Catalytic hydrogenation of carbon dioxide with a highly active hydride on Ir(III)pincer complex: Mechanism for CO2 insertion and nature of metalhydride bond

Bulletin of the Chemical Society of Japan

Volumn 84, Issue 10, 2011, Pages 1039-1048

  Li, Jun ^a   Yoshizawa, Kazunari ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE COMPLEXES; BOND PROPERTIES; CATALYTIC CYCLES; CATALYTIC HYDROGENATION; DENSITY FUNCTIONAL THEORY CALCULATIONS; EXPERIMENTAL OBSERVATION; METAL CENTERS; NATURAL BOND ORBITAL ANALYSIS; NUCLEOPHILIC ATTACK; PINCER COMPLEXES; RATE-LIMITING STEPS; REACTION MECHANISM; THEORETICAL RESULT; TRIHYDRIDE COMPLEXES;

CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; HYDRIDES; HYDROGENATION; IRIDIUM; MOLECULAR ORBITALS;

CARBON DIOXIDE;

EID: 80054101896     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.20110128     Document Type: Article

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