Reaction mechanism and chemoselectivity of intermolecular cycloaddition reactions between phenyl-substituted cyclopropenone ketal and methyl vinyl ketone

Journal of Organic Chemistry

Volumn 76, Issue 9, 2011, Pages 3086-3095

  Qiao, Yan ^a   Chu, Tian Shu ^a,b  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b QINGDAO UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

B3LYP/6-31G; CHARGE ANALYSIS; CHEMO-SELECTIVITY; CYCLOADDITION REACTION; CYCLOADDUCTS; ELECTRON-DEFICIENT; EXPERIMENTAL CONDITIONS; FIVE-MEMBERED RINGS; INTERMOLECULAR CYCLOADDITION; METHYL VINYL KETONES; NATURAL BOND ORBITAL; PCM MODEL; REACTION MECHANISM; REACTION PATHWAYS; REACTION SOLVENTS; RELATIVE REACTIONS; SECOND ORDERS; SOLVENT EFFECTS; STEPWISE REACTION;

BENZENE; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; KETONES; SOLVENTS; TOLUENE;

CYCLOADDITION;

ACETAL; BENZENE; CARBENE; CARBON; HYDROGEN; KETONE DERIVATIVE; METHYL GROUP; OXYGEN; PHENYL GROUP; SOLVENT; TOLUENE;

ARTICLE; CHEMICAL BOND; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; ELECTRON; ENERGY; REACTION ANALYSIS; SUBSTITUTION REACTION;

EID: 79955570597     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo102454y     Document Type: Article

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