Asymmetric synthesis of α-methyl-α-amino acids via diastereoselective alkylation of (1s)-(+)-3-carene derived tricyclic iminolactone

Journal of Organic Chemistry

Volumn 76, Issue 6, 2011, Pages 1621-1633

  Lu, Ta Jung ^a   Lin, Cheng Kun ^a  

^a NATIONAL CHUNG HSING UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC SYNTHESIS; BASIC HYDROLYSIS; CHIRAL AUXILIARIES; DEPROTECTION; DIASTEREOSELECTIVE ALKYLATION; DIASTEREOSELECTIVITIES; DOUBLE BONDS; ELECTROPHILES; HIGH REACTIVITY; HIGH YIELD; ISOLATED YIELD; PHASE TRANSFER CATALYSIS; ROOM TEMPERATURE; SECONDARY ALCOHOLS; STEREOSELECTIVE DIHYDROXYLATION; TERTIARY ALCOHOLS;

ALKYLATION; AMINO ACIDS; ESTERIFICATION; ESTERS; STEREOSELECTIVITY;

ORGANIC POLYMERS;

3 (4 METHOXYBENZYL) 5,5A,6,6A,7,7A HEXAHYDRO 3,6,6,7A TETRAMETHYLBICYCLO[4.1.0]HEPT 1(6) ENO[3,4 B][1,4]OXAZIN 2(3H) ONE; 3 (4 NITROBENZYL) 5,5A,6,6A,7,7A HEXAHYDRO 3,6, 6,7A TETRAMETHYLBICYCLO[4.1.0]HEPT 1(6) ENO[3,4 B][1,4]OXAZIN 2(3H) ONE; 3 BENZYL 5,5A,6,6A,7,7A HEXAHYDRO 3,6,6,7A TETRAMETHYLBICYCLO[4.1.0]HEPT 1(6) ENO[ 3,4 B][1,4]OXAZIN 2(3H) ONE; 3 CARENE; 4 HYDROXY 4,7,7 TRIMETHYLBICYCLO[4.1.0]HEPTAN 3 ONE; 5,5A,6,6A,7,7A HEXAHYDRO 3,6,6,7A TETRAMETHYLBICYCLO [4.1.0]HEPT 1(6) ENO[3,4 B][1,4]OXAZIN 2(3H) ONE; ALANINE; ALCOHOL; ALKYLATING AGENT; AMINO ACID DERIVATIVE; ELECTROPHILE; ESTER; IMINOLACTONE; LACTONE DERIVATIVE; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; ASYMMETRIC SYNTHESIS; CATALYSIS; CHEMICAL BOND; CHIRALITY; CYCLIZATION; DEPROTECTION REACTION; DIASTEREOISOMER; DIHYDROXYLATION; DRUG SYNTHESIS; ESTERIFICATION; HYDROGENATION; HYDROLYSIS; OXIDATION; QUANTUM YIELD; ROOM TEMPERATURE; STEREOCHEMISTRY;

ALANINE; ALKYLATION; AMINO ACIDS; CATALYSIS; HETEROCYCLIC COMPOUNDS, 3-RING; LACTONES; MONOTERPENES; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

EID: 79953887255     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1022537     Document Type: Article

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