Cation vacancy and possible hydrogen positions in hydrous forsterite, Mg1.985Si0.993H0.06O4, synthesized at 13.5 GPa and 1300 °C

Journal of Mineralogical and Petrological Sciences

Volumn 101, Issue 5, 2006, Pages 265-269

  Kudoh, Yasuhiro ^a   Kuribayashi, Takahiro ^a   Kagi, Hiroyuki ^b   Inoue, Toru ^c  

^a TOHOKU UNIVERSITY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c EHIME UNIVERSITY   (Japan)

Author keywords

Cation vacancy; Hydrogen location; Hydrous forsterite

Indexed keywords

EID: 33751109223     PISSN: 13456296     EISSN: 13493825     Source Type: Journal    
DOI: 10.2465/jmps.101.265     Document Type: Article

References (13)

1. Beran, A. and Putnis, A. (1983) A model of the OH positions in olivine, derived from infrared-spectroscopic investigations. Physics and Chemistry of Minerals, 9, 57-60.
2. Brese, N.E. and O'Keeffe, M. (1991) Bond-valence parameters for solids. Acta Crystallographica, B47, 192-197.
3. Brown, I.D. and Shannon, R.D. (1973) Empirical bond-strength-bond-length curves for oxides. Acta Crystallographica, A29, 266-282.
4. 4 system. Geophysical Research Letters, 29, 1875, doi:10.1029/2001GL014429.
5. 4. Contributions to Mineralogy and Petrology, 123, 345-357.
6. 4: possible hydrous magnesium silicate in the mantle transition zone. Physics and Chemistry of Minerals, 23, 461-469.
7. Libowitzky E. and Beran, A. (1995) OH defects in forsterite. Physics and Chemistry of Minerals, 22, 387-392.
8. Martin, R.F. and Donnay, G. (1972) Hydroxyl in the mantle. American Mineralogist, 57, 554-570.
9. Miller, G.H., Rossman, G.R. and Harlow, G.E. (1987) The natural occurrence of hydroxide in olivine. Physics and Chemistry of Minerals, 14, 461-472.
10. Mosenfelder, J.L., Deligne, N.I., Asimow, P.D. and Rossman, G.R. (2006) Hydrpgen incorporation in olivine from 2-12 GPa. American Mineralogist, 91, 285-294.
11. Nakamoto, K., Margoshes M., and Rundle, R.E. (1955) Stretching frequencies as a function of distances in hydrogen bonds. Journal of the American Chemical Society, 77, 6480-6486.
12. Smyth, J.R., Frost, D.J., Nestola, F., Holl, C.M. and Bromiley, G. (2006) Olivine hydration in the deep upper mantle: effects of temperature and silica activity. Geophysical Research Letters, 33, L15301, doi:10.1029/2006GL026194.
13. teXsan (1992) Crystallographic Structure Analysis Package, Molecular Structure Corporation, Texas, U.S.A.