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Volumn 17, Issue 24, 2011, Pages 6635-6642

Reduced molybenum-oxide-based core-shell hybrids: "Blue" electrons are delocalized on the shell

Author keywords

electron delocalization; host guest chemistry; Keggin ions; Keplerate; polyoxomolybdates; proton coupled electron transfer

Indexed keywords

ELECTRON DELOCALIZATION; HOST-GUEST CHEMISTRY; KEGGIN IONS; KEPLERATE; POLYOXOMOLYBDATES; PROTON-COUPLED ELECTRON TRANSFER;

EID: 79957945656     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201003260     Document Type: Article
Times cited : (27)

References (74)
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    • But even the 'simple' Keggin ions-known for a long time-are still of interest regarding different aspects, including their important electronic structures; see for instance
    • But even the 'simple' Keggin ions-known for a long time-are still of interest regarding different aspects, including their important electronic structures; see for instance:, J. J. Borrás-Almenar, J. M. Clemente, E. Coronado, B. S. Tsukerblat, Chem. Phys. 1995, 195, 1-15
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    • (the crystals of the hybrid compound obtained by method 1 were monoclinic before drying); see also
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    • highlighting the results of reference [5].
    • . highlighting the results of reference [5].
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    • Crystals of 3 belong to the orthorhombic system with cell parameters (a=34.626(6), b=36.419(6), c=34.709(6) Å) close to those of the cross-linked molybdophosphate-based hybrid (a=36.621(2), b=34.778(2), c=34.824(2) Å) (see reference [4]). The crystal quality was not good enough for further investigation.
    • Crystals of 3 belong to the orthorhombic system with cell parameters (a=34.626(6), b=36.419(6), c=34.709(6) Å) close to those of the cross-linked molybdophosphate-based hybrid (a=36.621(2), b=34.778(2), c=34.824(2) Å) (see reference [4]). The crystal quality was not good enough for further investigation.
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    • 2O and O at Mo atoms of the shells in positions trans to each other has no influence on the formula. The related cluster surface has been discussed in.
    • 2O and O at Mo atoms of the shells in positions trans to each other has no influence on the formula. The related cluster surface has been discussed in, T. Liu, M. L. K. Langston, D. Li, J. M. Pigga, C. Pichon, A. M. Todea, A. Müller, Science 2011, 331, 1590-1592.
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    • The broad features can be caused by fluorescence plus overtones. As we do not refer to the excited states here the fluorescence is not discussed
    • The broad features can be caused by fluorescence plus overtones. As we do not refer to the excited states here the fluorescence is not discussed.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.