메뉴 건너뛰기




Volumn 122, Issue 16, 2000, Pages 3867-3877

Theoretical study of ruthenium-catalyzed hydrogenation of carbon dioxide into formic acid. Reaction mechanism involving a new type of σ-bond metathesis

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; FORMIC ACID; RUTHENIUM;

EID: 0034716817     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9938027     Document Type: Article
Times cited : (130)

References (47)
  • 28
    • 0342713369 scopus 로고
    • John Wiley & Sons Inc.: New York. Chapter 6, and references therein
    • (b) Yamamoto, A. Organotransition Metal Chemistry; John Wiley & Sons Inc.: New York. 1986; Chapter 6, pp 195-304 and references therein.
    • (1986) Organotransition Metal Chemistry , pp. 195-304
    • Yamamoto, A.1
  • 30
    • 0343147893 scopus 로고    scopus 로고
    • note
    • 2 ligand takes a position cis to the η-OCOH ligand.
  • 40
    • 0343147891 scopus 로고    scopus 로고
    • note
    • 2 insertion would be slightly less exothermic and the H-OCOH reductive elimination would be slightly more endothermic than those calculated with the DFT(B3LYP)/BS-II method. However, this deviation would not change the conclusion about reaction courses because of considerably large differences in activation barrier between the four-membered σ-bond metathesis and the six-membered σ-bond metathesis and between the six-membered σ-bond metathesis and the five-membered H-OCOH reductive elimination.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.