Synthesis and characterization of a trianionic pincer supported Mo-alkylidene anion and alkyne insertion into a Mo(IV)-Cpincer bond to form metallocyclopropene(η2-vinyl) complexes

Journal of Organometallic Chemistry

Volumn 696, Issue 25, 2011, Pages 4079-4089

  Jan, Muhammad T ^a   Sarkar, Soumya ^a   Kuppuswamy, Subramaniam ^a   Ghiviriga, Ion ^a   Abboud, Khalil A ^a   Veige, Adam S ^a  

^a UNIVERSITY OF FLORIDA   (United States)

Author keywords

Alkylidene; Alkylidyne; Insertion; Metallocyclopropene; Trianionic pincer; Vinyl

Indexed keywords

ALKYLIDENES; ALKYLIDYNES; INSERTION; METALLOCYCLOPROPENE; TRIANIONIC PINCER; VINYL;

ACETYLENE; CHELATION; CHROMIUM COMPOUNDS; COMBUSTION; IONS; LIGANDS; MOLECULAR ORBITALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; TOLUENE; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

MOLYBDENUM COMPOUNDS;

EID: 81355149735     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2011.06.006     Document Type: Article

References (63)

1. F. Pennella, R.L. Banks, and G.C. Bailey Chem. Commun. 1968 1548
2. J.H. Wengrovius, J. Sancho, and R.R. Schrock J. Am. Chem. Soc. 103 1981 3932
3. J. Sancho, and R.R. Schrock J. Mol. Catal. 15 1982 75
4. R.R. Schrock Angew. Chem. Int. Ed. 45 2006 3748
5. R.R. Schrock, and C. Czekelius Adv. Synth. Catal. 349 2007 55
6. W. Zhang, and J.S. Moore Adv. Synth. Catal. 349 2007 93
7. A. Furstner, and P.W. Davies Chem. Commun. 2005 2307
8. Z.J. Tonzetich, R.R. Schrock, K.M. Wampler, B.C. Bailey, C.C. Cummins, and P. Muller Inorg. Chem. 47 2008 1560
9. R.R. Schrock, M.L. Listemann, and L.G. Sturgeoff J. Am. Chem. Soc. 104 1982 4291
10. X.A. Wu, and M. Tamm Beilstein J. Org. Chem. 7 2011 82
11. J.P. Boyd, M. Schlangen, A. Grohmann, and H. Schwarz Helv. Chim. Acta 91 2008 1430
12. A.M. Geyer, E.S. Wiedner, J.B. Gary, R.L. Gdula, N.C. Kuhlmann, M.J.A. Johnson, B.D. Dunietz, and J.W. Kampf J. Am. Chem. Soc. 130 2008 8984
13. A.M. Geyer, R.L. Gdula, E.S. Wiedner, and M.J.A. Johnson J. Am. Chem. Soc. 129 2007 3800
14. B.C. Bailey, A.R. Fout, H.J. Fan, J. Tomaszewski, J.C. Huffman, J.B. Gary, M.J.A. Johnson, and D.J. Mindiola J. Am. Chem. Soc. 129 2007 2234
15. R.L. Gdula, and M.J.A. Johnson J. Am. Chem. Soc. 128 2006 9614
16. E.S. Wiedner, K.J. Gallagher, M.J.A. Johnson, and J.W. Kampf Inorg. Chem. ASAP 2011
17. A.D. Finke, and J.S. Moore Chem. Commun. 46 2010 7939
18. J. Heppekausen, R. Stade, R. Goddard, and A. Furstner J. Am. Chem. Soc. 132 2010 11045
19. M. Bindl, R. Stade, E.K. Heilmann, A. Picot, R. Goddard, and A. Furstner J. Am. Chem. Soc. 131 2009 9468
20. A. Mayr, and G.A. Mcdermott J. Am. Chem. Soc. 108 1986 548
21. G.A. Mcdermott, A.M. Dorries, and A. Mayr Organometallics 6 1987 925
22. S. Lysenko, B. Haberlag, C.G. Daniliuc, P.G. Jones, and M. Tamm ChemCatChem 3 2011 115
23. R.L. Gdula, M.J.A. Johnson, and N.W. Ockwig Inorg. Chem. 44 2005 9140
24. M.H. Chisholm, E.E. Delbridge, A.R. Kidwell, and K.B. Quinlan Chem. Commun. 2003 126
25. S. Kuppuswamy, A.J. Peloquin, I. Ghiviriea, K.A. Abboud, and A.S. Veige Organometallics 29 2010 4227
26. S. Sarkar, A.R. Carlson, M.K. Veige, J.M. Falkowski, K.A. Abboud, and A.S. Veige J. Am. Chem. Soc. 130 2008 1116
27. J. Koller, S. Sarkar, K.A. Abboud, and A.S. Veige Organometallics 26 2007 5438
28. T. Agapie, and J.E. Bercaw Organometallics 26 2007 2957
29. S. Sarkar, K.A. Abboud, and A.S. Veige J. Am. Chem. Soc. 130 2008 16128
30. M. O'Reilly, J.M. Falkowski, V. Ramachandran, M. Pati, K.A. Abboud, N.S. Dalal, T.G. Gray, and A.S. Veige Inorg. Chem. 48 2009 10901
31. B.A. Burroughs, B.E. Bursten, S. Chen, M.H. Chisholm, and A.R. Kidwell Inorg. Chem. 47 2008 5377
32. Z.J. Tonzetich, R.R. Schrock, and P. Muller Organometallics 25 2006 4301
33. O.V. Dolomanov, L.J. Bourhis, R.J. Gildea, J.A.K. Howard, and H. Puschmann J. Appl. Crystallogr. 42 2009 339
34. R. Singh, C. Czekelius, R.R. Schrock, P. Muller, and A.H. Hoveyda Organometallics 26 2007 2528
35. W.C.P. Tsang, J.A. Jernelius, G.A. Cortez, G.S. Weatherhead, R.R. Schrock, and A.H. Hoveyda J. Am. Chem. Soc. 125 2003 2591
36. R.R. Schrock, J.Y. Jamieson, S.J. Dolman, S.A. Miller, P.J. Bonitatebus, and A.H. Hoveyda Organometallics 21 2002 409
37. S.L. Aeilts, D.R. Cefalo, P.J. Bonitatebus, J.H. Houser, A.H. Hoveyda, and R.R. Schrock Angew. Chem. Int. Ed. 40 2001 1452
38. S. Kuppuswamy, I. Ghiviriga, K.A. Abboud, and A.S. Veige Organometallics 29 2010 6711
39. A.W. Addison, T.N. Rao, J. Reedijk, J. Vanrijn, and G.C. Verschoor J. Chem. Soc. Dalton Trans. 1984 1349
40. B.L. Haymore, E.A. Maatta, and R.A.D. Wentworth J. Am. Chem. Soc. 101 1979 2063
41. V.C. Gibson, E.L. Marshall, C. Redshaw, W. Clegg, and M.R.J. Elsegood J. Chem. Soc. Dalton Trans. 1996 4197
42. V.C. Gibson, C. Redshaw, W. Clegg, and M.R.J. Elsegood Polyhedron 26 2007 3161
43. J.M. Blackwell, J.S. Figueroa, F.H. Stephens, and C.C. Cummins Organometallics 22 2003 3351
44. Y.C. Tsai, P.L. Diaconescu, and C.C. Cummins Organometallics 19 2000 5260
45. J.L. Templeton Adv. Organomet. Chem. 29 1989 1
46. M. Green, N.C. Norman, and A.G. Orpen J. Am. Chem. Soc. 103 1981 1267
47. S.R. Allen, R.G. Beevor, M. Green, N.C. Norman, A.G. Orpen, and I.D. Williams J. Chem. Soc. Dalton Trans. 1985 435
48. S.R. Allen, M. Green, A.G. Orpen, and I.D. Williams J. Chem. Soc. Chem. Commun. 1982 826
49. J.L. Davidson, W.F. Wilson, L. Manojlovicmuir, and K.W. Muir J. Organomet. Chem. 254 1983 C6
50. H. Ishino, S. Kuwata, Y. Ishii, and M. Hidai Organometallics 20 2001 13
51. N.M. Aghatabay, J.L. Davidson, G. Douglas, and K.W. Muir J. Chem. Soc. Chem. Commun. 1989 549
52. J.L. Kiplinger, M.A. King, A.M. Arif, and T.G. Richmond Organometallics 12 1993 3382
53. J.L. Kiplinger, M.A. King, A. Fechtenkotter, A.M. Arif, and T.G. Richmond Organometallics 15 1996 5292
54. J.L. Kiplinger, T.G. Richmond, A.M. Arif, C. DuckerBenfer, and R. vanEldik Organometallics 15 1996 1545
55. P. Legzdins, S.A. Lumb, and S.J. Rettig Organometallics 18 1999 3128
56. D.A. Dobbs, R.R. Schrock, and W.M. Davis Inorg. Chim. Acta 263 1997 171
57. S.R. Allen, R.G. Beevor, M. Green, A.G. Orpen, K.E. Paddick, and I.D. Williams J. Chem. Soc. Dalton Trans. 1987 591
58. A.E. Reed, L.A. Curtiss, and F. Weinhold Chem. Rev. 88 1988 899
59. A.D. Becke J. Chem. Phys. 98 1993 5648
60. C.T. Lee, W.T. Yang, and R.G. Parr Phys. Rev. B 37 1988 785
61. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G.A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H.P. Hratchian, A.F. Izmaylov, J. Bloino, G. Zheng, J.L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J.A. Montgomery Jr., J.E. Peralta, F. Ogliaro, M. Bearpark, J.J. Heyd, E. Brothers, K.N. Kudin, V.N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J.C. Burant, S.S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J.M. Millam, M. Klene, J.E. Knox, J.B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, R.L. Martin, K. Morokuma, V.G. Zakrzewski, G.A. Voth, P. Salvador, J.J. Dannenberg, S. Dapprich, A.D. Daniels, O. Farkas, J.B. Foresman, J.V. Ortiz, J. Cioslowski, and D.J. Fox Gaussian 09, Revision A.02 2009 Gaussian
62. P.J. Hay, and W.R. Wadt J. Chem. Phys. 82 1985 270
63. A.R. Allouche Gabedit. http://gabedit.sourceforge.net.