Production of extremely pure diacylglycerol from soybean oil by lipase-catalyzed glycerolysis

Enzyme and Microbial Technology

Volumn 49, Issue 2, 2011, Pages 192-196

  Wang, Weifei ^a   Li, Tie ^a   Ning, Zhengxiang ^a   Wang, Yonghua ^a   Yang, Bo ^a   Yang, Xiaoquan ^a  

^a SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Diacylglycerols; Glycerolysis; Immobilized lipase; Soybean oil

Indexed keywords

BATCH REACTIONS; CONVERSION RATES; DIACYLGLYCEROL; DIACYLGLYCEROLS; ENZYMATIC GLYCEROLYSIS; GLYCEROLYSIS; IMMOBILIZED LIPASE; LIPASE-CATALYZED GLYCEROLYSIS; LIPOZYME; LIPOZYME TL IM; MASS RATIO; MOLECULAR DISTILLATION; NOVOZYM435; OPTIMAL REACTION CONDITION; OPTIMIZED REACTION CONDITIONS; REACTION TEMPERATURE; SCALE-UP; SOYBEAN OIL; SUBSTRATE CONCENTRATIONS; T-BUTANOL; TWO STAGE;

DISTILLATION; ENGINEERING RESEARCH; LIPASES; OPTIMIZATION; SUBSTRATES;

GLYCEROL;

DIACYLGLYCEROL; ESTERASE; GLYCEROL; LIPOZYME RM IM; LIPOZYME TL IM; NOVOZYM 435; SOYBEAN OIL; TERT BUTYL ALCOHOL; TRIACYLGLYCEROL LIPASE; UNCLASSIFIED DRUG;

ARTICLE; BATCH REACTOR; BIOTRANSFORMATION; CATALYSIS; CHEMICAL REACTION; CONTROLLED STUDY; DISTILLATION; ENZYME ACTIVITY; ENZYME IMMOBILIZATION; ENZYME METABOLISM; ENZYME PURIFICATION; ENZYME SUBSTRATE; ENZYME SYNTHESIS; GLYCEROLYSIS; GLYCOLYSIS; LARGE SCALE PRODUCTION; MOLECULAR WEIGHT; NONHUMAN; REACTION TIME; ROOM TEMPERATURE;

DIGLYCERIDES; ENZYMES, IMMOBILIZED; GLYCEROL; KINETICS; LIPASE; SOYBEAN OIL; SUBSTRATE SPECIFICITY; TEMPERATURE; TERT-BUTYL ALCOHOL;

GLYCINE MAX;

EID: 79959862402     PISSN: 01410229     EISSN: 18790909     Source Type: Journal    
DOI: 10.1016/j.enzmictec.2011.05.001     Document Type: Article

References (14)

1. Kondo H., Hase T., Murase T., Tokimitsu I. Digestion and assimilation features of dietary DAG in the rat small intestine. J Lipids 2003, 38:25-30.
2. Lo S.K., Tan C.P., Mohd K.L., Yusoff S.A., Lai O.M. Diacylglycerol oil-properties, processes and products: a review. Food Bioprocess Technol 2008, 1:223-233.
3. Kristensen J.B., Xu X., Mu H. Process optimization using response surface design and pilot plant production of dietary diacylglycerols by lipase-catalyzed glycerolysis. J Agric Food Chem 2005, 53:7059-7066.
4. Xu X. Production of specific-structured triacylglycerols by lipase-catalyzed reactions: a review. Eur J Lipid Sci Technol 2000, 102:287-303.
5. M. Kase, M. Shimizu, J. Moriwaki, Process for producing oil and fat rich in diacylglycerol. United States Patent, Application no. 12,249,331; 2010.
6. Plou F.J., Barandiar M., Calvo M.A., Ballesteros A., Pastor E. High-yield production of mono- and di-oleylglycerol by lipase-catalysed hydrolysis of triolein. Enzyme Microb Technol 1996, 18:66-71.
7. Kristensen J.B., Xu X., Mu H. Diacylglycerol synthesis by enzymatic glycerolysis: screening of commercially available lipases. J Am Oil Chem Soc 2005, 82:329-335.
8. Yeoh C.M., Choong T.S.Y., Abdullah L.C., Yunus R., Siew W.L. Influence of silica gel in production of diacylglycerol via enzymatic glycerolysis of palm olein. Eur J Lipid Sci Technol 2009, 111:599-606.
9. Kahveci D., Guo Z., Özcelik B., Xu X. Lipase-catalyzed glycerolysis in ionic liquids directed towards diglyceride synthesis. Process Biochem 2009, 44:1358-1365.
10. Kahveci D., Guo Z., Özcelik B., Xu X. Optimisation of enzymatic synthesis of diacylglycerols in binary medium systems containing ionic liquids. Food Chem 2010, 119:880-885.
11. Valério A., Fiametti K.G., Rovani S., Franceschi E., Corazza M.L., Treichel H., et al. Enzymatic production of mono- and diglycerides in compressed n-butane and AOT surfactant. J Supercrit Fluids 2009, 49:216-220.
12. ISO Method 5509, Animal and Vegetable Fats and Oils-Preparation of Methyl Esters of Fatty Acids, 12-23-2000.
13. Rosa C.D., Morandim M.B., Ninow J.L., Oliveira D., Treichela H., Oliveira J.V. Continuous lipase-catalyzed production of fatty acid ethyl esters from soybean oil in compressed fluids. Bioresour Technol 2009, 100:5818-5826.
14. Duan Z., Du W., Liu D. Novozym 435-catalyzed 1,3-diacylglycerol preparation via esterification in t-butanol system. Process Biochem 2010, 45:1923-1927.