Spectroelectrochemical evidence for the nitrosyl redox siblings NO +, NO., and NO- coordinated to a strongly electron-accepting FeII porphyrin: DFT calculations suggest the presence of high-spin states after reduction of the FeII-NO - complex

Chemistry - A European Journal

Volumn 17, Issue 28, 2011, Pages 7868-7874

  Pellegrino, Juan ^a   Hübner, Ralph ^b   Doctorovich, Fabio ^a   Kaim, Wolfgang ^b  

^a UNIVERSIDAD DE BUENOS AIRES   (Argentina)

^b UNIVERSITY OF STUTTGART   (Germany)

Author keywords

density functional calculations; iron; nitric oxide; porphyrins; spectroelectrochemistry

Indexed keywords

CATIONIC FORMS; COMPLEX 1; COMPUTATIONAL RESULTS; DFT CALCULATION; ELECTRON-ACCEPTING; ELECTRON-DEFICIENT; ELECTRON-TRANSFER; FERRIC PORPHYRIN; HIGH SPIN STATE; HIGH-ENERGY SHIFTS; HIGHER FREQUENCIES; IRREVERSIBLE OXIDATION; LOWER FREQUENCIES; PENTAFLUOROPHENYL; PORPHYRIN COMPLEXES; PORPHYRIN VIBRATION; REVERSIBLE REDUCTION; SPECTROELECTROCHEMICAL; SPECTROELECTROCHEMICAL MEASUREMENTS; TIME-SCALES;

ELECTRONS; MICA; NITRIC OXIDE; OXIDATION; PORPHYRINS; SPECTROELECTROCHEMISTRY; SPIN DYNAMICS;

REDUCTION;

IRON; NITRIC OXIDE; PORPHYRIN;

ARTICLE; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; OXIDATION REDUCTION REACTION;

ELECTROCHEMISTRY; IRON; MODELS, CHEMICAL; MOLECULAR STRUCTURE; NITRIC OXIDE; OXIDATION-REDUCTION; PORPHYRINS;

EID: 79959645224     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201003516     Document Type: Article

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