Homogeneous palladium catalyst suppressing Pd black formation in air oxidation of alcohols

Journal of the American Chemical Society

Volumn 126, Issue 21, 2004, Pages 6554-6555

  Iwasawa, Tetsuo ^a   Tokunaga, Makoto ^a   Obora, Yasushi ^a   Tsuji, Yasushi ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; DENDRIMER; PALLADIUM; PYRIDINE DERIVATIVE; TOLUENE;

AIR ANALYSIS; ARTICLE; CATALYST; CHEMICAL STRUCTURE; DECOMPOSITION; OXIDATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 2542558084     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja031936l     Document Type: Article

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33. 2 as that in run 2 in Table 1 led to observation of complete Pd black formation within 2 h (S/C = 1000, run 2 in Table 1), 3 h (S/C = 700), 5 h (S/C = 400), and 7 h (S/C = 100), but no Pd black formation was observed with S/C = 50.
34. Such a "long-range steric effect" was also observed in a rhodium-catalyzed hydrosilylation of ketones with a bowl-shaped phoshine.15
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