Enantioselective friedel-crafts alkylation of indoles with trifluoroethylidene malonates by copper-bis(oxazoline) complexes: Construction of trifluoromethyl-substituted stereogenic tertiary carbon center

Journal of Organic Chemistry

Volumn 76, Issue 7, 2011, Pages 2282-2285

  Wen, Lele ^a   Shen, Qilong ^a   Wan, Xiaolong ^a   Lu, Long ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC REACTIONS; COPPER (II); ENANTIOSELECTIVE; ENANTIOSELECTIVE ALKYLATION; FRIEDEL-CRAFTS ALKYLATION; MALONATES; OXAZOLINES; SYNTHETIC UTILITY; TRIFLUOROMETHYL; TRIFLUOROMETHYL GROUP;

ALKYLATION; AMINO ACIDS; CATALYSIS; NITROGEN COMPOUNDS; ORGANIC POLYMERS;

COPPER COMPOUNDS;

CARBOLINE DERIVATIVE; CARBON; COPPER BIS(OXAZOLINE) DERIVATIVE; COPPER DERIVATIVE; DIETHYL 2 [2,2,2 TRIFLUORO 1 (1H INDOL 3 YL)ETHYL]MALONATE; INDOLE DERIVATIVE; MALONIC ACID DERIVATIVE; OXAZOLINE DERIVATIVE; TRIFLUOROETHYLIDENE MALONATE; TRYPTOPHAN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; COMPLEX FORMATION; CYCLIZATION; DIASTEREOISOMER; ELECTRON TRANSPORT; ENANTIOSELECTIVITY; FRIEDEL CRAFTS REACTION; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKYLATION; CARBON; CATALYSIS; COPPER; HYDROCARBONS, FLUORINATED; INDOLES; MALONATES; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 79953207675     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1024333     Document Type: Article

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