Determination of tebuconazole, trifloxystrobin and its metabolite in fruit and vegetables by a Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) method using gas chromatography with a nitrogen-phosphorus detector and ion trap mass spectrometry

Biomedical Chromatography

Volumn 25, Issue 10, 2011, Pages 1081-1090

  Liu, Xingang ^a   Wang, Xu ^a   Xu, Jun ^a   Dong, Fengshou ^a   Song, Wencheng ^b   Zheng, Yongquan ^a  

^a INSTITUTE OF PLANT PROTECTION   (China)

^b Institute for Control of Agrochemicals Ministry of Agriculture   (China)

Author keywords

Gas chromatography ion trap mass spectrometry; Gas chromatography nitrogen phosphorus detector; QuEChERS method; Residue; Tebuconazole; Trifloxystrobin and trifloxystrobin acid

Indexed keywords

FRUITS; IONS; MASS SPECTROMETRY; METABOLITES; NITROGEN; PHOSPHORUS; VEGETABLES;

GAS CHROMATOGRAPHY-ION TRAP MASS SPECTROMETRIES; GAS CHROMATOGRAPHY-NITROGEN-PHOSPHORUS DETECTOR; ION-TRAP MASS SPECTROMETRY; NITROGEN-PHOSPHORUS DETECTORS; QUICK, EASY, CHEAP, EFFECTIVE, RUGGED AND SAFE METHOD; RESIDUE; TEBUCONAZOLE; TRIFLOXYSTROBIN; TRIFLOXYSTROBIN AND TRIFLOXYSTROBIN ACID;

GAS CHROMATOGRAPHY;

FUNGICIDE; NITROGEN; OCTADECYLSILANE; PHOSPHORUS; SILANE; TEBUCONAZOLE; TRIFLOXYSTROBIN; TRIFLOXYSTROBIN ACID; UNCLASSIFIED DRUG;

ARTICLE; FRUIT; GAS CHROMATOGRAPHY; ION TRAP MASS SPECTROMETRY; LIMIT OF DETECTION; LIMIT OF QUANTITATION; NITROGEN DETECTOR; VEGETABLE;

EID: 80052522066     PISSN: 02693879     EISSN: 10990801     Source Type: Journal    
DOI: 10.1002/bmc.1575     Document Type: Article

References (38)

1. Abreu SD, Correia M, Herbert P, Santos L and Alves A. Screening of grapes and wine for azoxystrobin, kresoxim-methyl and trifloxystrobin fungicides by HPLC with diode array detection. Food Additives and Contaminants 2005; 22: 549-556.
2. Abreu SD, Caboni P, Cabras P, Garau VL and Alves A. Validation and global uncertainty of a liquid chromatographic with diode array detection method for the screening of azoxystrobin, kresoxim-methyl, trifloxystrobin, famoxadone, pyraclostrobin and fenamidone in grapes and wine. Analytica Chimica Acta 2006; 573: 291-297.
3. Anastassiades M, Lehotay SJ, Stajnbaher D and Schenck FJ. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and 'dispersive solid-phase extraction' for the determination of pesticide residues in produce. Journal of AOAC International 2003; 86: 412-431.
4. Banerjee K, Ligon AP and Spiteller M. Photoisomerization kinetics of trifloxystrobin. Analytical and Bioanalytical Chemistry 2005; 382: 1527-1533.
5. Banerjee K, Ligon AP and Spiteller M. Spectral elucidation of the acid metabolites of the four geometric isomers of trifloxystrobin. Analytical and Bioanalytical Chemistry 2007; 388: 1831-1838.
6. Battershill JM, Edwards PM and Johnson MK. Toxicological assessment of isomeric pesticides: a strategy for testing of chiral organophosphorus (OP) compounds for delayed polyneuropathy in a regulatory setting. Food and Chemical Toxicology 2004; 42: 1279-1285.
7. Chen J, Loo B and Ray C. Determination of trifloxystrobin and its metabolites in Hawaii soils by ASE-LC-MS/MS. Journal of Agricultural and Food Chemistry 2008; 56: 1829-1837.
8. Cho SK, El-Aty AMA, Choi JH, Jeong YM, Shin HC, Chang BJ, Lee C and Shim JH. Effectiveness of pressurized liquid extraction and solvent extraction for the simultaneous quantification of 14 pesticide residues in green tea using GC. Journal of Separation Science 2008; 31: 1750-1760.
9. Christensen HB and Granby K. Method validation for strobilurin fungicides in cereals and fruit. Food Additives and Contaminants 2001; 18: 866-874.
10. Cunha SC, Lehotay SJ, Mastovska K, Fernandes JO, Beatriz M and Oliveira PP. Evaluation of the QuEChERS sample preparation approach for the analysis of pesticide residues in olives. Journal of Separation Science 2007; 30: 620-632.
11. Di Muccio A, Fidente P, Barbini DA, Dommarco R, Seccia S and Morrica P. Application of solid-phase extraction and liquid chromatography-mass spectrometry to the determination of neonicotinoid pesticide residues in fruit and vegetables. Journal of Chromatography A 2006; 1108: 1-6.
12. Faria AM, Maldaner L, Santana CC, Jardim I and Collins CH. Poly(methyltetradecylsiloxane) immobilized onto silica for extraction of multiclass pesticides from surface waters. Analytica Chimica Acta 2007; 582: 34-40.
13. Garland SM, Menary RC and Davies NW. Dissipation of propiconazole and tebuconazole in peppermint crops (Mentha piperita (Labiatae) and their residues in distilled oils. Journal of Agricultural and Food Chemistry 1999; 47: 294-298.
14. Gonzalez-Rodriguez RM, Rial-Otero R, Cancho-Grande B and Simal-Gandara J. Occurrence of fungicide and insecticide residues in trade samples of leafy vegetables. Food Chemistry 2008a; 107: 1342-1347.
15. Gonzalez-Rodriguez RM, Rial-Otero R, Cancho-Grande B and Simal-Gandara J. Determination of 23 pesticide residues in leafy vegetables using gas chromatography-ion trap mass spectrometry and analyte protectants. Journal of Chromatography A 2008b; 1196: 100-109.
16. Gonzalez-Rodriguez RM, Cancho-Grande B and Simal-Gandara J. Multiresidue determination of 11 new fungicides in grapes and wines by liquid-liquid extraction/clean-up and programmable temperature vaporization injection with analyte protectants/gas chromatography/ion trap mass spectrometry. Journal of Chromatography A 2009a; 1216: 6033-6042.
17. Gonzalez-Rodriguez RM, Cancho-Grande B, Torrado-Agrasar A, Simal-Gandara J and Mazaira-Perez J. Evolution of tebuconazole residues through the winemaking process of Mencia grapes. Food Chemistry 2009b; 117: 529-537.
18. Karaoglanidis GS and Karadimos DA. Efficacy of strobilurins and mixtures with DMI fungicides in controlling powdery mildew in field-grown sugar beet. Crop Protection 2006; 25: 977-983.
19. Kovalczuk T, Lacina O, Jech M, Poustka J and Hajslova J. Novel approach to fast determination of multiple pesticide residues using ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). Food Additives and Contaminants 2008; 25: 444-457.
20. Lee JM, Park JW, Jang GC and Hwang KJ. Comparative study of pesticide multi-residue extraction in tobacco for gas chromatography-triple quadrupole mass spectrometry. Journal of Chromatography A 2008; 1187: 25-33.
21. Lesueur C, Knittl P, Gartner M, Mentler A and Fuerhacker M. Analysis of 140 pesticides from conventional farming foodstuff samples after extraction with the modified QuECheRS method. Food Control 2008; 19: 906-914.
22. Likas DT, Tsiropoulos NG and Miliadis GE. Rapid gas chromatographic method for the determination of famoxadone, trifloxystrobin and fenhexamid residues in tomato, grapeand wine samples. Journal of Chromatography A 2007; 1150: 208-214.
23. Lopez-Blanco MC, Cancho-Grande B and Simal-Gandara J. Comparison of solid-phase extraction and solid-phase microextraction for carbofuran in water analyzed by high-performance liquid chromatography-photodiode-array detection. Journal of Chromatography A 2002a; 963: 117-123.
24. Lopez-Blanco MC, Reboreda-Rodriguez B, Cancho-Grande B and Simal-Gandara J. Optimization of solid-phase extraction and solid-phase microextraction for the determination of alpha- and beta-endosulfan in water by gas chromatography-electron-capture detection. Journal of Chromatography A 2002b; 976: 293-299.
25. Lopez-Blanco MC, Blanco-Cid S, Cancho-Grande B and Simal-Gandara J. Application of single-drop microextraction and comparison with solid-phase microextraction and solid-phase extraction for the determination of alpha- and beta-endosulfan in water samples by gas chromatography-electron-capture detection. Journal of Chromatography A 2003; 984: 245-252.
26. Maldaner L, Santana CC and Jardim I. HPLC determination of pesticides in soybeans using matrix solid phase dispersion. Journal of Liquid Chromatography & Related Technologies 2008; 31: 972-983.
27. Menezes A, Navickiene S and Dorea HS. Development of MSPD method for the determination of pesticide residues in tomato by GC-MS. Journal of the Brazilian Chemical Society 2006; 17: 874-879.
28. Nguyen TD, Lee BS, Lee BR, Lee DM and Lee GH. A multiresidue method for the determination of 109 pesticides in rice using the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) sample preparation method and gas chromatography/mass spectrometry with temperature control and vacuum concentration. Rapid Communications in Mass Spectrometry 2007; 21: 3115-3122.
29. Nguyen TD, Han EM, Seo MS, Kim SR, Yun MY, Lee DM and Lee GH. A multi-residue method for the determination of 203 pesticides in rice paddies using gas chromatography/mass spectrometry. Analytica Chimica Acta 2008; 619: 67-74.
30. Otero RR, Ruiz CY, Grande BC and Gandara JS. Solid-phase microextraction-gas chromatographic-mass spectrometric method for the determination of the fungicides cyprodinil and fludioxonil in white wines. Journal of Chromatography A 2002; 942: 41-52.
31. Paya P, Anastassiades M, Mack D, Sigalova I, Tasdelen B, Oliva J and Barba A. Analysis of pesticide residues using the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) pesticide multiresidue method in combination with gas and liquid chromatography and tandem mass spectrometric detection. Analytical and Bioanalytical Chemistry 2007; 389: 1697-1714.
32. Reuveni M. Efficacy of trifloxystrobin (Flint), a new strobilurin fungicide, in controlling powdery mildews on apple, mango and nectarine, and rust on prune trees. Crop Protection 2000; 19: 335-341.
33. Rial-Otero R, Gonzalez-Rodriguez RM, Cancho-Grande B and Simal-Gandara J. Parameters affecting extraction of selected fungicides from vineyard soils. Journal of Agricultural and Food Chemistry 2004; 52: 7227-7234.
34. Rial-Otero R, Arias-Estevez M, Lopez-Periago E, Cancho-Grande B and Simal-Gandara J. Variation in concentrations of the Fungicides tebuconazole and dichlofluanid following successive applications to green house-grown lettuces. Journal of Agricultural and Food Chemistry 2005; 53: 4471-4475.
35. Sannino A, Bolzoni L and Bandini M. Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables. Journal of Chromatography A 2004; 1036: 161-169.
36. Schenck FJ, Brown AN, Podhorniak LV, Parker A, Reliford M and Wong JW. A rapid multiresidue method for determination of pesticides in fruits and vegetables by using acetonitrile extraction/partitioning and solid-phase extraction column cleanup. Journal of Aoac International 2008; 91: 422-438.
37. Sudisha J, Amruthesh KN, Deepak SA, Shetty NP, Sarosh BR and Shetty HS. Comparative efficacy of strobilurin fungicides against downy mildew disease of pearl millet. Pesticide Biochemistry and Physiology 2005; 81: 188-197.
38. Walz I and Schwack W. Multienzyme inhibition assay for residue analysis of insecticidal organophosphates and carbamates. Journal of Agricultural and Food Chemistry 2007; 55: 10563-10571.