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1
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0004263610
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Fukuda, M., Hindsgaul, O., Eds. Oxford University Press: Oxford, U.K.
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Fukuda, M., Hindsgaul, O., Eds. Molecular and Cellular Glycobiology; Oxford University Press: Oxford, U.K., 2000.
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Molecular and Cellular Glycobiology
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2
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33748245555
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Emil Fischer's proof of the configuration of sugars. A centennial tribute
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Lichtenthaler, F. W. Emil Fischer's proof of the configuration of sugars. A centennial tribute. Angew. Chem., Int. Ed. 1992, 31, 1541-1556.
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Lichtenthaler, F.W.1
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3
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0034994189
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Synthesis of D-galacto-1-azafagomine, a potent galactosidase inhibitor
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Jensen, H. H.; Bols, M. Synthesis of D-galacto-1-azafagomine, a potent galactosidase inhibitor. J. Chem. Soc., Perkin Trans 1 2001, 905-909.
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J. Chem. Soc., Perkin Trans 1
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Jensen, H.H.1
Bols, M.2
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5
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0036500382
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Stereoelectronic Substituent Effects in Polyhydroxylated Piperidines and Hexahydropyridazines
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Jensen, H. H.; Lyngbye, L.; Jensen, A.; Bols, M. Stereoelectronic Substituent Effects in Polyhydroxylated Piperidines and Hexahydropyridazines. Chem. - Eur. J. 2002, 8, 1218-1226.
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Chem. - Eur. J.
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Jensen, H.H.1
Lyngbye, L.2
Jensen, A.3
Bols, M.4
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6
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33646467138
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note
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It should be noted here that this increase in base strength is only when the axial OH is compared to the equatorial OH group. Overall the axial OH groups have decreasing base strength compared to the deoxy case.
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7
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0011786864
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Prediction of the strengths of organic bases
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Clark, J.; Perrin, D. D. Prediction of the strengths of organic bases. Q. Rev. 1964, 18, 295-320.
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Q. Rev.
, vol.18
, pp. 295-320
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Clark, J.1
Perrin, D.D.2
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8
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0014295278
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a values of amino sugars
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a values of amino sugars. Chem. Pharm. Bull. 1968, 16, 1134-1137.
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Chem. Pharm. Bull.
, vol.16
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Inouye, S.1
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9
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0037073955
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Equatorial contra axial polar substituents. The Relation of a Chemical Reaction to Stereochemical Substituent Constants
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Bols, M.; Liang, X.; Jensen, H. H. Equatorial contra axial polar substituents. The Relation of a Chemical Reaction to Stereochemical Substituent Constants. J. Org. Chem. 2002, 67, 8970-8974.
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Bols, M.1
Liang, X.2
Jensen, H.H.3
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10
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9644302342
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Stereochemical substituent effects: Investigation of the cyano, amide and carboxylate group
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Pedersen, C. M.; Bols, M. Stereochemical substituent effects: Investigation of the cyano, amide and carboxylate group. Tetrahedron 2005, 61, 115-122.
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Tetrahedron
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Pedersen, C.M.1
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11
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7044233785
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The electrostatic influence of substituents on the dissociation constants of organic acids. II
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Westheimer, F. H.; Kirkwood, J. G. The electrostatic influence of substituents on the dissociation constants of organic acids. II. J. Chem. Phys. 1938, 6, 513-517.
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Westheimer, F.H.1
Kirkwood, J.G.2
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12
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18444406251
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On the electronic effects from OH groups. Synthesis and investigation of tetrahydroxylated azabicycloheptanes
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Gregersen, A.; Pedersen, C. M.; Jensen, H. H.; Bols, M. On the electronic effects from OH groups. Synthesis and investigation of tetrahydroxylated azabicycloheptanes. Org. Biomol. Chem. 2005, 3, 1514-1519.
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Org. Biomol. Chem.
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, pp. 1514-1519
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Gregersen, A.1
Pedersen, C.M.2
Jensen, H.H.3
Bols, M.4
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13
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18444411435
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Stereo-electronic substituent effects on the basicity of amines and on the reactivity of carbohydrates
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Bols, M.; Jensen, H. H.; Lyngbye, L.; Jensen, A.; Thomsen, I. Stereo-electronic substituent effects on the basicity of amines and on the reactivity of carbohydrates. Latv. J. Chem. 2002, 60-68.
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Bols, M.1
Jensen, H.H.2
Lyngbye, L.3
Jensen, A.4
Thomsen, I.5
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14
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-
33646481571
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-
note
-
4 refers to the numbering of the molecules, which actually may be different in azasugars and carbohydrates. We are referring to the carbohydrate (or pyranoside) numbering, however.
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15
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0036012744
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Synthesis and investigation of L-fuco- and D-glucurono-azafagomine
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Jensen, H. H.; Jensen, A.; Hazell, R.; Bols, M. Synthesis and investigation of L-fuco- and D-glucurono-azafagomine. J. Chem. Soc., Perkin Trans 1 2002, 1190-1198.
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J. Chem. Soc., Perkin Trans 1
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-
Jensen, H.H.1
Jensen, A.2
Hazell, R.3
Bols, M.4
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16
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0001267759
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Protonated 3-fluoropiperidines: An unusual fluoro directing effect and a test for quantitative theories of solvation
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Lankin, D. C.; Chandrakumar, N. S.; Rao, S. N.; Spangler, D. P.; Snyder, J. P. Protonated 3-fluoropiperidines: an unusual fluoro directing effect and a test for quantitative theories of solvation. J. Am. Chem. Soc. 1993, 115, 3356-3357.
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Lankin, D.C.1
Chandrakumar, N.S.2
Rao, S.N.3
Spangler, D.P.4
Snyder, J.P.5
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17
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0034716326
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The Unexpected Diaxial Orientation of cis-3,5-Difluoropiperidine in Water: A Potent CF-NH Charge-Dipole Effect
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Snyder, J. P.; Chandrakumar, N. S.; Sato, H.; Lankin, D. C. The Unexpected Diaxial Orientation of cis-3,5-Difluoropiperidine in Water: A Potent CF-NH Charge-Dipole Effect. J. Am. Chem. Soc. 2000, 122, 544-545.
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Snyder, J.P.1
Chandrakumar, N.S.2
Sato, H.3
Lankin, D.C.4
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18
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0034623528
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Synthesis and Conformational Analysis of a Sulfonium-Ion Analogue of the Glycosidase Inhibitor Castanospermine
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Svansson, L.; Johnston, B. D.; Gu, J.-H.; Patrick, B.; Pinto, B. M. Synthesis and Conformational Analysis of a Sulfonium-Ion Analogue of the Glycosidase Inhibitor Castanospermine. J. Am. Chem. Soc. 2000, 122, 10769-10775.
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Svansson, L.1
Johnston, B.D.2
Gu, J.-H.3
Patrick, B.4
Pinto, B.M.5
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19
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0343696759
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Reactions at position 1 of carbohydrates. III. The acid catalyzed hydrolysis of glycosides
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Overend, W. G.; Rees, C. W.; Sequeira, J. S. Reactions at position 1 of carbohydrates. III. The acid catalyzed hydrolysis of glycosides. J. Chem. Soc. 1962, 3429-3440.
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Overend, W.G.1
Rees, C.W.2
Sequeira, J.S.3
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20
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0033996047
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The Role of Sugar Substituents in Glycoside Hydrolysis
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Namchuk, M. N.; McCarter, J. D.; Becalski, A.; Andrews, T.; Withers, S. G. The Role of Sugar Substituents in Glycoside Hydrolysis. J. Am. Chem. Soc. 2000, 122, 1270-1277.
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Namchuk, M.N.1
McCarter, J.D.2
Becalski, A.3
Andrews, T.4
Withers, S.G.5
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21
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0000607797
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Molecular mechanical investigations of the properties of oxocarbenium ions. 2. Application to glycoside hydrolysis
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Woods, R. J.; Andrews, C. W.; Bowen, J. P. Molecular mechanical investigations of the properties of oxocarbenium ions. 2. Application to glycoside hydrolysis. J. Am. Chem. Soc. 1992, 114, 859-864.
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Woods, R.J.1
Andrews, C.W.2
Bowen, J.P.3
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22
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0000023645
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Experimental and Theoretical Evidence of Through-Space Electrostatic Stabilization of the Incipient Oxocarbenium Ion by an Axially Oriented Electronegative Substituent during Glycopyranoside Acetolysis
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Miljkovic, M.; Yeagly, D.; Deslongchamps, P.; Dory, Y. L. Experimental and Theoretical Evidence of Through-Space Electrostatic Stabilization of the Incipient Oxocarbenium Ion by an Axially Oriented Electronegative Substituent During Glycopyranoside Acetolysis. J. Org. Chem. 1997, 62, 7597-7604.
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Miljkovic, M.1
Yeagly, D.2
Deslongchamps, P.3
Dory, Y.L.4
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23
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0002965416
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Stability of glycosides to acid hydrolysis
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Edward, J. T. Stability of glycosides to acid hydrolysis. Chem. Ind. (London) 1955, 1102-1104.
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(1955)
Chem. Ind. (London)
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Edward, J.T.1
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24
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0344392803
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Steric Effects are not the Cause of the Rate Difference in Hydrolysis of Stereoisomeric Glycosides
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Jensen, H. H.; Bols, M. Steric Effects are not the Cause of the Rate Difference in Hydrolysis of Stereoisomeric Glycosides. Org. Lett. 2003, 5, 3201-3203.
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Org. Lett.
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, pp. 3201-3203
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Jensen, H.H.1
Bols, M.2
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26
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84858883612
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s(ax) = 2.0
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s(ax) = 2.0.
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27
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4644228871
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Conformational effects on glycoside reactivity: Study of the high reactive conformer of glucose
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McDonnell, C.; Lopez, O. L.; Murphy, P.; Bolanos, J. F.; Hazell, R.; Bols, M. Conformational effects on glycoside reactivity: Study of the high reactive conformer of glucose. J. Am. Chem. Soc. 2004, 126, 12374-12385.
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McDonnell, C.1
Lopez, O.L.2
Murphy, P.3
Bolanos, J.F.4
Hazell, R.5
Bols, M.6
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28
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33646492242
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note
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For a discussion of the similarity of glycosylations and glycoside hydrolysis, see the section Glycosylation Reactions.
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29
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0000962030
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Torsional effects in glycoside reactivity: Saccharide couplings mediated by acetal protecting groups
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Fraser-Reid, B.; Wu, Z.; Andrews, C. W.; Skowronski, E.; Bowen, J. P. Torsional effects in glycoside reactivity: saccharide couplings mediated by acetal protecting groups. J. Am. Chem. Soc. 1991, 113, 1434-1435.
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Fraser-Reid, B.1
Wu, Z.2
Andrews, C.W.3
Skowronski, E.4
Bowen, J.P.5
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30
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0035130088
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1,2-Diacetals: A New Opportunity for Organic Synthesis
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Ley, S. V.; Baeschlin, D. K.; Dixon, D. J.; Foster, A. C.; Ince, S. J.; Priepke, H. W. M.; Reynolds, D. J. 1,2-Diacetals: A New Opportunity for Organic Synthesis. Chem. Rev. 2001, 101, 53-80.
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, vol.101
, pp. 53-80
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Ley, S.V.1
Baeschlin, D.K.2
Dixon, D.J.3
Foster, A.C.4
Ince, S.J.5
Priepke, H.W.M.6
Reynolds, D.J.7
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31
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3342978155
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The disarming effect of the 4,6-acetal group on glycoside reactivity. Torsional or electronic?
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Jensen, H. H.; Nordstrøm, L. U.; Bols, M. The disarming effect of the 4,6-acetal group on glycoside reactivity. Torsional or electronic? J. Am. Chem. Soc. 2004, 126, 9205-9213.
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J. Am. Chem. Soc.
, vol.126
, pp. 9205-9213
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Jensen, H.H.1
Nordstrøm, L.U.2
Bols, M.3
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32
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0033518559
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Programmable One-Pot Oligosaccharide Synthesis
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Zhang, Z.; Ollmann, I. R.; Ye, X.-S.; Wischnat, R.; Baasov, T.; Wong, C.-H. Programmable One-Pot Oligosaccharide Synthesis. J. Am. Chem. Soc. 1999, 121, 734-753.
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, vol.121
, pp. 734-753
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-
Zhang, Z.1
Ollmann, I.R.2
Ye, X.-S.3
Wischnat, R.4
Baasov, T.5
Wong, C.-H.6
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33
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0842349086
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The C-4 Configuration as a Probe to Study Glycosidation Reactions
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Bülow, A.; Meyer, T.; Olszewski, T. K.; Bols, M. The C-4 Configuration as a Probe to Study Glycosidation Reactions. Eur. J. Org. Chem. 2004, 2, 323-329.
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Eur. J. Org. Chem.
, vol.2
, pp. 323-329
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Bülow, A.1
Meyer, T.2
Olszewski, T.K.3
Bols, M.4
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