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Crystal data for 3a: C19H20F6O 6, Mr, 458.4, triclinic, Pl̄, a, 9.6109(12) Å, b, 11.0995(14) Å, c, 11.2859(14) Å, α, 99.188(2)°, β, 113.528(2)°, γ, 105.054(2)°, V, 1017.7(2) Å3, Z, 2, T, 150 K, R(F, F2>2σ, 0.0480, Rw(F2, all data, 0.1571, using data from a twinned crystal, b) Crystal data for 3b: C19H19ClF 6O6, Mr, 492.8, monoclinic, P21/n, a= 11.715(3) Å,b= 11.8054(15) Å, c, 16.619(4) Å,β, 108.851(18)°,V, 2175.0(8)Å3, Z, 4, T=150K, R(F, F 2 > 1σ, 0.0498, RwF2, all data, 0.1462
-
2, all data) = 0.1462.
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36749098912
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Full details of the analysis have been provided in the Supporting Information
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Full details of the analysis have been provided in the Supporting Information.
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55
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1)) = kt. Laidler, K. J. Chemical Kinetics, 3rd ed.; Harper & Row: New York, 1987.
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