Seven-membered ring formation from cyclopropanated oxo- and epoxyallylsilanes

Journal of Organic Chemistry

Volumn 76, Issue 14, 2011, Pages 5850-5855

  Pulido, Francisco J ^a   Barbero, Asunción ^a   Castreǹo, Pilar ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOHEPTANE ANNULATION; NATURAL PRODUCTS; SEVEN-MEMBERED RINGS; SILYLCUPRATION; STEREOSELECTIVE SYNTHESIS;

STEREOCHEMISTRY;

STEREOSELECTIVITY;

1 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]PENTAN 3 ONE; 2 ETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL] 1,2 EPOXYBUTANE; 2 ISOPROPYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL] 1,2 EPOXYBUTANE; 2 ISOPROPYL 5 METHYLENECYCLOHEPTANOL; 2 METHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL] 1,2 EPOXYBUTANE; 2 METHYL 5 METHYLENECYCLOHEPTANOL; 2,2 DIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL] 4 PHENYLBUTAN 1 OL; 2,2 DIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL] 4 PHENYLBUTANAL; 2,2 DIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]BUTAN 1 OL; 2,2 DIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]BUTANAL; 2,2 DIMETHYL 5 METHYLENE 4 PHENYLCYCLOHEPTANOL; 2,2 DIMETHYL 5 METHYLENECYCLOHEPTANOL; 2,2,4 TRIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL] 1,2 EPOXYPENTANE; 2,2,4 TRIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]PENTAN 1 OL; 2,2,4 TRIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]PENTANAL; 2,2,4,4 TETRAMETHYL 5 METHYLENECYCLOHEPTANOL; 2,2,5 TRIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]HEXAN 1 OL; 2,2,5 TRIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]HEXANAL; 2,4,4 TRIMETHYL 5 METHYLENECYCLOHEPTANOL; 2,5 DIMETHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL] 1,2 EPOXYHEXANE; 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]BUTAN 2 ONE; 4 ISOPROPYL 2 METHYL 5 METHYLENECYCLOHEPTANOL; 4 ISOPROPYL 2,2 DIMETHYL 5 METHYLENECYCLOHEPTANOL; 4 METHYL 1 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]PENTAN 3 ONE; 4 METHYL 4 [1 (DIMETHYLPHENYLSILYLMETHYL)CYCLOPROPYL]PENTAN 2 ONE; ALLENE DERIVATIVE; SILANE DERIVATIVE; UNCLASSIFIED DRUG;

ANNULATION REACTION; ARTICLE; CYCLOPROPANATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 79960168635     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo200705u     Document Type: Article

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