A dielectric study of oligo- and poly(propylene glycol)

Macromolecules

Volumn 43, Issue 4, 2010, Pages 1907-1914

  Gainaru, Catalin ^a   Hiller, Wolf ^a   Böhmer, Roland ^a  

^a TU DORTMUND UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHARACTERISTIC LENGTH; CHARACTERISTIC RATIO; DIELECTRIC STUDIES; GLASS TRANSFORMATIONS; GLASSY STATE; MOLECULAR RULER; NMR RELAXATION EXPERIMENTS; NORMAL MODES; POLYMER CHAINS; POLYPROPYLENE GLYCOL; ROUSE MODEL; SEGMENTAL MODE; SPECTRAL WIDTHS; TIME-SCALES; VITRIFICATION PROCESS;

ACTIVATION ENERGY; DISPERSIONS; GLYCOLS; HYDRATES; POLYPROPYLENE OXIDES;

PROPYLENE;

EID: 77249167664     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9026383     Document Type: Article

References (92)

1. Baur, M. E.; Stockmayer, H. J. Chem. Phys. 1965, 43, 4319-4325.
2. Beevers, M. S.; Elliott, D. A.; Williams, G. Polymer 1980, 21, 13-20.
3. Adachi, K.; Kotaka, T. Macromolecules 1987, 20, 2018-2023.
4. Jacobsson, P.; Börjesson, L.; Torell, L. M. J. Non-Cryst. Solids 1991, 131-133, 104-108.
5. Ding, Y.; Kisliuk, A.; Sokolov, A. P. Macromolecules 2004, 37, 161-166.
6. Kariyo, S.; Gainaru, C.; Schick, H.; Brodin, A.; Rössler, E. A. Phys. Rev. Lett. 2006, 97, 207803.
7. Schönhals, A. In Broadband Dielectric Spectroscopy; .Kremer, F., Schönhals, A., Eds.; Springer: Berlin, 2003; Chapter 7.
8. de Gennes, P. G. In Scaling Concepts in Polymer Physics; Cornell University Press: Ithaca, NY, 1979.
9. Doi, M.; Edwards, S. F. The Theory of Polymer Dynamics; Clarendon: Oxford, 1986.
10. Riande, E.; Diaz-Calleja, R. Electrical Properties of Polymers; Marcel Dekker: New York, 2004.
11. Williams, G. Macromol. Symp. 2009, 286, 1-19.
12. Adachi, K.; Kotaka, T. Prog. Polym. Sci. 1993, 18, 585-622.
13. Se, K.; Adachi, K.; Kotaka, T. Polym. J. 1981, 13, 1009-1017.
14. Casalini, R.; Roland, C. M. Macromolecules 2005, 38, 1779-1788.
15. Mierzwa, M.; Floudas, G.; Dorgan, J.; Knauss, D.; Wegner, J. J. Non-Cryst. Solidi 2002, 307-310, 296-303.
16. Further examples are given in: Hirose, Y.; Adachi, K. Polymer 2005, 46, 1913-1920.
17. Hayakawa, T.; Adachi, K. Polymer 2001, 42, 1725-1732.
18. Engberg, D.; Schüller, J.; Strube, B.; Sokolov, A. P.; Torell, L. M. Polymer 1999, 40, 4755-4761.
19. Schönhals, A.; Schlosser, E. Phys. Scr. 1993, T49, 233-236.
20. Schönhals, A.; Schlosser, E. Prog. Colloid Polym. Sci. 1993, 91, 158-161.
21. Mattsson, J.; Bergman, R.; Jacobsson, P.; Börjesson, L. Phys. Rev. Lett. 2003, 90, 075702.
22. Mattsson, J.; Bergman, R.; Jacobsson, P.; Börjesson, L. Phys. Rev. Lett. 2005, 94, 165701.
23. Moon, I. K.; Jeong, Y. H.; Furukawa, T. Thermochim. Acta 2001, 377, 97-104.
24. Mel'nichenko, Y. B.; Schüller, J.; Richert, R.; Ewen, B.; Long, C.-K. J. Chem. Phys. 1995, 103, 2016-2024.
25. Fleischer, G.; Helmstedt, M.; Alig, I. Polym. Commun. 1990, 31, 409-411.
26. Appel, M.; Fleischer, G.; Kärger, J.; Chang, I.; Fujara, F.; Schönhals, A. Colloid Polym. Sci. 1997, 275, 187-191.
27. Wang, C. H.; Fytas, G.; Lilge, D.; Dorfmüller, T. Macromolecules 1981, 14, 1363-1370.
28. Ko, J.-H.; Kojima, S. Phys. Lett. A 2004, 321, 141-146.
29. Yano S.; Rabalkar, R. R.; Hunter, S. P.; Wang, C. H.; Boyd, R. H. J. Polym. Sci., Polym. Phys. Ed. 1976, 14, 1877-1890.
30. (a)Yoshihara, A.; Sato, H.; Kojima, S. Jon. J. Appl. Phys. 1996, 35, 2925-2929.
31. (b) Yoshihara, A.; Sato, H.; Kojima, S. Prog. Theor. Suppl. 1996, 126, 423-426.
32. Kojima, S.; Sato, H.; Yosihara, A. J. Phys.: Condens. Matter 1997, 9, 10079-10085.
33. Alig, I.; Grigorev, S. B.; Manucarov, Yu. S.; Manucarova, S. A. Acta Polym. 1986, 37, 698-702 and 733-736.
34. Cochrane, J.; Harrison, G.; Lamb, J.; Phillips, D. W. Polymer 1980, 21, 837-844.
35. Swenson, J.; Köper, I.; Telling, M. T. F. J. Chem. Phys. 2002, 116, 5073-5079.
36. Vogel, M.; Torbrügge, T. J. Chem. Phys. 2007, 126, 204902.
37. Roland, C. M.; Psurek, T.; Pawlus, S.; Paluch, M. J. Polym. Sci., Part B: Polym. Phys. 2003, 41, 3047-3052.
38. (a) Schönhals, A.; Stauga, R. J. Non-Cryst. Solids 1998, 450, 235-237.
39. (b) Schönhals, A.; Stauga, R. J. Chem. Phys. 1998, 108, 5130-5136.
40. Schwartz, G. A.; Bergman, R.; Swenson, J. J. Chem. Phys. 2004, 120, 5736-5744 and references cited therein.
41. Gainaru, C.; Böhmer, R. Macromolecules 2009, 42, 7616-7618.
42. Smith, B. A.; Samulski, E. T.; Yu, L. P.; Winnik, M. A. Macromolecules 1985, 18, 1901-1905.
43. Heinrich, G.; Alig, I.; Donth, E. Polymer 1988, 29, 1198-1202.
44. Alig, I.; Donth, E.; Schenk, W.; Horing, S.; Wohlfarth, C. Polymer 1988, 29, 2081-2086.
45. Ahlström, P.; Wahnström, G.; Carlsson, P.; Schantz, S.; Brodin, A.; Maurer, F.; Torell, L. Philos. Mag. B 1998, 77, 699-707.
46. Leon, C.; Ngai, K. L.; Roland, C. M. J. Chem. Phys. 1999, 110, 11585-11591.
47. (a) Grzybowska, K.; Grzybowski, A.; Ziolo, J.; Paluch, M.; Capaccioli, S. J. Chem, Phys. 2006, 125, 044904.
48. (b) Grzybowska, K.; Grzybowsky, A.; Ziolo, J.; Rzoska, S. J.; Paluch, M. J. Phys.: Condens. Matter 2007, 19, 376105.
49. Köhler, M.; Lunkenheimer, P.; Goncharov, Y.; Wehn, R.; Loidl, A. arXiv:0810.5316v1, 2008.
50. Wagner, H.; Richert, R. J. Phys. Chem. B 1999, 103, 4071-4077.
51. Osaki, S.; Uemura, S.; Ishida, Y. J. Polym. Sci., Polym. Phys. Ed. 1971, 9, 585-594
52. Nazemi, A.; Williams, G.; Attard, G. S.; Karasz, F. E. Polym. Adv. Technol. 1992, 3, 157-168.
53. Gainaru, C.; Böhmer, R.; Williams, G., to be published.
54. Rouse, P. E., Jr. J. Chem. Phys. 1953, 21, 1272-1280.
55. Watanabe, H. Macromol. Rapid Commun. 2001, 22, 127-175.
56. Note that according to ref 44 the calorimetric glass transition temperatures of 2PG and 3PG are rather similar.
57. Vold, R. L.; Waugh, J. S.; Klein, M. P.; Phelps, D. E. J. Chem. Phys. 1968, 48, 3831-3832.
58. Heatley, F. Prog. Nucl. Magn. Reson. Spectrosc. 1979, 13, 47-87.
59. Bloembergen, N.; Purcell, E.; Pound, R. Phys. Rev. 1948, 73, 679-712.
60. Connor, T. M. Trans. Faraday Soc. 1964, 60, 1574-1591.
61. Fox, T.; Flory, P. J. J. Polym. Sci. 1954, 14, 315-319.
62. Smooth molecular-weight-dependent broadening effects are more clearly revealed for PPG than for many other polymer systems. See, e.g.: Lusceac, S. A.; Gainaru, C.; Vogel, M.; Koplin, C.; Medick, P.; Rössler, E. A. Macromolecules 2005, 38, 5625-5633.
63. Pawlus, S.; Hensel-Bielowka, S.; Grzybowska, K.; Zioo, J.; Paluch, M. Phys. Rev. 2005, 71, 174107.
64. Ngai, K., L.; Paluch, M. J. Chem. Phys. 2004, 120, 857-873.
65. Dyre, J.; Olsen, N. B. Phys. Rev. Lett. 2003, 91, 155703.
66. Cerveny, S.; Alegria, A.; Colmenero, J. Phys. Rev. 2008, E 77, 031803.
67. Kudlik, A.; Benkhof, S.; Blochowicz, T.; Tschirwitz, C.; Rössler, E. A. J. Mol. Struct. 1999, 479, 201-218.
68. Brandrup, J., Immergut, E. H. Polymer Handbook; John Wiley: New York, 1989.
69. Ishikawa, T.; Teramono, A. Polym. J. 1974, 6, 207-215.
70. Tracht, U.; Wilhelm, M.; Heuer, A.; Feng, H.; Schmidt-Rohr, K.; Spiess, H. W. Phys. Rev. Lett, 1998, 81, 2727-2730.
71. Reinsberg, S. A.; Heuer, A.; Doliwa, B.; Zimmermann, H.; Spiess, H. W. J. Non-Cryst. Solids 2002, 307-310, 208-214.
72. Chamberlin, R. V. Phys. Rev. Lett. 1999, 82, 2520-2523.
73. Dalle-Ferrier, C.; Thibierge, C.; Alba-Simionesco, C.; Berthier, L.; Biroli, G.; Bouchaud, J.-P.; Ladieu, F.; L'Hôte, D.; Tarjus, G. Phys. Rev. 2007, E 76, 041510.
74. Moynihan, C. T.; Schroeder, J. J. Non-Cryst. Solids 1993, 160, 52-59.
75. Masciovecchio, C.; Baldi, G.; Caponi, S.; Comez, L.; Di Fonzo, S.; Fioretto, D.; Fontana, A.; Gessini, A.; Santucci, S. C.; Sette, F.; Viliani, G.; Vilmercati, P.; Ruocco, G. Phys. Rev. Lett. 2006, 97, 035501.
76. Hong, L.; Gujrati, P. D.; Novikov, V. N.; Sokolov, A. P. J. Chem. Phys. 2009, 131, 194511.
77. Böttcher, C. J. F.; Bordewijk, P. Theory of Electric Polarization I: Dielectrics in Static Fields; Elsevier: Amsterdam, 1978.
78. These relations are expected to hold best at high temperatures and for large N. Under these conditions static dipole correlations, sometimes parametrized using Kirkwood's g factor (see e.g., ref 10), should, be small.
79. Flory, P. J. Statistical Mechanics of Chain Molecules; Interscience Publishers: New York, 1969;
80. Volkenstein, M. V. Configurational Statistics of Polymeric Chains; Interscience Publishers: New York, 1963.
81. 2.This modification does not change the arguments advanced in that paper.
82. Imanishi, Y.; Adachi, K.; Kotaka, T. J. Chem. Phys. 1988, 89, 7585-7592.
83. Stühn, B.; Stickel, F. Macromolecules 1992, 25, 5306-5312.
84. Stockmayer, W. H. Pure Appl. Chem. 1967, 15, 539-554.
85. This determination implies that static dipole correlations are absent (g = 1), identical, or otherwise known for the segmental as well as for the normal mode processes.
86. Ilan, B.; Loring, R. F. Macromolecules 1999, 32, 949-951.
87. Decoupling effects are often discussed for simple molecular glass formers. See e.g.: Chang, I.; Fujara, F.; Geil, B.; Heuberger, G.; Mangel, T.; Sillescu, H. J. Non-Cryst. Solidis 1994, 172-174, 248-255.
88. Ngai, K. L.; Schönhals, A.; Schlosser, E. Macromolecules 1992, 25, 4915-4919.
89. Ngai, K. L.; Plazek, D. J.; Deo, S. S. Macromolecules 1987, 20, 3047-3054.
90. Mattsson, J.; Bergman, R.; Jacobsson, P.; Börjesson, L. Phys. Rev. B 2009, 79, 174205.
91. Sokolov, A. P.; Novikov, V. N.; Ding, Y. J. Phys.: Condens. Matter 2007, 19, 205116.
92. Abou Elfadl, A.; Kahlau, R.; Herrmann, A.; Novikov, V. N.; Rössler, E. A. Macromolecules, submitted.