Diluting the hydrogen bonds in viscous solutions of n-butanol with n-bromobutane: II. A comparison of rotational and translational motions

Journal of Chemical Physics

Volumn 134, Issue 6, 2011, Pages

  Lederle, Christina ^a   Hiller, Wolf ^a   Gainaru, Catalin ^a   Böhmer, Roland ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL CHAIN; BROMOBUTANE; CHAIN MODELS; HIGH TEMPERATURE; HYDRODYNAMIC RADIUS; MONOHYDROXY ALCOHOLS; N-BUTANOL; NUCLEAR MAGNETIC RESONANCE TECHNIQUES; PROTON NMR; PULSED-FIELD GRADIENTS; REORIENTATIONAL MOTION; SELF-DIFFUSION COEFFICIENTS; SINGLE MOLECULE; SPIN RELAXATION TIME; TRANSLATIONAL DIFFUSION COEFFICIENT; TRANSLATIONAL MOTIONS; VAN DER WAALS RADIUS; VISCOUS SOLUTION;

ALCOHOLS; DIFFUSION; HYDROGEN BONDS; NUCLEAR MAGNETIC RESONANCE; RESONANCE; STRUCTURAL RELAXATION; VAN DER WAALS FORCES;

BINARY MIXTURES;

1 BROMOBUTANE; BROMINATED HYDROCARBON; BUTANOL;

ARTICLE; CHEMISTRY; COMPARATIVE STUDY; HYDROGEN BOND; MOTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ROTATION; SOLUTION AND SOLUBILITY; TEMPERATURE;

1-BUTANOL; HYDROCARBONS, BROMINATED; HYDROGEN BONDING; MAGNETIC RESONANCE SPECTROSCOPY; MOTION; ROTATION; SOLUTIONS; TEMPERATURE;

EID: 79951805154     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3549123     Document Type: Article

References (90)

1. M. Tomsic, A. Jamnik, G. Fritz-Popovski, O. Glatter, and L. Vlcek, J. Phys. Chem. B 111, 1738 (2007). 10.1021/jp066139z (Pubitemid 46384267)
2. A. K. Sum and S. I. Sandler, J. Phys. Chem. A 104, 1121 (2000). 10.1021/jp993094b
3. W. Dannhauser and R. H. Cole, J. Chem. Phys. 23, 1762 (1955). 10.1063/1.1740576
4. V. V. Levin and Y. D. Feldman, Chem. Phys. Lett. 87, 162 (1982). 10.1016/0009-2614(82)83579-3
5. S. W. Benson, J. Am. Chem. Soc. 118, 10645 (1996). 10.1021/ja962101w (Pubitemid 26381251)
6. M. A. Floriano and C. A. Angell, J. Chem. Phys. 91, 2537 (1989). 10.1063/1.457013
7. K. S. Vahvaselk, R. Serimaa, and M. Torkkeli, J. Appl. Crystallogr. 28, 189 (1995); 10.1107/S0021889894010149
8. J. L. MacCallum and D. P. Tieleman, J. Am. Chem. Soc. 124, 15085 (2002); 10.1021/ja027422o (Pubitemid 36014117)
9. L. Zoranik, F. Sokolic, and A. Perera, J. Chem. Phys. 127, 024502 (2007). 10.1063/1.2753482 (Pubitemid 47130428)
10. W. Dannhauser, J. Chem. Phys. 48, 1911 (1968). 10.1063/1.1668989
11. D. Fragiadakis, C. M. Roland, and R. Casalini, J. Chem. Phys. 132, 144505 (2010). 10.1063/1.3374820
12. A. Reiser, G. Kasper, C. Gainaru, and R. Bhmer, J. Chem. Phys. 132, 181101 (2010). 10.1063/1.3421555
13. S. Pawlus, M. Paluch, and M. Dzida, J. Phys. Chem. Lett. 1, 3249 (2010). 10.1021/jz101288v
14. L.-M. Wang, S. Shahriari, and R. Richert, J. Phys. Chem. B 109, 23255 (2005). 10.1021/jp054542k (Pubitemid 43081491)
15. T. El Goresy and R. Bhmer, J. Chem. Phys. 128, 154520 (2008). 10.1063/1.2903403 (Pubitemid 351574666)
16. C. Gainaru, S. Schildmann, and R. Bhmer, J. Phys. Chem. (unpublished).
17. A. Sanz, M. Jiménez-Ruiz, A. Nogales, D. Martn y Marero, and T. A. Ezquerra, Phys. Rev. Lett. 93, 015503 (2004). 10.1103/PhysRevLett.93.015503
18. P. Debye, Polare Molekeln (S. Hirzel, Leipzig, 1929).
19. D. W. Davidson and R. H. Cole, J. Chem. Phys. 19, 1484 (1951). 10.1063/1.1748105
20. S. K. Garg and C. P. Smyth, J. Phys. Chem. 69, 1294 (1964). 10.1021/j100888a033
21. G. P. Johari and W. Dannhauser, J. Chem. Phys. 48, 5114 (1968). 10.1063/1.1668182
22. S. S. N. Murthy and S. K. Nayak, J. Chem. Phys. 99, 5362 (1993). 10.1063/1.466187
23. C. Hansen, F. Stickel, T. Berger, R. Richert, and E. W. Fischer, J. Chem. Phys. 107, 1086 (1997). 10.1063/1.474456
24. M. Iwahashi, Y. Ohbu, T. Kato, Y. Suzuki, and K. Yamauchi, Bull. Chem. Soc. Jpn. 59, 3771 (1986). 10.1246/bcsj.59.3771
25. Room temperature values were reported for some alcohols including n-butanol, see, e.g., D. W. McCall and D. C. Douglass, J. Chem. Phys. 32, 1876 (1960). 10.1063/1.1731042
26. R. L. Hurle, A. J. Easteal, and L. A. Woolf, J. Chem. Soc., Faraday Trans. 1 81, 769 (1985). 10.1039/f19858100769
27. S. Meckl and M. D. Zeidler, Mol. Phys. 63, 85 (1988). 10.1080/00268978800100081
28. N. Shaker-Gaafar, N. Karger, S. Wappmann, and H. D. Ldemann, Ber. Bunsenges. Phys. Chem. 97, 805 (1993).
29. N. Karger, S. Wappmann, N. Shaker-Gaafar, and H.-D. Ldemann, J. Mol. Liq. 64, 211 (1995). 10.1016/0167-7322(95)00810-W
30. B. M. Fung and T. W. McGaughy, J. Chem. Phys. 65, 2970 (1976); 10.1063/1.433533
31. M. Pschl and H. G. Hertz, J. Phys. Chem. 98, 8195 (1994); 10.1021/j100084a043
32. T. Frech and H. G. Hertz, Ber. Bunsenges. Phys. Chem. 89, 948 (1985);
33. M. Butsch and H. Sillescu, private communication (March 2006).
34. R. Ludwig, M. D. Zeidler, and T. C. Farrar, Z. Phys. Chem., Neue Folge 189, 19 (1995) focus on room temperature.
35. M. Hakes and M. D. Zeidler, Phys. Chem. Chem. Phys. 4, 5119 (2002). 10.1039/b205662n
36. C. Gainaru, R. Meier, S. Schildmann, C. Lederle, W. Hiller, E. A. Rssler, and R. Bhmer, Phys. Rev. Lett. 105, 258303 (2010). 10.1103/PhysRevLett.105. 258303
37. H. Huth, L.-M. Wang, C. Schick, and R. Richert, J. Chem. Phys. 126, 104503 (2007). 10.1063/1.2539105 (Pubitemid 46440091)
38. B. Jakobsen, C. Maggi, T. Christensen, and J. C. Dyre, J. Chem. Phys. 129, 184502 (2008). 10.1063/1.3007988
39. R. Coelho and D. K. Manh, C. R. Acad. Sc. Paris C 264, 641 (1967);
40. J. Crossley and G. Williams, J. Chem. Soc., Faraday Trans. 2 73, 1906 (1977). 10.1039/f29777301906
41. M. Maroncelli and G. R. Fleming, J. Chem. Phys. 86, 6221 (1987); 10.1063/1.452460
42. H. Wendt and R. Richert, J. Phys. Chem. A 102, 5775 (1998); 10.1021/jp981613p
43. S. Yu. Grebenkin and V. M. Syutkin, Phys. Rev. B 76, 054202 (2007). 10.1103/PhysRevB.76.054202
44. S. S. N. Murthy and M. Tyagi, J. Chem. Phys. 117, 3837 (2002). 10.1063/1.1494428 (Pubitemid 35000309)
45. L.-M. Wang and R. Richert, J. Chem. Phys. 121, 11170 (2004). 10.1063/1.1811072 (Pubitemid 40025619)
46. H. Nadolny, Ph.D. dissertation, Ruhr-Universität Bochum, 2003.
47. See Fig. 37 in Chapter VI of C. J. F. Bttcher, Theory of Electric Polarization (Elsevier, Amsterdam, 1973), vol. I.
48. I. Chang and H. Sillescu, J. Phys. Chem. B 101, 8794 (1997). 10.1021/jp9640989
49. H can result depending on whether stick' or slip'' boundary conditions do apply.
50. W. Weber, Rheol. Acta 14, 1012 (1975); 10.1007/BF01516304
51. A. Ansn, R. Garriga, S. Martnez, P. Pérez, and M. Gracia, J. Chem. Eng. Data 50, 1478 (2005). 10.1021/je0501235
52. S. Gibbs und C. Johnson, J. Magn. Reson. 93, 395 (1991); 10.2466/PR0.68.3.739-746
53. A. Jerschow and N. Mller. J. Magn. Reson. 123, 222 (1996); 10.1006/jmra.1996.0241
54. for a review see C. Johnson, Prog. Nucl. Magn. Reson. Spectrosc. 34, 203 (1999). 10.1016/S0079-6565(99)00003-5
55. A. Jerschow and N. Mller, J. Magn. Reson. 125, 372 (1997). 10.1006/jmre.1997.1123
56. max were added in our experiments after the pulses 3, 6, and 9, i.e., in the time intervals in which only longitudinal magnetization should be retained.
57. B. Geil, Concepts Magn. Reson. 10, 299 (1998). 10.1002/(SICI)1099- 0534(1998)10:5299::AID-CMR33.0.CO;2-S
58. M. Holz, S. R. Heil, and A. Sacco, Phys. Chem. Chem. Phys. 2, 4740 (2000). 10.1039/b005319h
59. E. O. Stejskal and J. E. Tanner, J. Chem. Phys. 42, 288 (1965). 10.1063/1.1695690
60. The DSC measurements, kindly provided by Thomas Blochowicz (Darmstadt), were carried out at ramp rates of ∼30 Kmin (corresponding to a time scale 33 s) and yielded an onset temperature of 105 K.
61. L.-M. Wang, Y. Tian, R. Liu, and R. Richert, J. Chem. Phys. 128, 084503 (2008). 10.1063/1.2840357 (Pubitemid 351328704)
62. C. Gainaru, R. Kahlau, E. A. Rssler, and R. Bhmer, J. Chem. Phys. 131, 184510 (2009). 10.1063/1.3258430
63. g, see A. Kudlik, S. Benkhof, T. Blochowicz, C. Tschirwitz, and E. Rssler, J. Mol. Struct. 479, 201 (1999). 10.1016/S0022-2860(98)00871-0 (Pubitemid 29162253)
64. J. R. Lyerla Jr., and G. C. Levy, in Topics in Carbon-13 NMR Spectroscopy, edited by, G. C. Levy, (Wiley, New York, 1974), vol. 1, pp. 79-149.
65. 13C experiments were carried out, the application of a Cole-Davidson distribution would yield time constants which that can be up to a factor of 2 shorter than those reported in the text. 10.1016/0370-1573(88)90073-7
66. F. Stickel, E. W. Fischer, and R. Richert, J. Chem. Phys. 104, 2043 (1996); 10.1063/1.470961
67. D. Kivelson and G. Tarjus, J. Non-Cryst. Solids 235-237, 86 (1998); 10.1016/S0022-3093(98)00631-0
68. T. Blochowicz, C. Gainaru, P. Medick, C. Tschirwitz, and E. A. Rssler, J. Chem. Phys. 124, 134503 (2006). 10.1063/1.2178316
69. F. Stickel, Ph.D. dissertation, Universität Mainz, 1995.
70. R. Brand, P. Lunkenheimer, U. Schneider, and A. Loidl, Phys. Rev. B 62, 8878 (2000); 10.1103/PhysRevB.62.8878 (Pubitemid 32367351)
71. P. Lunkenheimer, private communication (September 2010).
72. Y. Yomogida, Y. Sato, K. Yamakawa, R. Nozaki, T. Mishina, and J. Nakahara, J. Mol. Struct. 970, 171 (2010). 10.1016/j.molstruc.2010.03.002
73. A. V. Lesikar, J. Solution Chem. 6, 81 (1977). 10.1007/BF00643434
74. Data for octanol seem to be available in a rather restricted temperature range only.
75. A similar plot mainly focusing on the audio-frequency range was shown by Wang and Richert in Ref..
76. E. Schlosser and A. Schnhals, Prog. Colloid Polym. Sci. 91, 158 (1993). 10.1007/BFb0116441
77. C. Gainaru, W. Hiller, and R. Bhmer, Macromolecules 43, 1907 (2010). 10.1021/ma9026383
78. J. T. Edward, J. Chem. Educ. 47, 261 (1970). 10.1021/ed047p261
79. D). Use of Eq. yields a radius close to the one reported in the present work.
80. vdW ≈ 0.6 0.8 for the seven glass-forming liquids compared in Table 1 of Ref..
81. H, increases to 0.6 if one uses for the experimental values reported in Ref. instead of the extrapolation.
82. R. Zimmermann and W. E. Brittin, J. Phys. Chem. 61, 1328 (1957); 10.1021/j150556a015
83. D. Beckert and H. Pfeiffer, Ann. Phys. 16, 262 (1965); 10.1002/andp.19654710510
84. J. E. Anderson and R. Ullmann, J. Chem. Phys. 47, 2178 (1967); 10.1063/1.1712250
85. G. P. Johari and W. Dannhauser, J. Chem. Phys. 50, 1862 (1969); 10.1063/1.1671282
86. W. Huang and R. Richert, J. Chem. Phys. 124, 164510 (2006). 10.1063/1.2191491
87. J. Lehtola, M. Hakala, and K. Hmlinen, J. Phys. Chem. B 114, 6426 (2010). 10.1021/jp909894y
88. N. Giovambattista, S. V. Buldyrev, F. W. Starr, and H. E. Stanley, Phys. Rev. Lett. 90, 085506 (2003). 10.1103/PhysRevLett.90.085506
89. U. Kaatze, R. Behrends, and R. Pottel, J. Non-Cryst. Solids 305, 19 (2002). 10.1016/S0022-3093(02)01084-0 (Pubitemid 34552112)
90. M. Sokolova, S. J. Barlow, G. V. Bondarenko, Y. E. Gorbaty, and M. Poliakoff, J. Phys. Chem. A 110, 3882 (2006). 10.1021/jp055931h