Direct experimental evidence for the high chemical reactivity of α- and β-xylopyranosides adopting a 2,5B conformation in glycosyl transfer

Chemistry - A European Journal

Volumn 17, Issue 26, 2011, Pages 7345-7356

  Amorim, Luis ^a   Marcelo, Filipa ^a,b   Rousseau, Cyril ^c,g   Nieto, Lidia ^d   Jiménez Barbero, Jesés ^d   Marrot, Jérôme ^e   Rauter, Amélia P ^b   Sollogoub, Matthieu ^a   Bols, Mikael ^c   Blériot, Yves ^a,f  

^a SORBONNE UNIVERSITÉ   (France)

^b UNIVERSITY OF LISBON   (Portugal)

^c UNIVERSITY OF COPENHAGEN   (Denmark)

^d CENTRO DE INVESTIGACIONES BIOLÓGICAS   (Spain)

^e UNIVERSITÉ DE VERSAILLES SAINT QUENTIN EN YVELINES   (France)

^f UNIVERSITÉ DE POITIERS   (France)

^g UNIVERSITÉ D'ARTOIS   (France)

Author keywords

conformation analysis; enzyme catalysis; glycosides; glycosylation; hydrolysis; structure activity relationships

Indexed keywords

BOATS; ENZYMATIC HYDROLYSIS; GLYCOSIDES; GLYCOSYLATION; HYDROLYSIS; LOCKS (FASTENERS);

BOAT CONFORMATIONS; CONFORMATION ANALYSIS; ENERGY PENALTIES; ENZYME CATALYSIS; EXPERIMENTAL EVIDENCE; GLYCOSYLATION REACTIONS; STRUCTURE ACTIVITY RELATIONSHIPS; TRANSITION STATE;

CONFORMATIONS;

EID: 79958816218     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201003251     Document Type: Article

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