Observation of the turnover between the solvent friction (overdamped) and tunneling (nonadiabatic) charge-transfer mechanisms for a Au/Fe(CN)63-/4- electrode process and evidence for a freezing out of the Marcus barrier

Journal of Physical Chemistry A

Volumn 105, Issue 10, 2001, Pages 1818-1829

  Khoshtariya, Dimitri E ^a,b   Dolidze, Tina D ^a   Zusman, Leonid D ^c,d   Waldeck, David H ^c  

^a Institute of Inorganic Chemistry and Electrochemistry   (Georgia)

^b INSTITUTE OF PHYSICS   (Georgia)

^c UNIVERSITY OF PITTSBURGH   (United States)

^d NIKOLAEV INSTITUTE OF INORGANIC CHEMISTRY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

FRACTIONAL VISCOSITY; MARCUS BARRIER;

CHARGE TRANSFER; DAMPING; ELECTRODES; ELECTRON TRANSITIONS; ELECTRON TUNNELING; FREEZING; FRICTION; GOLD; INTERFACES (MATERIALS); IRON COMPOUNDS; RATE CONSTANTS; REDOX REACTIONS; VISCOSITY;

SOLVENTS;

EID: 0035869064     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0041095     Document Type: Article

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