Mechanism of 4,6-O-benzylidene-directed β-mannosylation as determined by α-deuterium kinetic isotope effects

Angewandte Chemie - International Edition

Volumn 43, Issue 40, 2004, Pages 5386-5389

  Crich, David ^a   Chandrasekera, N Susantha ^a  

^a UNIVERSITY OF ILLINOIS AT CHICAGO   (United States)

Author keywords

Carbohydrates; Glycosylation; Isotope effects; Reaction mechanisms

Indexed keywords

DEUTERIUM; PHASE TRANSITIONS; REACTION KINETICS; STEREOCHEMISTRY;

MANNOSYLATION; STEREOSELECTIVITY;

AROMATIC HYDROCARBONS;

4,6 O BENZYLIDINE; BENZYLIDENE DERIVATIVE; DEUTERIUM; MANNOSIDE; UNCLASSIFIED DRUG;

ARTICLE; GLYCOSYLATION; REACTION ANALYSIS; SYNTHESIS;

BENZYLIDENE COMPOUNDS; DEUTERIUM; GLYCOSYLATION; ISOTOPE LABELING; ISOTOPES; KINETICS; MANNOSE; MODELS, CHEMICAL; THIOGLYCOSIDES;

EID: 7244245511     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200453688     Document Type: Article

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