Catecholase activity of dicopper(II)-bispidine complexes: Stabilities and structures of intermediates, kinetics and reaction mechanism

Journal of Biological Inorganic Chemistry

Volumn 12, Issue 1, 2007, Pages 36-48

  Born, Karin ^a   Comba, Peter ^a   Daubinet, André ^a   Fuchs, Alexander ^a   Wadepohl, Hubert ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Catalysis mechanism; Catechol oxidase; Density functional theory; Oxygen activation; Type 3 copper enzymes

Indexed keywords

3,5 DI TERT BUTYLCATECHOL; 3,7 DIAZABICYCLO[3.3.1]NONANE; CATECHOL; CATECHOL OXIDASE; COPPER COMPLEX; DICOPPER BISPIDINE COMPLEX; NONANE; OXYGEN; QUINONE DERIVATIVE;

ARTICLE; BINDING KINETICS; DENSITY FUNCTIONAL THEORY; ENZYME ACTIVITY; ENZYME KINETICS; ENZYME STRUCTURE; METAL BINDING; MOLECULAR MECHANICS; MOLECULAR STABILITY; OXIDATION KINETICS; PRIORITY JOURNAL; PROCESS MODEL; REACTION ANALYSIS; STOICHIOMETRY; X RAY ANALYSIS;

BICYCLO COMPOUNDS, HETEROCYCLIC; CATALYSIS; CATECHOL OXIDASE; CATECHOLS; COPPER; CRYSTALLOGRAPHY, X-RAY; ENZYME ACTIVATION; ENZYME STABILITY; KINETICS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; OXYGEN; STEREOISOMERISM; STRUCTURE-ACTIVITY RELATIONSHIP;

EID: 33845362509     PISSN: 09498257     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00775-006-0161-2     Document Type: Article

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