An unusual two-dimensional 2-fold interpenetrating metal-organic framework based on tetranuclear manganese(II) clusters: Synthesis, structure and magnetic properties

Inorganic Chemistry Communications

Volumn 14, Issue 6, 2011, Pages 867-872

  Liu, Guang Xiang ^a,b   Cha, Xiao Chun ^a   Li, Xin Long ^a   Zhang, Chun You ^a   Wang, Yan ^a,b   Nishihara, Sadafumi ^c   Ren, Xiao Ming ^a  

^a ANQING NORMAL UNIVERSITY   (China)

^b NANJING UNIVERSITY   (China)

^c Osaka Prefecture University   (Japan)

Author keywords

Crystal structure; Magnetism; Manganese(II) coordination polymer; Tetranuclear

Indexed keywords

EID: 79955859788     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.03.013     Document Type: Article

References (38)

1. 26 single-molecule magnets, Angew. Chem. Int. Ed. 47 (2008) 6694-6698.
2. M. Manoli, A. Collins, S. Parsons, A. Candini, M. Evangelisti, E.K. Brechin, Mixed-valent Mn supertetrahedra and planar discs as enhanced magnetic coolers, J. Am. Chem. Soc. 130 (2008) 11129-11139.
3. C. Desroches, G. Pilet, S.A. Borshch, S. Parola, D. Luneau, Tetranuclear manganese (II) complexes of thiacalixarenemacrocycles with trigonal prismatic six-coordinate geometries: synthesis, structure, and magnetic properties, Inorg. Chem. 44 (2005) 9112-9120.
4. 4], J. Am. Chem. Soc. 115 (1993) 1804-1816.
5. 3, Chem. Commun. (2009) 2839-2841.
6. H.C. Yao, Y.Z. Li, Y. Song, Y.S. Ma, L.M. Zheng, X.Q. Xin, Dodecanuclear manganese (III) phosphonates with cage structures, Inorg. Chem. 45 (2006) 59-65.
7. V.K. Yachandra, K. Sauer, M.P. Klein, Manganese cluster in photosynthesis: where plants oxidize water to dioxygen, Chem. Rev. 96 (1996) 2927-2950.
8. 6+ core, Chem. Commun. (2002) 864-865.
9. 6+ (X=Cl-, Br-) face-capped octahedral cores and S=12 ground states, J. Am. Chem. Soc. 121 (1999) 5489-5499.
10. A.J. Tasiopoulos, A. Vinslava, W. Wernsdorfer, K.A. Abboud, G. Christou, Giant single-molecule magnets: a Mn84 torus and its supramolecular nanotubes, Angew. Chem. Int. Ed. 43 (2004) 2117-2121. (Pubitemid 39257786)
11. 4] cluster from a novel bis(β- diketonate) ligand, Eur. J. Inorg. Chem. (2006) 1940-1944.
12. S.K. Langley, N.F. Chilton, M. Massi, B. Moubaraki, K.J. Berry, K.S. Murray, Synthesis and characterization of homo- and heterovalent tetra- hexa- hepta- and decanuclear manganese clusters using pyridyl functionalized β-diketone, carboxylate and triethanolamine ligands, Dalton Trans. (2010) 7236-7249.
13. 2] units: syntheses, structures, magnetic properties, and DFT study, Eur. J. Inorg. Chem. (2010) 4492-4498.
14. E.C. Sanudo, T. Cauchy, E. Ruiz, R.H. Laye, O. Roubeau, S.J. Teat, G. Aromi, Transition-metal porous coordination polymers with a podand ligand: structure of discrete water clusters and variable-temperature magnetism, Inorg. Chem. 46 (2007) 9045-9047.
15. S.R. Batten, R. Robson, Interpenetrating nets: ordered, periodic entanglement, Angew. Chem. Int. Ed. 37 (1998) 1460-1494.
16. J. Zhang, Z.J. Li, Y. Kang, J.K. Cheng, Y.G. Yao, Hydrothermal syntheses, crystal structures, and properties of a novel class of 3,3′,4,4′- benzophenone-tetracarboxylate (BPTC) polymers, Inorg. Chem. 43 (2004) 8085-8091.
17. O.R. Evans, W.B. Lin, Crystal engineering of NLO materials based on metal-organic coordination networks, Acc. Chem. Res. 35 (2002) 511-522.
18. L. Liu, Z.F. Li, B.L. Wang, G. Li, L.P. Wang, X.R. Meng, Z.H. He, Polymeric frameworks constructed from bulky carboxylates and 4,4′-bipyridine linkages: synthesis, crystal structures, and properties, Cryst. Growth Des. 9 (2009) 5244-5258.
19. 3 (MOF-5), J. Am. Chem. Soc. 129 (2007) 14176-14177.
20. D.R. Xiao, E.B. Wang, H.Y. An, Z.M. Su, Y.G. Li, L. Gao, C.Y. Sun, L. Xu, Rationally designed, polymeric, extended metal-ciprofloxacin complexes, Chem. Eur. J. 11 (2005) 6673-6686. (Pubitemid 41587511)
21. 2 (bix=1,4-bis(imidazol-1-ylmethyl)benzene), J. Am. Chem. Soc. 119 (1997) 2952-2953.
22. Crystal data for 1: M=737.49, Triclinic, P-1, a=12.3701(15) Å, b=12.4007(15) Å, c=13.0916(16) Å, α=108.230(2)° β=98.100(2)° γ=117.600(2)° V=1589.9(3) Å3, Z=2, F(000)=754, GOF=1.005, R1=0.0485, wR2=0.1028 [I>2σ(I)]. Structural data for 1 were collected on a Bruker Smart APEX II CCD diffractometer with Mo Kα radiation (λ=0.71073 Å). The structure was solved by direct methods and refined with the full-matrix least-squares technique using the SHELXS-97 and SHELXL-97 programs [38]. Anisotropicthermal parameters were used to refine all non-hydrogenatoms. Carbon-bound hydrogen atoms were placed ingeometrically calculated positions and constrained to ride on their parent atoms with Uiso (H)=1.2Ueq.
23. 2: a polymeric 34- and 68-membered metallacyclic network forming a novel woven polycatenated structure, Angew. Chem. Int. Ed Engl. 34 (1995) 574-575.
24. 2O (bix=1,4-bis(imidazol-1-ylmethyl)benzene): A new type of two dimensional polyrotaxane, Angew. Chem. Int. Ed Engl. 36 (1997) 2336-2338.
25. J. Yang, J.F. Ma, S.R. Batten, Z.M. Su, Unusual parallel and inclined interlocking modes inpolyrotaxane-like metal-organic frameworks, Chem. Commun. (2008) 2233-2235.
26. F. Luo, Y.T. Yang, Y.X. Che, J.M. Zheng, An unusual metal-organic framework showing both rotaxane- and cantenane-like motifs, CrystEngComm 10 (2008) 981-982.
27. G.H. Wang, Z.G. Li, H.Q. Jia, N.H. Hu, J.W. Xu, Topological diversity of coordination polymers containing the rigid terephthalate and a flexible N, N′-type ligand: interpenetration, polyrotaxane, and polythreading, Cryst. Growth Des. 8 (2008) 1932-1939.
28. L.E. Pence, A. Caneschi, S.J. Lippard, Synthesis, structural studies, and magnetic exchange interactions in low-valent manganese alkoxide cubes, Inorg. Chem. 35 (1996) 3069-3072.
29. E. Ramos, J.E. Roman, S. Cardona-Serra, J.M. Clemente-Juan, Parallel implementation of the MAGPACK package for the analysis of high-nuclearity spin clusters, Comput. Phys. Commun. 181 (2010) 1929-1940.
30. B. Albela, M. Corbella, J. Ribas, I. Castro, J. Sletten, H. Stoeckli-Evans, Synthesis, structural characterization (X-ray and EXAFS), and magnetic properties of polynuclear manganese(II) complexes with chlorobenzoato bridges, Inorg. Chem. 37 (1998) 788-798.
31. 4cubane carboxylate clusters derived from di-2-pyridyl ketone: synthesis, characterization and magnetic properties, Polyhedron 28 (2009) 2017-2025.
32. 4] single-molecule magnets, Dalton Trans. (2008) 755-766.
33. 2+/3+ species, Eur. J. Inorg. Chem. (2006) 4324-4337.
34. G.M. Yu, L. Zhao, Y.N. Guo, G.F. Xu, L.F. Zou, J.K. Tang, Y.H. Li, Synthesis, structures and magnetic properties of di- and tetranuclear manganese complexes derived from a 3-methoxysalicylaldehyde benzoylhydrazide ligand, J. Mol. Struct. 982 (2010) 139-144.
35. V. Tangoulis, G. Psomas, C. Dendrinou-Samara, C.P. Raptopoulou, A. Terzis, D. Kessissoglou, A two-dimensional manganese(II) carboxylato polymer. Structure, magnetism, and EPR study, Inorg. Chem. 35 (1996) 7655-7660.
36. H. Iikura, T. Nagata, Structural variation in manganase complexes: synthesis and characterization of manganese complexes from carboxylate- containing chelating ligands, Inorg. Chem. 37 (1998) 4702-4711.
37. E. Ruiz, S. Alvarez, P. Alemany, Theoretical search for new ferromagnetically coupled transition metal complexes, Chem. Commun. (1998) 2767-2768.
38. G.M. Sheldrick, SHELXS-97andSHELXL-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, 1997.