Synthesis and protonolysis of tungsten- and molybdenum - Dinitrogen complexes bearing ruthenocenyldiphosphines

Organometallics

Volumn 28, Issue 16, 2009, Pages 4741-4746

  Yuki, Masahiro ^a   Midorikawa, Tatsuya ^a   Miyake, Yoshihiro ^a   Nishibayashi, Yoshiaki ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

DINITROGEN COMPLEXES; GOOD YIELD; PROTONOLYSIS; ROOM TEMPERATURE; RUTHENOCENES;

BEARINGS (STRUCTURAL); METHANOL; MOLYBDENUM; MOLYBDENUM COMPOUNDS; SULFURIC ACID; SYNTHESIS (CHEMICAL); TUNGSTEN;

TUNGSTEN COMPOUNDS;

EID: 68949191224     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900298g     Document Type: Article

References (82)

1. (a) Hudson, R. D. A. J. Organomet. Chem. 2001, 637-639, 47.
2. (b) Nishihara, H. Adv. Inorg. Chem. 2002, 53, 41.
3. (c) Nakamura, E. Pure Appl. Chem. 2003, 75, 421.
4. (d) van Staveren, D. R.; Metzler-Nolte, N. Chem. Rey. 2004, 104, 5931.
5. (e) Nakamura, E. J. Organomet. Chem. 2004, 689, 4630.
6. (f) J. Inorg. Organomet. Polym. Mater. 2005, 15(1) (the special issue celebrating the 50th anniversary of polyferrocenes).
7. (g) Fouda, M. F. R.; Abd-Elzaher, M. M.; Abdelsamaia, R. A.; Labib, A. A. Appl. Organomet. Chem. 2007, 21, 613.
8. (h) Gao, Y.; Shreeve, J. M. J. Inorg. Organomet. Polym. Mater. 2007, 17, 19.
9. (i) Seiwert, B.; Karst, U. Anal. Bioanal. Chem. 2008, 390, 181.
10. (a) Colacot, T. J. Chem. Rev. 2003, 103, 3101.
11. (b) Barbara, P.; Bianchini, C.; Giambastiani, G.; Parisel, S. L. Cooprd. Chem. Rev. 2004, 248, 2131.
12. (c) Gómez Arrayás, R.; Adrio, J.; Carretero, J. C. Angew. Chem., Int. Ed. 2006, 45, 7674.
13. (d) Film, A.; Meunier, P.; Hierso, J.-C. Cooprd. Chem. Rev. 2007, 251, 2017.
14. (a) Ferrocenes. Homogenous Catalysis, Organic Synthesis, Material Science; Togni, A., Hayashi, T., Eds.; VCH: Weinheim, Germany, 1995.
15. (b) Ferrocenes. Ligands, Materials and Biomolecules; Stepnicka, P., Ed.; Wiley: Sussex, England, 2008.
16. (a) Havashi, T.; Ohno, A.; Lu, S.; Matsumoto, Y.; Fukuvo, E.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 4221.
17. (b) Li, Sihai; Wei, B.; LOW, P. M. N.; Lee, H. K.; Hor, T. S. A.; Xue, F.; Mak, T. C. W. J. Chem. Soc., Dalton Trans. 1997, 1289.
18. (c) Hamann, B. C.; Hartwig, J. F. J. Am. Chem. Soc 1998, 120, 3694.
19. (d) Mendez, M.; Cuerva, J. M.; Gómez-Bengoa, E.; Cárdenas, D. J.; Echavarren, A. M. Chem. Eur, J. 2002, 8, 3620.
20. (e) Gusev, O. V.; Peganova, T. A.; Kalsin, A. M.; Vologdin, N. V.; Petrovskii, P. V.; Lyssenko, K. A.; Tsvetkov, A. V.; Beletskaya, I. P. Organometallics 2006, 25, 2750.
21. van Leeuwen, P. W. N. M.; Kamer, P. C. J.; Reek, J. N. H.; Dierkes, P. Chem. Rev. 2000, 100, 2741.
22. (a) Barlow, S.; Marder, S. R. Chem. Commun. 2000, 1555.
23. (b) Nataro, C.; Campbell, A. N.; Ferguson, M. A.; Incarvito, C. D.; Rheingold, A. L. J. Organomet. Chem. 2003, 673, 47.
24. (c) Gusev, O. V.; Peterleitner, M. G.; Kal'sin, A. M.; Vologdin, N. V. Russ, J. Electrochem. 2003, 39, 1293.
25. (d) Kinnibaugh, T. L.; Salman, S.; Getmanenko, Y. A.; Coropceanu, V.; Porter, W. W. III; Timofeeva, T. V.; Matzger, A. J.; Brédas, J.-L.; Marder, S. R.; Barlow, S. Organometallics 2009, 28, 1350.
26. Yuki, M.; Miyake, Y.; Nishibayashi, Y.; Wakiji, I.; Hidai, M. Organome tallics 2008, 27, 3947.
27. George, T. A.; Tisdale, R. C. J. Am. Chem. Soc. 1985, 107, 5157.
28. (a) Nishibayashi, Y.; Iwai, S.; Hidai, M. Science 1998, 279, 506.
29. (b) Nishibayashi, Y.; Takemoto, S.; Iwai, S.; Hidai, M. Inorg. Chem. 2000, 39, 5946.
30. (c) Nishibayashi, Y.; Saito, M.; Uemura, S.; Takekuma, S.; Takekuma, H.; Yoshida, Z. Nature 2004, 428, 279.
31. For recent reviews on dinitrogen fixation, see: (a) Hidai, M.; Mizobe, Y. Chem. Rev. 1995, 95, 1115.
32. (b) Gambarotta, S. J. Ormnomet. Chem. 1995, 500, 117.
33. (c) Fryzuk, M. D.; Johnson, S. A. Coord. Chem. Rev. 2000, 200-202, 379.
34. (d) MacKay, B. A.; Fryzuk, M. D. Chem. Rev. 2004, 104, 385.
35. (e) Gambarotta, S.; Scott, J. Angew. Chem., Int. Ed. 2004, 43, 5298.
36. (f) Hidai, M.; Mizobe, Y. Can, J. Chem. 2005, 83, 358.
37. (g) Himmel, H.-J.; Reiher, M. Angew. Chem., Int. Ed. 2006, 45, 6264.
38. For recent examples of dinitrogen complexes, see: (a) Yandulov, D. V.; Schrock, R. R. Science 2003, 301, 76.
39. (b) Pool, J. A.; Lobkovsky, E.; Chirik, P. J. Nature 2004, 427, 527.
40. (c) Curley, J. J.; Sceats, E. L.; Cummins, C. C. J. Am. Chem. Soc. 2006, 128, 14036.
41. (d) Smythe, N. C.; Schrock, R. R.; Muller, P.; Weare, W. W. Inorg. Chem. 2006, 45, 9197.
42. (e) Bart, S. C.; Chfopek, K.; Bill, E.; Bouwkamp, M. W.; Lobkovsky, E.; Neese, F.; Wieghardt, K.; Chirik, P. J. J. Am. Chem. Soc. 2006, 128, 13901.
43. (f) Mori, H.; Seino, H.; Hidai, M.; Mizobe, Y. Angew. Chem., Int. Ed. 2007, 46, 5431.
44. (g) Akagi, F.; Matsuo, T.; Kawaguchi, H. Angew. Chem., Int. Ed. 2007, 46, 8778.
45. (h) Scott, J.; Vidyaratne, I.; Korobkov, I.; Gambarotta, S.; Budzelaar, P. H. M. Inorg. Chem. 2008, 47, 896.
46. (i) Knobloch, D. J.; Toomey, H. E.; Chirik, P. J. J. AM Chem. Soc. 2008, 130, 4248.
47. (J) Morello, L.; Ferreira, M. J.; Patrick, B. O.; Fryzuk, M. D. Inorg. Chem. 2008, 47, 1319.
48. (k) Romer, R.; Stephan, G.; Habeck, C.; Hoberg, C.; Peters, G.; Näther. C.; Tuczek, F. Eur, J. Inorg. Chem. 2008, 3258.
49. 2] are given in the Supporting Information.
50. (a) Nordwig, B. L.; Ohlscn, D. J.; Beyer, K. D.; Brummer, J. G. Inorg. Chem. 2006, 45, 858.
51. (b) Hussain, W.; Leigh, G. J.; Mohd.-Ali, H.; Pickett, C. J.; Rankin, D. A. J. Chem. Soc, Dalton Trans. 1984, 1703.
52. (c) Chatt, J.; Pearman, A. J.; Richards, R. L. J. Chem. Soc, Dalton Trans. 1977, 2139.
53. (d) George, T. A.; DeBord, J. R. D.; Kaul, B. B.; Pickett, C. J.; Rose, D. J. Inorg. Chem. 1992, 31, 1295.
54. (e) Filippou, A. C.; Schnakenburg, G.; Philippopoulos, A. I.; Weidemann, N. Angew. Chem., Int. Ed. 2005, 44, 5979.
55. (f) George, T. A.; Noble, M. E. Inorg. Chem. 1978, 17, 1678.
56. (g) Lazarowych, N. J.; Morris, R. H.; Ressner, J. M. Inorg. Chem. 1986, 25, 3926.
57. 6): δ 4.4 (s).
58. (a) Chatt, J.; Heath, G. A.; Richards, R. L. J. Chem. Soc, Dalton Trans. 1974, 2074.
59. (b) Chatt, J.; Pearman, A. J.; Richards, R. L. Nature 1975, 253, 39.
60. (c) Chatt, J.; Pearman, A. J.; Richards, R. L. J. Chem. Soc, Dalton Trans. 1977, 1852.
61. (d) Hidai, M.; Mizobe, Y.; Takahashi, T.; Uchida, Y. Chem. Lett. 1978, 1187.
62. (e) Takahashi, T.; Mizobe, Y.; Sato, M.; Uchida, Y.; Hidai, M. J. Am. Chem. Soc. 1979, 101, 3405.
63. (f) Baumann, J. A.; George, T. A. J. Am. Chem. Soc. 1980, 102, 6153.
64. (g) George, T. A.; Kovar, R. A. Inorg. Chem. 1981, 20, 285.
65. (h) Anderson, S. N.; Fakley, M. E.; Richards, R. L.; Chatt, J. J. Chem. Soc., Dalton Trans. 1981, 1973.
66. (i) Bossard, G. E.; George, T. A.; Lester, R. K. Inorg. Chim. Acta 1982, 64, L227.
67. (j) Anderson, S. N.; Richards, R. L.; Hughes, D. L. J. Chem. Soc, Dalton Trans. 1986, 245.
68. (a) Heath, G. A.; Mason, R.; Thomas, K. M. J. Am. Chem. Soc 1974, 96, 259.
69. (b) Hidai, M.; Kodama, T.; Sato, M.; Hirakawa, M.; Uchida, Y. Inorg. Chem. 1976, 15, 2694.
70. (c) Chatt, J.; Leigh, G. J.; Neukomm, H.; Pickett, C. J.; Stanley, D. R. J. Chem. Soc. Dalton Trans. 1980, 121.
71. (d) Nishihara, H.; Mori, Y.; Nakano, K.; Saito, T.; Sasaki, Y. J. Am. Chem. Soc 1982, 104, 4367.
72. (e) Henderson, R. A. J. Chem. Soc, Dalton Trans. 1982, 917.
73. (f) Bakar, M. A.; Hughes, D. L.; Hussain, W.; Leigh, G. J.; Macdonald, C. J.; Mohd.-Ali, H. J. Chem. Soe., Dalton Trans. 1988, 2545.
74. (g) Barclay, J. E.; Hills, A.; Hughes, D. L.; Leigh, G. J.; Macdonald, C. J.; Bakar, M. A.; Mohd.-Ali, H. J. Chem. Soc, Dalton Trans. 1990, 2503.
75. Reich, H. J. WINDNMR: NMR Spectrum Calculations, version 7.1.12; Department of Chemistry, University of Wisconsin. Madison, WI, 2005.
76. Lazarowych, N. J.; Morris, R. H.; Ressner, J. M. Inorg. Chem. 1986, 25, 3926.
77. Chanev, A. L.; Marbach, E. P. Chin. Chem. 1962, 8, 130.
78. Watt, G. W.; Chrisp, J. D. Anal. Chem. 1952, 24, 2006.
79. SIR97: Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G. C.; Giacovazzo, C.; Guagliardi, A.; Moliterni, A. G. G.; Polidori, G.; Spagna, R. J. Appl. Crystallogr. 1999, 32, 115.
80. DIRDIF99: Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosnian, W. P.; de Gelder, R.; Israel, R.; Smits, J. M. M. The DIRDIF-99 program system. Technical Report of the Crystallography Laboratory; University of Nijmegen, Nijmegen, The Netherlands. 1999.
81. Carruthcrs, J. R.; Rollett, J. S.; Betteridge, P. W.; Kinna, D.; Pearce, L.; Larsen, A.; Gabe, E. CRYSTALS Issue 11; Chemical Crystallography Laboratory, Oxford, U.K., 1999.
82. CrystalStructure 3.8: Crystal Structure Analysis Package; Riga-ku and Rigaku Americas, 2000-2007.