An enantiomerically pure adamantylimido molybdenum alkylidene complex. An effective new catalyst for enantioselective olefin metathesis

Journal of the American Chemical Society

Volumn 125, Issue 9, 2003, Pages 2591-2596

  Tsang, W C Peter ^b   Jernelius, Jesper A ^a   Cortez, G A ^a   Weatherhead, Gabriel S ^a   Schrock, Richard R ^b   Hoveyda, Amir H ^a  

^a BOSTON COLLEGE   (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; SYNTHESIS (CHEMICAL); X RAY ANALYSIS;

LIGANDS;

MOLYBDENUM COMPOUNDS;

ADAMANTANE DERIVATIVE; ALKENE; ALKYL GROUP; IMIDE; LIGAND; MOLYBDENUM COMPLEX; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHIRALITY; ENANTIOMER; ENANTIOSELECTIVITY; PROTON NUCLEAR MAGNETIC RESONANCE; RING CLOSING METATHESIS; SYNTHESIS; X RAY ANALYSIS;

ALKENES; BORONIC ACIDS; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; MOLYBDENUM; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM;

EID: 0142046305     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja021204d     Document Type: Article

References (36)

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32. See the Supporting Information for crystal data and structure refinement parameters.
33. CH determination.
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