Communications: High-pressure dielectric scaling study of a monohydroxy alcohol

Journal of Chemical Physics

Volumn 132, Issue 18, 2010, Pages

  Reiser, Andreas ^a   Kasper, Gernot ^a   Gainaru, Catalin ^b   Böhmer, Roland ^b  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b TU DORTMUND UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

2-ETHYL-1-HEXANOL; DEBYE-TYPE DIELECTRIC RELAXATION; DIELECTRIC SCALING; GLASS-FORMING; MONOHYDROXY ALCOHOLS; SCALING EXPONENT;

PRESSURE MEASUREMENT; STRUCTURAL RELAXATION;

ORGANIC POLYMERS;

EID: 77952719818     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3421555     Document Type: Article

References (41)

1. C. A. Angell, Science SCIEAS 0036-8075 582, 319 (2008).
2. W. Huang and R. Richert, J. Phys. Chem. B JPCBFK 1089-5647 112, 9909 (2008). 10.1021/jp8038187
3. P. Lunkenheimer, R. Wehn, U. Schneider, and A. Loidl, Phys. Rev. Lett. PRLTAO 0031-9007 95, 055702 (2005). 10.1103/PhysRevLett.95.055702 (Pubitemid 41509222)
4. R. H. Cole and D. W. Davidson, J. Chem. Phys. JCPSA6 0021-9606 20, 1389 (1952) 10.1063/1.1700767;
5. W. Dannhauser and R. H. Cole, J. Chem. Phys. JCPSA6 0021-9606 23, 1762 (1955). 10.1063/1.1740576
6. G. P. Johari and M. Goldstein, J. Chem. Phys. JCPSA6 0021-9606 55, 4245 (1971) 10.1063/1.1676742;
7. O. E. Kalinovskaya, J. K. Vij, and G. P. Johari, J. Phys. Chem. A JPCAFH 1089-5639 105, 5061 (2001). 10.1021/jp0040695 (Pubitemid 35381685)
8. B. Schiener and R. Böhmer, J. Non-Cryst. Solids JNCSBJ 0022-3093 182, 180 (1995). 10.1016/0022-3093(94)00581-8
9. C. Hansen, F. Stickel, T. Berger, R. Richert, and E. W. Fischer, J. Chem. Phys. JCPSA6 0021-9606 107, 1086 (1997). 10.1063/1.474456
10. L. M. Wang and R. Richert, J. Chem. Phys. JCPSA6 0021-9606 121, 11170 (2004). 10.1063/1.1811072 (Pubitemid 40025619)
11. B. Jakobsen, C. Maggi, T. Christensen, and J. C. Dyre, J. Chem. Phys. JCPSA6 0021-9606 129, 184502 (2008). 10.1063/1.3007988
12. H. Huth, L. -M. Wang, C. Schick, and R. Richert, J. Chem. Phys. JCPSA6 0021-9606 126, 104503 (2007). 10.1063/1.2539105 (Pubitemid 46440091)
13. C. J. F. Böttcher and P. Bordewijk, Theory of Electric Polarization, 2nd ed. (Elsevier, Amsterdam, 1978), Vol. 2, Sec. 75, and references cited therein.
14. K. Kessairi, S. Capaccioli, D. Prevosto, M. Lucchesi, S. Sharifi, and P. A. Rolla, J. Phys. Chem. B JPCBFK 1089-5647 112, 4470 (2008) 10.1021/jp800764w.
15. S. Hensel-Bielowka and M. Paluch, Phys. Rev. Lett. PRLTAO 0031-9007 89, 025704 (2002). 10.1103/PhysRevLett.89.025704
16. R. Böhmer, G. Diezemann, B. Geil, G. Hinze, A. Nowaczyk, and M. Winterlich, Phys. Rev. Lett. PRLTAO 0031-9007 97, 135701 (2006). 10.1103/PhysRevLett.97.135701 (Pubitemid 44477068)
17. A. Tölle, H. Schober, J. Wuttke, O. G. Randl, and F. Fujara, Phys. Rev. Lett. PRLTAO 0031-9007 80, 2374 (1998) 10.1103/PhysRevLett.80.2374;
18. A. Tölle, Rep. Prog. Phys. RPPHAG 0034-4885 64, 1473 (2001). 10.1088/0034-4885/64/11/203 (Pubitemid 33105418)
19. K. L. Ngai, R. Casalini, S. Capaccioli, M. Paluch, and C. M. Roland, J. Phys. Chem. B JPCBFK 1089-5647 109, 17356 (2005). 10.1021/jp053439s (Pubitemid 41398169)
20. K. L. Ngai, R. Casalini, S. Capaccioli, M. Paluch, and C. M. Roland, Adv. Chem. Phys. ADCPAA 0065-2385 133, 497 (2006).
21. U. R. Pedersen, N. P. Bailey, T. B. Schrøder, and J. C. Dyre, Phys. Rev. Lett. PRLTAO 0031-9007 100, 015701 (2008). 10.1103/PhysRevLett.100. 015701 (Pubitemid 351388321)
22. D. Coslovich and C. M. Roland, J. Chem. Phys. JCPSA6 0021-9606 130, 014508 (2009). 10.1063/1.3054635
23. A. A. Pronin, M. V. Kondrin, A. G. Lyapin, V. V. Brazhkin, A. A. Volkov, P. Lunkenheimer, and A. Loidl, Phys. Rev. E 81, 041503 (2010).
24. C. M. Roland, S. Hensel-Bielowka, M. Paluch, and R. Casalini, Rep. Prog. Phys. RPPHAG 0034-4885 68, 1405 (2005), and references cited therein. 10.1088/0034-4885/68/6/R03 (Pubitemid 40906221)
25. D. Prevosto, S. Capaccioli, M. Lucchesi, P. A. Rolla, M. Paluch, S. Pawlus, and J. Zioo, J. Chem. Phys. JCPSA6 0021-9606 122, 61102 (2005) report on the emergence of Debye-like low-frequency feature that becomes obvious for tri-propylene glycol upon the application of high pressures at temperatures not too close to the glass transition.
26. Some calorimetric high-pressure data on the α -relaxation of 1-propanol are also available; see O. Yamamuro, S. Takahara, and H. Suga, J. Non-Cryst. Solids JNCSBJ 0022-3093 183, 144 (1995). 10.1016/0022-3093(94)00561-3
27. Y. Hiejima and M. Yao, J. Chem. Phys. JCPSA6 0021-9606 119, 7931 (2003). 10.1063/1.1609981
28. A. Gilchrist, J. E. Earley, and R. H. Cole, J. Chem. Phys. JCPSA6 0021-9606 26, 196 (1957) 10.1063/1.1743249
29. H. Forsman, P. Andersson, and G. Backstrom, J. Chem. Soc., Faraday Trans. II 82, 857 (1986). 10.1039/f29868200857 0300-9238
30. G. P. Johari and W. Dannhauser, J. Chem. Phys. JCPSA6 0021-9606 50, 1862 (1969), and references cited therein. 10.1063/1.1671282
31. C. Gainaru and R. Böhmer, J. Non-Cryst. Solids JNCSBJ 0022-3093 356, 542 (2010). 10.1016/j.jnoncrysol.2009.07.030
32. A. Reiser, G. Kasper, and S. Hunklinger, Phys. Rev. B PRBMDO 0163-1829 72, 094204 (2005). 10.1103/PhysRevB.72.094204 (Pubitemid 43024236)
33. The pressure induced rupture of H-bonds was also made responsible for the breakdown of isochronal scaling in polyalcohols that do not show a Debye-type relaxation; see Ref..
34. T. El Goresy and R. Böhmer, J. Chem. Phys. JCPSA6 0021-9606 128, 154520 (2008). 10.1063/1.2903403 (Pubitemid 351574666)
35. This was also demonstrated by altering the effective ion density via the application of bias fields; see C. Gainaru, R. Böhmer, and G. Williams, " Ion sweeping in conducting dielectric materials.," Eur. Phys. J. B EPJBFY 1434-6028 (in press).
36. G. Tarjus, D. Kivelson, S. Mossa, and C. Alba-Simionesco, J. Chem. Phys. JCPSA6 0021-9606 120, 6135 (2004). 10.1063/1.1649732
37. D. W. Oxtoby, Ann. N.Y. Acad. Sci. ANYAA9 0077-8923 484, 26 (1986). 10.1111/j.1749-6632.1986.tb49559.x
38. J. P. Hansen and I. R. McDonald, Theory of Simple Liquids (Academic, London, 1986).
39. C. Dreyfus, A. Le Grand, J. Gapinski, W. Steffen, and A. Patkowski, Eur. Phys. J. B EPJBFY 1434-6028 42, 309 (2004). 10.1140/epjb/e2004-00386-3 (Pubitemid 40043235)
40. V. G. Baonza, M. Cáceres, and J. Núez, Phys. Rev. B PRBMDO 0163-1829 51, 28 (1995). 10.1103/PhysRevB.51.28
41. dTg/dp should not depend significantly on the choice of the reference time scale; see Ref..