comparisons between fluoride and hydroxide incorporation in nominally anhydrous and fluorine-free mantle minerals. Geochimica et Cosmochimica Acta, 71, Goldschmidt Conference Abstracts, A124.
14. Clocchiatti, R., Massare, D., and Jehanno, C. (1981) Origine hydrothermale des olivines gemmes de l'île de Zabargad (St. Johns) Mer Rouge, par l'étude de leurs inclusions. Bulletin de Minéralogie, 104, 354-360.
15. Dekas, A.E., Poretzky, R., and Orphan, V. (2009) Deep-sea Archaea fix and share nitrogen in methane consuming microbial consortia. Science, 326, 422-426.
16. Demouchy, S. and Mackwell, S. (2006) Mechanisms of hydrogen incorporation and diffusion in iron-bearing olivine. Physics and Chemistry of Minerals, 33, 347-355. (Pubitemid 44143770)
17. Diamond, L.W., Marshall, D.D., Jackman, J.A., and Skippen, G.B. (1990) Elemental analysis of individual fluid inclusions in minerals by secondary ion mass spectrometry (SIMS): Application to cation ratios of fluid inclusions in an Archaean mesothermal gold-quartz vein. Geochimica et Cosmochimica Acta, 54, 545-552.
18. Fitzsimmons, I.C.W., Harte, B., and Clark, R.M. (2000) SIMS stable isotope measurement: Counting statistics and analytical precision. Mineralogical Magazine, 64, 59-83. (Pubitemid 30205958)
19. Gose, J., Schmädicke, E., Markowitz, M., and Beran, A. (2010) OH point defects in olivine from Pakistan. Mineralogy and Petrology, 99, 105-111.
20. 2O. Earth and Planetary Science Letters, 260, 227-241. (Pubitemid 47040595)
21. Guggino, S.N., Hervig, R.L., and Bell, D.R. (2007) Fluorine in olivines from plutonic, extrusive, and hypabyssal suites. American Geophysical Union, Fall Meeting 2007, abstract V41B-0609.
22. Hauri, E.H., Wang, J., Dixon, J.E., King, P.L., Mandeville, C., and Newman, S. (2002) SIMS analysis of volatiles in silicate glasses 1. Calibration, matrix effects and comparisons with FTIR. Chemical Geology, 183, 99-114. (Pubitemid 34268163)
23. Hervig, R.L. and Bell, D.R. (2005) Fluorine and hydrogen in mantle megacrysts. American Geophysical Union, Fall Meeting 2005, abstract V41A-1426.
24. Hinthorne, J.R. and Andersen, C.A. (1975) Microanalysis for fluorine and hydrogen in silicates with the ion microprobe mass analyzer. American Mineralogist, 60, 143-147.
25. Hirschmann, M.M., Tenner, T., Aubaud, C., and Withers, A.C. (2009) Dehydration melting of nominally anhydrous mantle: The primacy of partitioning. Physics of the Earth and Planetary Interiors, 176, 54-68.
26. Ihinger, P.D., Hervig, R.L., and McMillan, P.F. (1994) Analytical methods for volatiles in glasses. In M.R. Carroll and J.R. Holloway, Eds., Volatiles in Magmas, 30, p. 67-121. Reviews in Mineralogy, Mineralogical Society of America. Chantilly, Virginia.
27. 2O system. American Mineralogist, 89, 1433-1437. (Pubitemid 39447844)
28. Kent, A.J.R. and Rossman, G.R. (2002) Hydrogen, lithium, and boron in mantle-derived olivine: The role of couple substitutions. American Mineralogist, 87, 1432-1436. (Pubitemid 35372175)
29. Khisina, N.R., Wirth, R., Andrut, M., and Ukhanov, A.V. (2001) Extrinsic and intrinsic mode of hydrogen occurrence in natural olivines: FTIR and TEM investigation. Physics and Chemistry of Minerals, 28, 291-301. (Pubitemid 32682915)
30. Koch-Müller, M., Matsyuk, S.S., Rhede, D., Wirth, R., and Khisina, N. (2006) Hydroxyl in mantle olivine xenocrysts from the Udachnaya kimberlite pipe. Physics and Chemistry of Minerals, 33, 276-287.
31. Koga, K., Hauri, E., Hirschmann, M.M., and Bell, D. (2003) Hydrogen concentration analyses using SIMS and FTIR: Comparison and calibration for nominally anhydrous minerals. Geochemistry, Geophysics, and Geosystems, 4, 1019, DOI: 10.1029/2002GC000378.
32. 4, Contributions to Mineralogy and Petrology, 123, 345-357.
33. Kovács, I., Hermann, J., O'Neill, H.St.C., Fitz Gerald, J., Sambridge, M., and Horváth, G. (2008) Quantitative absorbance spectroscopy with unpolarized light: Part II. Experimental evaluation and development of a protocol for quantitative analysis of mineral spectra. American Mineralogist, 93, 765-778.
34. Kovács, I., O'Neill, H.St.C., Hermann, J., and Hauri, E.H. (2010) Site-specific infrared O-H absorption coefficients for water substitution into olivine. American Mineralogist, 95, 292-299.
35. Kudoh, Y., Kuribayashi, T., Kagi, H., and Inoue, T. (2006) Cation vacancy and possible hydrogen positions in hydrous forsterite, Mg1.985Si0.993H0.06O4, synthesized at 13.5 GPa and 1300 °C. Journal of Mineralogical and Petrological Sciences, 101, 265-269. (Pubitemid 44768735)
36. Kurosawa, M., Yurimoto, H., and Sueno, S. (1997) Patterns in the hydrogen and trace element compositions of mantle olivines. Physics and Chemistry of Minerals, 24, 385-395.
37. Lemaire, C., Kohn, S.C., and Brooker, R.A. (2004) The effect of silica activity on the incorporation mechanisms of water in synthetic forsterite: A polarised infrared spectroscopic study. Contributions to Mineralogy and Petrology, 147, 48-57. (Pubitemid 38473960)
38. 2O, Cl, and F concentrations in olivines and their associated melt inclusions. American Geophysical Union, Fall Meeting 2010, abstract V23E-07.
39. Libowitzky, E. and Rossman, G.R. (1997) An IR absorption calibration for water in minerals. American Mineralogist, 82, 1111-1115.
40. Long, G.L. and Winefordner, J.D. (1983) Limit of detection. A closer look at the IUPAC definition. Analytical Chemistry, 55, 712A-724A.
41. Maldener, J., Hösch, A., Langer, K., and Rauch, F. (2003) Hydrogen in some natural garnets studied by nuclear reaction analysis and vibrational spectroscopy. Physics and Chemistry of Minerals, 30, 337-344. (Pubitemid 37024403)
42. Matsyuk, S.S. and Langer, K. (2004) Hydroxyl in olivines from mantle xenoliths in kimberlites from the Siberian platform. Contributions to Mineralogy and Petrology, 147, 413-437. (Pubitemid 38889270)
43. Miller, G.H., Rossman, G.R., and Harlow, G.E. (1987) The natural occurrence of hydroxide in olivine. Physics and Chemistry of Minerals, 14, 461-472.
44. Mosenfelder, J.L., Deligne, N.I., Asimow, P.D., and Rossman, G.R. (2006a) Hydrogen incorporation in olivine from 2-12 GPa. American Mineralogist, 91, 285-294. (Pubitemid 44056450)
45. Mosenfelder, J.L., Sharp, T.G., Asimow, P.D., and Rossman, G.R. (2006b) Hydrogen incorporation in natural mantle olivines. In S.D. Jacobsen and S. van der Lee, Eds., Earth's Deep Water Cycle p. 45-56. American Geophysical Union, Washington, D.C.
46. Mosenfelder, J.L., Le Voyer, M., Rossman, G.R., Guan, Y., Bell, D.R., Asimow, P.D., and Eiler, J. (2010) Combined SIMS, NanoSIMS, FTIR, and SEM studies of OH in nominally anhydrous minerals (NAMs). American Geophysical Union, Fall Meeting 2010, abstract V43F-04.
47. 3+ on the partitioning of water between clinopyroxene and silicate melt. Earth and Planetary Science Letters, 297, 111-120, DOI: 10.1016/j.epsl.2010.06.011.
48. Peslier, A.H., Woodland, A.B., Bell, D.R., and Lazarov, M. (2010) Olivine water contents in the continental lithosphere and the longevity of cratons. Nature, 467, 78-83.
49. Paterson, M.S. (1982) The determination of hydroxyl by infrared absorption inquartz, silicate glasses, and similar materials. Bulletin de Minéralogie, 105, 20-29.
50. Roedder, E. (1984) The origin of inclusions. In E. Roedder, Ed., Fluid Inclusions, 12, p. 12-45. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
51. Rossman, G.R. (1990) Hydrogen in "anhydrous" minerals. Nuclear Instruments and Methods in Research B, 45, 41-44.
52. - (2006) Analytical methods for measuring water in nominally anhydrous minerals. In H. Keppler and J.R. Smyth, Eds., Water in Nominally Anhydrous Minerals, 62, p. 1-28. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.
53. Saal, A.E., Hauri, E.H., Lo Cascio, M., van Orman, J.A., Rutherford, M.C., and Cooper, R.E. (2008) Volatile content of lunar volcanic glasses and the presence of water in the Moon's interior. Nature, 454, 192-196.
54. Serratosa, J.M. and Bradley, W.F. (1958) Determination of the orientation of OH bond axes in layer silicates by infrared absorption. Journal of Physical Chemistry, 62, 1164-1167.
55. Shankland, T.J. (1967) Synthetic forsterite. Ceramic Bulletin, 46, 1160-1162.
56. Shinoda, K. and Aikawa, N. (1998) Interlayer proton transfer in brucite under pressure by polarized IR spectroscopy. Physics and Chemistry of Minerals, 25, 197-202.
57. Skogby, H. and Rossman, G.R. (1991) The intensity of amphibole OH bands in the infrared absorption spectrum. Physics and Chemistry of Minerals, 18, 64-68.
58. Smyth, J.R. and Jacobsen, S.D. (2006) Nominally anhydrous minerals and Earth's deep water cycle. In S.D. Jacobsen and S. van der Lee, Eds., Earth's Deep Water Cycle, p. 1-11. American Geophysical Union, Washington, D.C.
59. Smyth, J.R., Frost, D.J., Nestola, F., Holl, C.M., and Bromiley, G. (2006) Olivine hydration in the deep upper mantle: Effects of temperature and silica activity. Geophysical Research Letters, 33, L15301, DOI: 10.1029/2006GL026194. (Pubitemid 44945773)
60. Sykes, D., Rossman, G.R., Veblen, D.R., and Grew, E.S. (1994) Enhanced H and F incorporation in borian olivine. American Mineralogist, 79, 904-908.
61. Tenner, T.J., Hirschmann, M.M., Withers, A.C., and Hervig, R.L. (2009) Hydrogen partitioning between nominally anhydrous upper mantle minerals and melt between 3 and 5 GPa. Chemical Geology, 262, 42-56.
62. Walker, A.M., Hermann, J., Berry, A.J., and O'Neill, H.S.C. (2007) Three water sites in upper mantle olivine and the role of titanium in the water weakening mechanism. Journal of Geophysical Research, 112, B05211, DOI: 10.1029/2006JB004620.
63. 2O storage capacity of olivine at 8 GPa. Contributions to Mineralogy and Petrology, 156, 595-605.
64. York, D. (1966) Least-squares fitting of a straight line. Canadian Journal of Physics, 44, 1079-1086.