Extreme N≡N bond elongation and facile N-atom functionalization reactions within two structurally versatile new families of group 4 bimetallic "side-on-bridged" dinitrogen complexes for zirconium and hafnium

Journal of the American Chemical Society

Volumn 129, Issue 42, 2007, Pages 12690-12692

  Hirotsu, Masakazu ^a   Fontaine, Philip P ^a   Zavalij, Peter Y ^a   Sita, Lawrence R ^a  

^a Bldg 142   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDINE; GRAPHITE; GUANIDINE DERIVATIVE; HAFNIUM; METAL COMPLEX; NITROGEN; ZIRCONIUM DERIVATIVE;

ARTICLE; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTALLOGRAPHY; GEOMETRY; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; REDUCTION; SOLID STATE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

EID: 35548959637     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0752989     Document Type: Article

References (31)

1. For recent reviews, see: (a) Hidai, M.; Mizobe, Y. Chem. Rev. 1995, 95, 1115.
2. (b) Gambarotta, S.; Scott, J. Angew. Chem., Int. Ed. 2004, 43, 5298.
3. (c) MacLachlan, E. A.; Fryzuk, M. D. Organometallics 2006, 25, 1530.
4. (d) Ohki, Y.; Fryzuk, M. D. Angew. Chem., Int. Ed. 2007, 46, 3180.
5. (e) Chirik, P. J. Dation Trans. 2007, 16.
6. (a) Fryzuk, M. D.; Love, J. B.; Rettig, S. J.; Young, V. G. Science 1997, 275, 1445.
7. (b) Maclachlan, E.; Hess, F. M.; Patrick, B. O.; Fryzuk, M. D. J. Am. Chem. Soc. 2007, 129, 10895 and references cited therein.
8. (a) Pool, J. A.; Lobkovsky, E.; Chirik, P. J. Nature 2004, 427, 527.
9. (b) Hanna, T. E.; Keresztes, I.; Lobkovsky, E.; Chirik, P. J. Inorg. Chem. 2007, 46, 1675 and references cited therein.
10. (a) Fryzuk, M. D.; Haddad, T. S.; Mylvaganam, M.; McConville, D. H.; Rettig, S. J. J. Am. Chem. Soc. 1993, 115, 2782.
11. (b) Basch, H.; Musaev, D. G.; Morokuma, K.; Fryzuk, M. D.; Love, J. B.; Seidel, W. W.; Albinati, A.; Koetzle, T. F.; Klooster, W. T.; Mason, S. A.; Eckert, J. J. Am. Chem. Soc. 1999, 121, 523.
12. (c) Studt, F.; Morello, L.; Lehnen, N.; Fryzuk, M. D.; Tuczek, F. Chem. - Eur. J. 2003, 9, 520.
13. (d) Pool, J. A.; Bernskoetter, W. H.; Chirik, P. J. J. Am. Chem. Soc. 2004, 126, 14326.
14. (e) Bobadova-Parvanova, P.; Wang, Q. F.; Morokuma, K.; Musaev, D. G. Angew. Chem., Int. Ed. 2005, 44, 7101.
15. (f) Yates, B. F.; Basch, H.; Musaev, D. G.; Morokuma, K. J. Chem. Theory Comput. 2006, 2, 1298.
16. (g) Bobadova-Parvanova, P.; Wang, Q. F.; Quinonero-Santiago, D.; Morokuma, K.; Musaev, D. G. J. Am. Chem. Soc. 2006, 128, 11391.
17. (h) Musaev, D. G.; Bobadova-Parvanova, P.; Morokuma, K. Inorg. Chem. 2007, 46, 2709.
18. Details are provided in the Supporting Information.
19. (a) Wilkinson, P. G.; Houk, N. B. J. Chem. Phys. 1956, 24, 528.
20. (b) Sutton, L. E., Ed. Tables of Interatomic Distances and Configurations in Molecules and Ion; Chemical Society Special Publications, The Chemical Society: London, 1958; Vol. 11.
21. 4 and experimentally observed once for bimetallic complexation. See: Bernskoetter, W. H.; Olmos, A. V.; Lobkovsky, E.; Chirik, P. J. Organometallics 2006, 25, 1021 and references cited therein.
22. 2-Ni)}[Na]). See: Guillemot, G.; Castellano, B.; Prangé, T.; Solari, E.; Floriani, C. Inorg. Chem. 2007, 46, 5152.
23. (a) Fryzuk, M. D.; Haddad, T. S.; Rettig, S. J. J. Am. Chem. Soc. 1990, 112, 8185.
24. (b) Cohen, J. D.; Fryzuk, M. D.; Loehr, T. M.; Mylvaganam, M.; Rettig, S. J. Inorg. Chem. 1998, 37, 112.
25. Duchateau, R.; Gambarotta, S.; Beydoun, N.; Bensimon, C. J. Am. Chem. Soc. 1991, 113, 8986.
26. Hirotsu, M.; Fontaine, P. P.; Epshteyn, A.; Zavalij, P. Y.; Sita, L. R. J. Am. Chem. Soc. 2007, 129, 9284.
27. MacKay, B. A.; Munha, R. F.; Fryzuk, M. D. J. Am. Chem. Soc. 2006, 128, 9472.
28. Also see: Bernskoetter, W. H.; Olmos, A. V.; Pool, J. A.; Lobkovsky, E.; Chirik, P. J. J. Am. Chem. Soc. 2006, 128, 10696.
29. 2) complex with benzylbromide, see: Fryzuk, M. D.; Johnson, S. A.; Patrick, B. O.; Albinati, A.; Mason, S. A.; Koetzle, T. F. J. Am. Chem. Soc. 2001, 123, 3960.
30. (a) Chatt, J.; Leigh, G. J.; Head, R. A.; Pickett, C. J. J. Chem. Soc., Dalton Trans. 1978, 1638.
31. (b) Bossard, G. E.; Busby, D. C.; Chang, M.; George, T. A.; Iske, S. D. A., Jr. J. Am. Chem. Soc. 1980, 102, 1001.