Structural Variation in Manganase Complexes: Synthesis and Characterization of Manganese Complexes from Carboxylate-containing Chelating Ligands

Inorganic Chemistry

Volumn 37, Issue 18, 1998, Pages 4702-4711

  Iikura, Hitoshi ^a   Nagata, Toshi ^b  

^a KYOTO UNIVERSITY   (Japan)

^b INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001676240     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971184u     Document Type: Article

References (122)

1. Wieghardt, K. Angew. Chem., Int. Ed. Engl. 1989, 28, 1153.
2. (a) Manganese Redox Enzymes; Pecoraro, V. L., Ed.; VCH: New York, 1992.
3. (b) Dismukes, G. C. Chem. Rev. 1996, 96, 2909.
4. (c) Yachandra, V. K.; Sauer, K.; Klein, M. P. Chem. Rev. 1996, 96, 2927.
5. (a) Christou, G. Acc. Chem. Res. 1989, 22, 328.
6. (b) Que, L., Jr.; True, A. E. Prog. Inorg. Chem. 1990, 38, 97.
7. (c) Lardin, R. L.; Tolman, W. B.; Lippard, S. J. New J. Chem. 1991, 15, 417.
8. 4e,f
9. (e) Tamura, N.; Ikeuchi, M.; Inoue, Y. Biochim. Biophys. Acta 1989, 973, 281.
10. (f) Andreasson, L.-E. Biochim. Biophys. Acta 1989, 973, 465.
11. (a) Karipides, A.; Reed, A. T. Inorg. Chem. 1976, 15, 44.
12. (b) Kennard, C. H.; Smith, G.; O'Reilly, E. J.; Chiangjin, W. Inorg. Chim. Acta 1983, 69, 53.
13. (c) Ardiwinata, E. S.; Craig, D. C.; Phillips, D. J. Inorg. Chim. Acta 1989, 166, 233.
14. (d) Devereux, M.; McCann, M.; Casey, M. T.; Curran, M.; Ferguson, G.; Cardin, C.; Convery, M.; Quillet, V. J. Chem. Soc., Dalton Trans. 1995, 771.
15. (e) Wemple, M. W.; Tsai, H.-L.; Wang, S.; Claude, J. P.; Streib, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1996, 35, 6437.
16. (f) Tangoulis, V.; Psomas, G.; Dendrinou-Samara, C.; Raptopoulou, C. P.; Terzis, A.; Kessissoglou, D. P. Inorg. Chem. 1996, 35, 7655.
17. (a) Kessissoglou, D. P.; Kirk, M. L.; Lah, M. S.; Li, X.; Raptopoulou, C.; Hatfield, W. E.; Pecoraro, V. L. Inorg. Chem. 1992, 31, 5424.
18. (b) Darovsky, A.; Kezerashvili, V.; Coppens, P.; Weyhermueller, T.; Hummel, H.; Weighardt, K. Inorg. Chem. 1996, 35, 6916.
19. (c) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708.
20. (d) Oshio, H.; Ino, E.; Mogi, I.; Ito, T. Inorg. Chem. 1993, 32, 5697.
21. (e) Rardin, R. L.; Poganiuch, P.; Bino, A.; Goldberg, D. P.; Tolman, W. B.; Liu, S.; Lippard, S. J. J. Am. Chem. Soc. 1992, 114, 5240.
22. (f) Bhula, R.; Weatherburn, D. C. Angew. Chem., Int. Ed. Engl. 1991, 30, 688.
23. (g) Chen, X.-M.; Tong, Y.-X.; Xu, Z.-T.; Mak, T. C. W. J. Chem. Soc., Dalton Trans. 1995, 4001.
24. (h) Kitajima, N.; Osawa, M.; Tamura, N.; Moro-oka, Y.; Hirano, T.; Hirobe, M.; Nagano, T. Inorg. Chem. 1993, 32, 1879.
25. (i) Caneschi, A.; Ferraro, F.; Gatteschi, D.; Melandri, M. C.; Rey, P.; Sessoli, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1365.
26. (j) Huebner, K.; Roesky, H. W.; Noltemeyer, M.; Bohra, R. Chem. Ber. 1991, 124, 515.
27. (k) Ménage, S.; Vitols, S. E.; Bergerat, P.; Codjovi, E.; Kahn, O.; Girerd, J.-J.; Guillot, M.; Solans, X.; Calvet, T. Inorg. Chem. 1991, 30, 2666.
28. (l) Matsushima, H.; Ishiwa, E.; Koikawa, M.; Nakashima, M.; Tokii, T. Chem. Lett. 1995, 129.
29. (m) Reynolds, R. A., III; Yu, W. O.; Dunham, W. R.; Coucouvanis, D. Inorg. Chem. 1996, 35, 2721.
30. (n) Wu, F.-J.; Kurtz, D. M., Jr.; Hagen, K. S.; Nyman, P. D.; Debrunner, P. G.; Vankai, V. A. Inorg. Chem. 1990, 29, 5174.
31. (o) Dave, B. C.; Czernuszewicz, R. S.; Bond, M. R.; Carrano, C. J. Inorg. Chem. 1993, 32, 3593.
32. (p) Corbella, M.; Costa, R.; Ribas, J.; Fries, P. H.; Latour, J.-M.; Öhrström, L.; Solans, X.; Rodrîguez, V. Inorg. Chem. 1996, 35, 1857.
33. (q) Hulme, C. E.; Watkinson, M.; Haynes, M.; Pritchard, R. G.; McAuliffe, C. A.; Jaiboon, N.; Beagley, B.; Sousa, A.; Bermejo, M. R.; Fondo, M. J. Chem. Soc., Dalton Trans. 1997, 1805.
34. (a) Mikuriya, M.; Hashimoto, Y.; Kawamori, A. Chem. Lett. 1995, 1095.
35. (b) Pal, S.; Armstrong, W. H. Inorg. Chem. 1992, 31, 5417.
36. (c) Suzuki, M.; Sugisawa, T.; Senda, H.; Oshio, H.; Uehara, A. Chem. Lett. 1989, 1091.
37. (d) Higuchi, C.; Sakiyama, H.; Okawa, H.; Isobe, R.; Fenton, D. E. J. Chem. Soc., Dalton Trans. 1994, 1097.
38. (e) Gultneh, Y.; Ahvazi, B.; Khan, R.; Butcher, R.; Tuchagues, J. P. Inorg. Chem. 1995, 34, 3633.
39. (f) Nagata, T.; Mizukami, J. J. Chem. Soc., Dalton Trans. 1995, 2825.
40. (g) Gultneh, Y.; Farooq, A.; Liu, S.; Karlin, K. D.; Zubieta, J. Inorg. Chem. 1992, 31, 3607.
41. (h) Buchanan, R. M.; Oberhausen, K. J.; Richardson, J. F. Inorg. Chem. 1988, 27, 971.
42. (i) Downard, A. J.; McKee, V.; Tandon, S. S. Inorg. Chim. Acta 1990, 173, 181.
43. (a) Saalfrank, R. W.; Stark, A.; Bremer, M.; Hummel, H.-U. Angew. Chem., Int. Ed. Engl. 1990, 29, 311.
44. (b) Cano, J.; DeMunno, G.; Sanz, J.; Ruiz, R.; Lloret, F.; Faus, J.; Julve, M. J. Chem. Soc., Dalton Trans. 1994, 3465.
45. (c) Glerup, J.; Goodson, P. A.; Hodgson, D. J.; Michelsen, K. Inorg. Chem. 1995, 34, 6255.
46. (a) Bashkin, J. S.; Schake, A. R.; Vincent, J. B.; Chang, H.-R.; Li, Q.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun. 1988, 700.
47. (b) Wemple, M. W.; Tsai, H.-L.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1993, 32, 2025.
48. (a) Richards, S.; Pedersen, B.; Silverton, J. B.; Hoard, J. L.Inorg. Chem. 1964, 3, 27.
49. (b) Nakasuka, N.; Azuma, S.; Katayama, C.; Honda, M.; Tanaka, J.; Tanaka, M. Acta Crystallogr. 1985, C41, 1176.
50. (c) Suzuki, M.; Senda, H.; Kobayashi, Y.; Oshio, H.; Uehara, A. Chem. Lett. 1988, 1763.
51. (d) Rockage, S. M.; Sheffer, S. H.; Cacheris, W. P.; Quay, S. C.; Hahn, F. E.; Raymond, K. N. Inorg. Chem. 1988, 27, 3530.
52. (e) Stilbrany, R. T.; Gorun, S. M. Angew. Chem., Int. Ed. Engl. 1990, 29, 1156.
53. (f) Inoue, M. B.; Villegas, C. A.; Asano, K.; Nakamura, M.; Inoue, M.; Fernando, Q. Inorg. Chem. 1992, 31, 2480.
54. (g) Tanase, T.; Lippard, S. J. Inorg. Chem. 1995, 34, 4682.
55. (a) Cox, D. D.; Benkovic, S. J.; Bloom, L. M.; Bradley, F. C.; Nelson, M. J.; Que, L., Jr.; Wallick, D. E. J. Am. Chem. Soc. 1988, 110, 2026.
56. (b) Cox, D. D.; Que, L., Jr. J. Am. Chem. Soc. 1988, 110, 8085.
57. (c) Menage, S.; Fujii, H.; Hendrich, M. P.; Que, L., Jr. Angew. Chem., Int. Ed. Engl. 1994, 33, 1660.
58. Abufarag, A.; Vahrenkamp, H. Inorg. Chem. 1995, 34, 2207.
59. (a) Hazel, A.; Jensen, K. B.; McKenzie, C. J.; Toftlund, H. J. Chem. Soc., Dalton Trans. 1993, 3249.
60. (b) Andersen, U. N.; McKenzie, C. J.; Bojesen, G. Inorg. Chem. 1995, 34, 1435.
61. TEXSAN, Crystal Structure Analysis Package; Molecular Structure Corporation: The Woodlands, Texas, 1985, 1992.
62. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1974.
63. (a) Pascal, P. Ann. Chim. Phys. 1910, 19, 5.
64. (b) Pacault, A.; Hoarau, J.; Marchand, A. Adv. Chem. Phys. 1961, 3, 171.
65. Perrin, D. D.; Armarego, W. L. F. Purification of Laboratory Chemicals, 3rd ed.; Pergamon Press: New York, 1988; p 68.
66. Burnett, M. N.; Johnson, C. K. ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations; Oak Ridge National Laboratory Report ORNL-6895; Oak Ridge National Laboratory: Oak Ridge, TN, 1996.
67. (a) Drew, M. G. B.; Othman, A. H. B.; McFall, S. G., McIlroy, P. D. A.; Nelson, S. M. J. Chem. Soc., Dalton Trans. 1977, 438.
68. (b) Drew, M. G. B.; Othman, A. H. B.; McFall, S. G.; McIlroy, P. D. A.; Nelson, S. N. J. Chem. Soc., Dalton Trans. 1977, 1173.
69. (c) Palenik, G. J.; Wester, D. W. Inorg. Chem. 1978, 17, 864.
70. (d) Pelizzi, C.; Pelizzi, G.; Tarasconi, P. J. Chem. Soc., Dalton Trans. 1985, 215.
71. (e) Capparelli, M. V.; de Meester, P.; Goodgame, D. M. L.; Gunn, S. J.; Skapski, A. C. Inorg. Chim. Acta 1985, 97, L37.
72. (f) Brooker, S.; McKee, V. J. Chem. Soc., Dalton Trans. 1990, 2397.
73. (g) Bailey, N. A.; Fenton, D. E.; Kitchen, S. J.; Lilley, T. H.; Williams, M. G.; Tasker, P. A.; Leong, A. J.; Lindoy, L. F. J. Chem. Soc., Dalton Trans. 1991, 2989.
74. (h) Brooker, S.; McKee, V. Acta Crystallogr. 1993, C49, 441.
75. (a) Cockman, R. W.; Hoskins, B. F.; McCormick, M. J.; O'Donnell, T. A. Inorg. Chem. 1988, 27, 2742.
76. (b) Gon, S. G.; You, X.; Yu, K.; Lu, J. Inorg. Chem. 1993, 32, 1883.
77. (c) Inoue, M. B.; Navarro, R. E.; Inoue, M.; Fernando, Q. Inorg. Chem. 1995, 34, 6074.
78. (d) Brooker, S.; Kelly, R. J. J. Chem. Soc., Dalton Trans. 1996, 2117.
79. (e) Deroche, A.; Morgenstern-Badaran, I.; Cesario, M.; Gailhem, J.; Keita, B.; Nadjo, L.; Houée-Levin, C. J. Am. Chem. Soc. 1996, 118, 4567.
80. (f) Mikuriya, M.; Hatano, Y.; Asato, E. Chem. Lett. 1996, 849.
81. (g) Oki, A. R.; Gogineni, P.; Yurchenko, M.; Yound, V. G., Jr. Inorg. Chim. Acta 1997, 257, 279.
82. References 21-26 are classified by the nature of the ligands employed. Bidentate ligands: (a) Plaskin, P. M.; Stoufer, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121. (b) Cooper, S. R.; Dismukes, G. C.; Klein, M. P.; Calvin, M. J. Am. Chem. Soc. 1978, 100, 7248. (c) Stebler, M.; Ludi, A.; Bürgi, H.-B. Inorg. Chem. 1986, 25, 4743. (d) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037.
83. References 21-26 are classified by the nature of the ligands employed. Bidentate ligands: (a) Plaskin, P. M.; Stoufer, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121. (b) Cooper, S. R.; Dismukes, G. C.; Klein, M. P.; Calvin, M. J. Am. Chem. Soc. 1978, 100, 7248. (c) Stebler, M.; Ludi, A.; Bürgi, H.-B. Inorg. Chem. 1986, 25, 4743. (d) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037.
84. References 21-26 are classified by the nature of the ligands employed. Bidentate ligands: (a) Plaskin, P. M.; Stoufer, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121. (b) Cooper, S. R.; Dismukes, G. C.; Klein, M. P.; Calvin, M. J. Am. Chem. Soc. 1978, 100, 7248. (c) Stebler, M.; Ludi, A.; Bürgi, H.-B. Inorg. Chem. 1986, 25, 4743. (d) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037.
85. References 21-26 are classified by the nature of the ligands employed. Bidentate ligands: (a) Plaskin, P. M.; Stoufer, R. C.; Mathew, M.; Palenik, G. J. J. Am. Chem. Soc. 1972, 94, 2121. (b) Cooper, S. R.; Dismukes, G. C.; Klein, M. P.; Calvin, M. J. Am. Chem. Soc. 1978, 100, 7248. (c) Stebler, M.; Ludi, A.; Bürgi, H.-B. Inorg. Chem. 1986, 25, 4743. (d) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 1989, 28, 4037.
86. Tridentate ligands: (a) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651. (b) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398. (c) Bossek, U.; Weyhermuller, T.; Wieghardt, K.; Nuber, B.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387. (d) Niemann, A.; Bossek, U.; Wieghardt, K.; Butzlaff, C.; Trautwein, A. X.; Nuber, B. Angew. Chem., Int. Ed. Engl. 1992, 31, 311. (e) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708.
87. Tridentate ligands: (a) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651. (b) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398. (c) Bossek, U.; Weyhermuller, T.; Wieghardt, K.; Nuber, B.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387. (d) Niemann, A.; Bossek, U.; Wieghardt, K.; Butzlaff, C.; Trautwein, A. X.; Nuber, B. Angew. Chem., Int. Ed. Engl. 1992, 31, 311. (e) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708.
88. Tridentate ligands: (a) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651. (b) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398. (c) Bossek, U.; Weyhermuller, T.; Wieghardt, K.; Nuber, B.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387. (d) Niemann, A.; Bossek, U.; Wieghardt, K.; Butzlaff, C.; Trautwein, A. X.; Nuber, B. Angew. Chem., Int. Ed. Engl. 1992, 31, 311. (e) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708.
89. Tridentate ligands: (a) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651. (b) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398. (c) Bossek, U.; Weyhermuller, T.; Wieghardt, K.; Nuber, B.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387. (d) Niemann, A.; Bossek, U.; Wieghardt, K.; Butzlaff, C.; Trautwein, A. X.; Nuber, B. Angew. Chem., Int. Ed. Engl. 1992, 31, 311. (e) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708.
90. Tridentate ligands: (a) Wieghardt, K.; Bossek, U.; Zsolnai, L.; Huttner, G.; Blondin, G.; Girerd, J.-J.; Babonneau, F. J. Chem. Soc., Chem. Commun. 1987, 651. (b) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398. (c) Bossek, U.; Weyhermuller, T.; Wieghardt, K.; Nuber, B.; Weiss, J. J. Am. Chem. Soc. 1990, 112, 6387. (d) Niemann, A.; Bossek, U.; Wieghardt, K.; Butzlaff, C.; Trautwein, A. X.; Nuber, B. Angew. Chem., Int. Ed. Engl. 1992, 31, 311. (e) Pal, S.; Olmstead, M. M.; Armstrong, W. H. Inorg. Chem. 1995, 34, 4708.
91. Tetradentate ligands, aliphatic amines: (a) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967. (b) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 1989, 28, 4446. (c) Goodson, P. A.; Hodgson, D. J.; Michelson, K. Inorg. Chim. Acta 1990, 172, 49.
92. Tetradentate ligands, aliphatic amines: (a) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967. (b) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 1989, 28, 4446. (c) Goodson, P. A.; Hodgson, D. J.; Michelson, K. Inorg. Chim. Acta 1990, 172, 49.
93. Tetradentate ligands, aliphatic amines: (a) Hagen, K. S.; Armstrong, W. H.; Hope, H. Inorg. Chem. 1988, 27, 967. (b) Brewer, K. J.; Calvin, M.; Lumpkin, R. S.; Otvos, J. W.; Spreer, L. O. Inorg. Chem. 1989, 28, 4446. (c) Goodson, P. A.; Hodgson, D. J.; Michelson, K. Inorg. Chim. Acta 1990, 172, 49.
94. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
95. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
96. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
97. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
98. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
99. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
100. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
101. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
102. Tetradentate ligands, aromatic amines: (a) Collins, M. A.; Hodgson, D. J.; Michelsen, K.; Towle, D. K. J. Chem. Soc. Chem. Commun. 1987, 1659. (b) Suzuki, M.; Tokura, S.; Suhara, M.; Uehara, A. Chem. Lett. 1988, 477. (c) Towle, D. K.; Botsford, C. A.; Hodgson, D. J. Inorg. Chim. Acta 1988, 141, 167. (d) Goodson, P. A.; Hodgson, D. J. Inorg. Chem. 1989, 28, 3606. (e) Goodson, P. A.; Oki, A. R.; Glerup, J.; Hodgson, D. J. J. Am. Chem. Soc. 1990, 112, 6248. (f) Oki, A, R,; Glerup, J.; Hodgson, D. J. Inorg. Chem. 1990, 29, 2435. (g) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Pedersen, E. Inorg. Chem. 1990, 29, 503. (h) Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Weihe, H. Inorg. Chem. 1991, 30, 4909. (i) Frapart, Y.-M.; Boussac, A.; Albach, R.; Anxolabéhère-Mallart, E.; Delroisse, M.; Verlhac, J.-B.; Blondin, G.; Girerd, J.-J.; Guilhem, J.; Cesario, M.; Rutherford, A. W.; Lexa, D. J. Am. Chem. Soc. 1996, 118, 2669.
103. Schiff-base ligands: (a) Miller, J. D.; Oliver, D. J. Inorg. Nucl. Chem. 1972, 34, 1873. (b) Maslen, H. S.; Waters, T. N. J. Chem. Soc. Chem. Commun. 1973, 760. (c) McAuliffe, C. A.; Parish, R. V.; Abu-El-Wafa, S. M.; Issa, R. M. Inorg. Chim. Acta 1986, 115, 91. (d) Larson, E. J.; Pecoraro, V. L. J. Am. Chem. Soc. 1991, 113, 3810.
104. Schiff-base ligands: (a) Miller, J. D.; Oliver, D. J. Inorg. Nucl. Chem. 1972, 34, 1873. (b) Maslen, H. S.; Waters, T. N. J. Chem. Soc. Chem. Commun. 1973, 760. (c) McAuliffe, C. A.; Parish, R. V.; Abu-El-Wafa, S. M.; Issa, R. M. Inorg. Chim. Acta 1986, 115, 91. (d) Larson, E. J.; Pecoraro, V. L. J. Am. Chem. Soc. 1991, 113, 3810.
105. Schiff-base ligands: (a) Miller, J. D.; Oliver, D. J. Inorg. Nucl. Chem. 1972, 34, 1873. (b) Maslen, H. S.; Waters, T. N. J. Chem. Soc. Chem. Commun. 1973, 760. (c) McAuliffe, C. A.; Parish, R. V.; Abu-El-Wafa, S. M.; Issa, R. M. Inorg. Chim. Acta 1986, 115, 91. (d) Larson, E. J.; Pecoraro, V. L. J. Am. Chem. Soc. 1991, 113, 3810.
106. Schiff-base ligands: (a) Miller, J. D.; Oliver, D. J. Inorg. Nucl. Chem. 1972, 34, 1873. (b) Maslen, H. S.; Waters, T. N. J. Chem. Soc. Chem. Commun. 1973, 760. (c) McAuliffe, C. A.; Parish, R. V.; Abu-El-Wafa, S. M.; Issa, R. M. Inorg. Chim. Acta 1986, 115, 91. (d) Larson, E. J.; Pecoraro, V. L. J. Am. Chem. Soc. 1991, 113, 3810.
107. (e) Gohdes, J. W.; Armstrong, W. H. Inorg. Chem. 1992, 31, 368.
108. (f) Larson, E.; Lah, M. S.; Li, X.; Bonadies, J. A.; Pecoraro, V. L. Inorg. Chem. 1992, 31, 373.
109. (g) Dailey, G. C.; Horwitz, C. P.; Lisek, C. A. Inorg. Chem. 1992, 31, 5325.
110. (h) Torayama, H.; Nishide, T.; Asada, H.; Fujiwara, M.; Matsushita, T. Chem. Lett. 1996, 387.
111. Hexadentate ligands: Pal, S.; Gohdes, J. W.; Wilisch, W. C. A.; Armstrong, W. H. Inorg. Chem. 1992, 31, 713.
112. Smart, J. S. Effective Field Theories of Magnetism; W. B. Saunders Co.: Philadelphia, 1966.
113. Since the structure of 3 contains two independent manganese ions, there are two structurally different Mn-Mn pairs, namely Mn(1)-Mn(2) and Mn(2)-Mn(1*). We assume here that the exchange integrals for these two pairs are identical. This would be a good approximation for the simple calculation employed here, because the Mn-Mn distances are similar (5.376(4) and 5.282(4) Å).
114. 27 This requirement is fulfilled for T > 30 K.
115. (a) Mikuriya, M.; Fujii, T.; Kamisawa, S.; Kawasaki, Y.; Tokii, T.; Oshio, H. Chem. Lett. 1990, 1181.
116. (b) Sakiyama, H.; Tamaki, H.; Kodera, M.; Matsumoto, N.; Okawa, H. J. Chem. Soc., Dalton Trans. 1993, 591.
117. (c) Bossek, U.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chim. Acta 1989, 165, 123.
118. (d) Yu, S.-B.; Lippard, S. J.; Shweky, I.; Bino, A. Inorg. Chem. 1992, 31, 3502.
119. (e) Wieghardt, K.; Bossek, U.; Nuber, B.; Weiss, J.; Bonvoisin, J.; Corbella, M.; Vitols, S. E.; Girerd, J. J. J. Am. Chem. Soc. 1988, 110, 7398.
120. We are grateful to one of the reviewers for advising us to obtain an EPR spectrum of 4.
121. Wang, K.; Mayer, J. M. J. Am. Chem. Soc. 1997, 119, 1470.
122. Baldwin, M. J.; Pecoraro, V. L. J. Am. Chem. Soc. 1996, 118, 11325.