A higher energy conformer of (S)-proline is the active catalyst in intermolecular aldol reaction: Evidence from DFT calculations

Journal of Molecular Catalysis A: Chemical

Volumn 345, Issue 1-2, 2011, Pages 37-43

  Ajitha, Manjaly J ^a   Suresh, Cherumuttathu H ^a  

^a REGIONAL RESEARCH LABORATORY CSIR   (India)

Author keywords

(S) Proline; Aldol reaction; Dispersion corrected DFT; Hydrogen bond catalysis; Organocatalysis; Proton transfer mechanism

Indexed keywords

(S)-PROLINE; ALDOL REACTIONS; DISPERSION-CORRECTED DFT; ORGANOCATALYSIS; PROTON TRANSFER MECHANISM;

ACETONE; ALDEHYDES; AMINO ACIDS; CATALYSIS; CATALYSTS; CONDENSATION REACTIONS; HYDROGEN; HYDROGEN BONDS; PROTON TRANSFER; REACTION KINETICS; STEREOSELECTIVITY;

REACTION INTERMEDIATES;

EID: 79960713324     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2011.05.016     Document Type: Article

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