New selective haloform-type reaction yielding 3-hydroxy-2,2-difluoroacids: Theoretical study of the mechanism

Journal of the American Chemical Society

Volumn 127, Issue 8, 2005, Pages 2620-2627

  Olivella, Santiago ^a   Solé, Albert ^b   Jiménez, Oscar ^a   Bosch, M Pilar ^a   Guerrero, Angel ^a  

^a DEPARTMENT OF ENVIRONMENTAL CHEMISTRY   (Spain)

^b UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CARBOXYLIC ACIDS; CHARGE TRANSFER; COMPLEXATION; HYDROGEN BONDS; KETONES; PROBABILITY DENSITY FUNCTION; REACTION KINETICS; SOLVENTS;

3-HYDROXY-2,2-DIFLUOROACIDS; BOND CLEAVAGE; FLUOROFORM; SOLVENT-INDUCED EFFECTS;

HALOGEN COMPOUNDS;

1,1,1,3,3 PENTAFLUORO 4 HYDROXYPENTAN 2 ONE; 3 HYDROXY 2,2 DIFLUOROACID; 4 HYDROXY 3,3 DIFLUOROMETHYL KETONE; FLUORINE DERIVATIVE; HYDROXIDE; KETONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL BOND; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; HYDROGEN BOND; PHASE TRANSITION; REACTION ANALYSIS;

EID: 84962449131     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja043522d     Document Type: Article

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