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Volumn 125, Issue 7, 2003, Pages 2004-2013

Heterogeneous electron-transfer kinetics for ruthenium and ferrocene redox moieties through alkanethiol monolayers on gold

Author keywords

[No Author keywords available]

Indexed keywords

CYCLIC VOLTAMMETRY; ELECTRON TRANSITIONS; RATE CONSTANTS; RUTHENIUM; SELF ASSEMBLY;

EID: 0037442897     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028458j     Document Type: Article
Times cited : (281)

References (90)
  • 1
    • 0001318962 scopus 로고    scopus 로고
    • Bard, A. J., Rubinstein, I., Eds.; Marcel Dekker: New York
    • Finklea, H. O. In Electroanalytical Chemistry: Bard, A. J., Rubinstein, I., Eds.; Marcel Dekker: New York, 1996; Vol. 19, pp 109-335.
    • (1996) Electroanalytical Chemistry , vol.19 , pp. 109-335
    • Finklea, H.O.1
  • 3
    • 0013373626 scopus 로고    scopus 로고
    • Ph.D. Thesis, Stanford University, Stanford, CA
    • Sachs, S. B., Ph.D. Thesis, Stanford University, Stanford, CA, 2000.
    • (2000)
    • Sachs, S.B.1
  • 31
    • 0013422454 scopus 로고    scopus 로고
    • note
    • 30 have recently observed that the distance dependence of the ferrocene (redox couple)/unsubstituted OPE (bridge) electron-transfer rate constants is not monotonic.
  • 42
    • 0013373525 scopus 로고    scopus 로고
    • note
    • 41 demonstrate that both thiols and disulfides react with gold surfaces to form the same species.
  • 50
    • 0013326948 scopus 로고    scopus 로고
    • note
    • 17
  • 57
    • 0013326949 scopus 로고    scopus 로고
    • note
    • A (see eq 10).
  • 62
    • 0013326487 scopus 로고    scopus 로고
    • note
    • τ = 0.15 eV.
  • 68
    • 0013378333 scopus 로고    scopus 로고
    • note
    • app values seen at long bridge lengths are the same (within experimental error) as the anticipated values of the outer sphere reorganization energies of the ferrocene and ruthenium redox couples, and that the activation entropies of both redox couples are negligibly small.
  • 87
    • 0013371248 scopus 로고    scopus 로고
    • note
    • n. The linearized Butler-Volmer expression? therefore, gives eq 15.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.