Qualitative and quantitative electroanalysis of synthetic phenolic antioxidant mixtures in edible oils based on their acid-base properties

Food Chemistry

Volumn 127, Issue 3, 2011, Pages 1361-1369

  Noel Robledo, Sebastian ^a   Alicia Zón, María ^a   Daniel Ceballos, Claudio ^a   Fernández, Héctor ^a  

^a DEPARTAMENTO DE QUÍMICA   (Argentina)

Author keywords

Edible oils; Square wave voltammetry; Standard addition method; Synthetic phenolic antioxidants

Indexed keywords

ACID-BASE PROPERTY; COMMERCIAL REAGENTS; EDIBLE OIL; ELECTROANALYTICAL METHOD; NEUTRAL MEDIUM; OLIVE OIL; PHENOLIC ANTIOXIDANT; QUALITATIVE AND QUANTITATIVE ANALYSIS; REACTION MEDIUM; REAL MATRICES; REAL SAMPLES; REPRODUCIBILITIES; SQUARE WAVE VOLTAMMETRY; STANDARD ADDITION METHOD; SYNTHETIC ANTIOXIDANTS; SYNTHETIC PHENOLIC ANTIOXIDANTS; ULTRAMICROELECTRODES; VOLTAMMETRIC SIGNALS;

ACETONITRILE; MICROELECTRODES; MIXTURES; PHENOLS; PLATINUM; STANDARDS; VEGETABLE OILS; VOLTAMMETRY;

QUALITY CONTROL;

ANTIOXIDANT; EDIBLE OIL; PHENOL;

ACID BASE BALANCE; ARTICLE; CHEMICAL REACTION; NONHUMAN; QUALITATIVE ANALYSIS; QUANTITATIVE ANALYSIS; REPRODUCIBILITY;

EID: 79952538263     PISSN: 03088146     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.foodchem.2011.01.102     Document Type: Article

References (28)

1. A. Agiomyrgianaki, P.V. Petrakis, and P. Dais Detection of refined olive oil adulteration with refined hazelnut oil by employing NMR spectroscopy and multivariate statistical analysis Talanta 80 2010 2165 2171
2. M.L. Agui, A.J. Reviejo, P. Yañez-Sedeño, and J.M. Pingarrón Analytical applications of cylindrical carbon fiber microelectrodes. Simultaneous voltammetric determination of phenolic antioxidants in foods Anal. Chem. 67 1995 2195 2200
3. C. Ceballos, and H. Fernández The electroanalytical determination of antioxidants in corn oil using ultramicroelectrodes J. Braz. Chem. Soc. 6 1995 1 5
4. C. Ceballos, and H. Fernández Synthetic antioxidants determination in lard and vegetable oils by the use of voltammetric methods on disk ultramicroelectrodes Food Res. Int. 33 2000 357 365 (Pubitemid 30390693)
5. C. Ceballos, and H. Fernández Synthetic antioxidants in edible oils by square-wave voltammetry on ultramicroelectrodes J. Am. Oil Chem. Soc. 77 2000 731 735
6. Codex Alimentarius (2009). FAO/WHO. http://www.codexalimentarius.net.
7. Código Alimentario Argentino (2009). Capítulo VII-Art 523bis, Ley N° 18284. Decreto 2126/71, Buenos Aires, Argentina, http://www.anmat.gov.ar.
8. M. dos Santos Raymundo, M. Marques da Silva Paula, C. Franco, and R. Fett Quantitative determination of the phenolic antioxidants using voltammetric techniques LWT 40 2007 1133 1139 (Pubitemid 46661772)
9. D.H. Evans, P.J. Jiménez, and M.J. Kelly Reversible dimerization of phenoxyl radicals formed by anodic oxidation of phenolates. A quantitative study by cyclic voltammetry J. Electroanal. Chem. 163 1984 145 157
10. T. Galeano Díaz, A. Guiberteau Cabanillas, M.F. Alexandre Franco, F. Salinas, and J.C. Viré Voltammetric behaviour and simultaneous determination of the antioxidants propyl gallate, butyl hydroxianisole and butyl hydroxytoluene in acidic acetonitrile-water medium using PLS calibration Electroanalysis 10 1998 497 505
11. T. Galeano Díaz, I. Durán Merás, A. Guiberteau Cabanillas, and M.F. Alexandre Franco Voltammetric behavior and determination of tocopherols with partial least squares calibration: Analysis in vegetable oil samples Analytica Chimica Acta 511 2004 231 238 (Pubitemid 38581285)
12. M. González, M. Gallego, and M. Valcárcel Gas chromatographic flow method for the preconcentration and simultaneous determination of antioxidant and preservative additives in fatty foods Journal of Chromatography A 848 1999 529 536 (Pubitemid 29306864)
13. G. Gurdeniz, and B. Ozen Detection of adulteration of extra-virgin olive oil by chemometric analysis of mid-infrared spectral data Food Chemistry 116 2009 519 525
14. O. Hammerich, and B. Svensmark Anodic oxidation of oxygen-containing compounds H. Lund, M.M. Baizer, Organic electrochemistry: An introduction and a guide 3rd ed. 1991 Marcel Dekker New York 615 657
15. H.D. McBride, and D.H. Evans Rapid voltammetric method for the estimation of tocopherols and antioxidants in oils and fats Anal. Chem. 45 3 1973 446 449
16. P.G. Molina, M.A. Zón, and H. Fernández Determination of the acid dissociation constants for some mycotoxins of the Alternaria alternata genus Can. J. Chem. 76 1998 576 582 (Pubitemid 128496467)
17. Morrison, R. T., & Boyd, R. N. (1990). Química Orgánica (5th ed., p. 981). Willmington, Delaware, USA: Wesley Iberoamericana.
18. Y. Ni, L. Wang, and S. Kokot Voltammetry determination of butylated hydroxyanisole, butylated hydroxytoluene, propyl gallate and tert-butylhydroxyquinone by use of chemometric approaches Analytica Chimica Acta 412 2000 185 193 (Pubitemid 30173275)
19. J. Osteryoung Square-wave and staircase voltammetry at small electrodes M.A. Queiros, J.L. Daschbach, M.I. Montenegro, Microelectrodes: Theory and applications Vol. 197 1990 NATO ASI Series, Academic Publisher Dordrecht 139 176
20. C. Perrin, and L. Meyer Quantification of synthetic phenolic antioxidants in dry foods by reversed-phase HPLC with photodiode array detection Food Chemistry 77 2002 93 100 (Pubitemid 34232322)
21. D. Rajalakshmi, and S. Narasimhan Food antioxidants: Sources and methods of evaluation D.L. Madhavi, S.S. Deshpande, D.K. Salunkhe, Food antioxidants 1996 Marcel Dekker New York 70 71
22. J.A. Richards, P.E. Whitson, and D.H. Evans Electrochemical oxidation of 2,4,6-tri-tert-butylphenol J. Electroanal. Chem. 63 1975 311 327
23. D.T. Sawyer, A. Sobkowiak, and J.L. Roberts Jr. Electrochemistry for Chemists 2nd ed. 1995 John Willey & Sons, Inc. New York
24. D.W.M. Sin, Y.C. Wong, C.Y. Mak, S.T. Sze, and W.Y. Yao Determination of five phenolic antioxidants in edible oils: Method validation and estimation of measurement uncertainly Journal of Food Composition and Analysis 19 2006 784 791 (Pubitemid 44294110)
25. Skoog, D. A., Holler, F. J., & Nieman T. A. (2001). Principios de Análisis Instrumental (5th ed., p. 16). Madrid, Spain: Mc Graw Hill.
26. A. Szabo, D.K. Cope, D.E. Tallman, P.M. Kovach, and R.M. Wightman Chronoamperometric current at hemicylinder and band microelectrodes: Theory and experiment J. Electroanal. Chem. 217 1987 417 423
27. U. Viplava Prasad, T.E. Divakar, K. Hariprasad, and C.S.P. Sastry Spectrophotometric determination of some antioxidants in oils and fats Food Chemistry 25 1987 159 164
28. M.A. Zón, M.B. Moressi, L.E. Sereno, and H. Fernández Characteristic behaviour of ultramicroelectrodes. Their use for the determination of thermodynamic and kinetic parameters of redox couples Bol. Soc. Chil. Quím. 39 1994 139 151