Cleavage of carbon-carbon bonds through the mild release of trifluoroacetate: Generation of α,α-difluoroenolates for aldol reactions

Journal of the American Chemical Society

Volumn 133, Issue 15, 2011, Pages 5802-5805

  Han, Changho ^a   Kim, Eun Hoo ^a   Colby, David A ^a,b  

^a PURDUE UNIVERSITY   (United States)

^b PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDOL REACTIONS; BUILDING BLOCKES; C-C BONDS; CARBON-CARBON BOND; MILD REACTION CONDITIONS; REACTIVE INTERMEDIATE; SMALL GROUPS; SYNTHETIC CHEMISTRY; TRIFLUOROACETATES;

CONDENSATION REACTIONS;

CHEMICAL BONDS;

ALPHA,ALPHA DIFLUOROENOLATE; CARBENE; CARBON; FLUORINE DERIVATIVE; TRIFLUOROACETIC ACID; UNCLASSIFIED DRUG;

ALDOL REACTION; ARTICLE; CHEMICAL BOND; FLUORINATION; SYNTHESIS;

ALDEHYDES; CARBON; TRIFLUOROACETIC ACID;

EID: 79954517011     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja202213f     Document Type: Article

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