Linking icosahedral, strong molecular magnets {Mo72/(VI)Fe30/(III)} to layers - A solid-state reaction at room temperature

Angewandte Chemie - International Edition

Volumn 39, Issue 9, 2000, Pages 1612-1614

  Müller, Achim ^a   Krickemeyer, Erich ^a   Das, Samar K ^a   Kögerler, Paul ^a   Sarkar, Sabyasachi ^a   Bögge, Hartmut ^a   Schmidtmann, Marc ^a   Sarkar, Shatarupa ^a  

^a BIELEFELD UNIVERSITY   (Germany)

Author keywords

Cluster compounds; Magnetic properties; Molybdenum; Polyoxometalates; Solid state chemistry

Indexed keywords

IRON; LIGAND; MOLYBDENUM; OXYGEN; WATER;

ARTICLE; CHEMICAL REACTION; COVALENT BOND; ENVIRONMENTAL TEMPERATURE; MAGNET; POLYMERIZATION; SOLID;

EID: 0039965044     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000502)39:9<1612::AID-ANIE1612>3.0.CO;2-L     Document Type: Article

References (27)

1. See, for example Chemistry of Advanced Materials (Eds.: L. V. Interrante, M. J. Hampden-Smith), Wiley, New York, 1998, and, in relation to the problem presented here, S. Mengel, Technologiefrüherkennung, Technologieanalyse, Magnetismus, Band I, Molekulare Magnete, VDI-Technologiezentrum und bmb + f, Dusseldorf, 1999.
2. See, for example Chemistry of Advanced Materials (Eds.: L. V. Interrante, M. J. Hampden-Smith), Wiley, New York, 1998, and, in relation to the problem presented here, S. Mengel, Technologiefrüherkennung, Technologieanalyse, Magnetismus, Band I, Molekulare Magnete, VDI-Technologiezentrum und bmb + f, Dusseldorf, 1999.
3. 2} spacers according to:
4. 2} spacers according to:
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12. 2O molecules inside the sphere and in the crystal lattice could be refined for the same reason as above. Structure graphics were produced with DIAMOND 2.1 program (K. Brandenburg. Crystal Impact GbR, 1999). Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-138290. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
13. 2O molecules inside the sphere and in the crystal lattice could be refined for the same reason as above. Structure graphics were produced with DIAMOND 2.1 program (K. Brandenburg. Crystal Impact GbR, 1999). Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-138290. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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26. [2a] a spherical cluster of the same type without these fragments but correspondingly more acetate ligands should also exist.
27. [5]