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Volumn , Issue 16, 2011, Pages 2610-2615

Optimization of the efficiency of oxidation catalysts based on iron bispidine complexes

Author keywords

Bioinspired catalysis; Homogeneous catalysis; Iron; Oxidation; Rigid ligands

Indexed keywords

BIOMIMETICS; CATALYSIS; CATALYSTS; CATALYTIC OXIDATION; CHELATION; EFFICIENCY; IRON COMPOUNDS; METAL IONS; PYRIDINE; REDOX REACTIONS; RIGIDITY; STYRENE; SYNTHESIS (CHEMICAL);

EID: 79956299890     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201100212     Document Type: Article
Times cited : (13)

References (56)
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    • D. Wang, K. Ray, E. R. Farkuhar, J. R. Frisch, L. Gomez, T. A. Jackson, M. Kerscher, A. Waleska, P. Comba, M. Costas, L. Que Jr., unpublished results
    • D. Wang, K. Ray, E. R. Farkuhar, J. R. Frisch, L. Gomez, T. A. Jackson, M. Kerscher, A. Waleska, P. Comba, M. Costas, L. Que Jr., unpublished results.
  • 41
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    • note
    • There is an obvious relation between the driving force and the efficiency (kinetics), and the correlation between yield (TON) and driving force is most likely related to the suppression of slower side reactions. We are therefore currently also studying various possible pathways for the deactivation of the catalysts.
  • 43
    • 85153227986 scopus 로고    scopus 로고
    • note
    • Note that for styrene there is also an increase of the epoxide vs. aldehyde selectivity with an increasing redox potential, but this might be fortuitous, and a correlation based on only three catalysts is a dangerous interpretation in general.
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    • 85153247973 scopus 로고    scopus 로고
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    • SAINT, Bruker AXS, 1997 -2008.
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  • 47
    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen, Göttingen
    • G. M. Sheldrick, SHELXS-97, University of Göttingen, Göttingen, 1997.
    • (1997) SHELXS-97
    • Sheldrick, G.M.1
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    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen, Göttingen
    • G. M. Sheldrick, SHELXL-97, University of Göttingen, Göttingen, 1997.
    • (1997) SHELXL-97
    • Sheldrick, G.M.1
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    • 0004048804 scopus 로고    scopus 로고
    • Utrecht University, The Netherlands
    • A. L. Spek, PLATON, Utrecht University, The Netherlands.
    • PLATON
    • Spek, A.L.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.