Investigation of the shear-mechanical and dielectric relaxation processes in two monoalcohols close to the glass transition

Journal of Chemical Physics

Volumn 129, Issue 18, 2008, Pages

  Jakobsen, Bo ^a   Maggi, Claudio ^a   Christensen, Tage ^a   Dyre, Jeppe C ^a  

^a ROSKILDE UNIVERSITY   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CHEMICAL RELAXATION; DIELECTRIC RELAXATION; GLASS; LIQUIDS; RELAXATION PROCESSES; SUPERCONDUCTING TRANSITION TEMPERATURE;

ALPHA RELAXATIONS; COMMON FEATURES; DEBYE PEAKS; DIELECTRIC MEASUREMENTS; DIELECTRIC RELAXATION PROCESSES; DIELECTRIC RELAXATION SPECTRUMS; HEXANOL; MECHANICAL RELAXATIONS; MOLECULAR GLASS FORMERS; MONO ALCOHOLS; RELAXATION STRENGTHS; TIME SCALES; TRANSITION TEMPERATURES;

GLASS TRANSITION;

EID: 56349108096     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3007988     Document Type: Article

References (47)

1. C. J. F. Böttcher and P. Bordewijk, Theory of Electric Polarization II: Dielectrics in Time-Dependent Fields, 2nd ed. (Elsevier, New York, 1980).
2. D. W. Davidson and R. H. Cole, J. Chem. Phys. 0021-9606 10.1063/1.1748105 19, 1484 (1951).
3. R. H. Cole and D. W. Davidson, J. Chem. Phys. 0021-9606 10.1063/1.1700767 20, 1389 (1952).
4. R. Kono, T. A. Litovitz, and G. E. McDuffie, J. Chem. Phys. 0021-9606 10.1063/1.1727831 45, 1790 (1966).
5. T. A. Litovitz and G. E. McDuffie, J. Chem. Phys. 0021-9606 10.1063/1.1734316 39, 729 (1963).
6. G. P. Johari and M. Goldstein, J. Chem. Phys. 0021-9606 10.1063/1.1676742 55, 4245 (1971).
7. S. S. N. Murthy, Mol. Phys. 0026-8976 10.1080/00268979650027414 87, 691 (1996).
8. S. S. N. Murthy, J. Phys. Chem. 0022-3654 10.1021/jp953596z 100, 8508 (1996).
9. C. Hansen, F. Stickel, T. Berger, R. Richert, and E. W. Fischer, J. Chem. Phys. 0021-9606 10.1063/1.474456 107, 1086 (1997).
10. A. Kudlik, C. Tschirwitz, S. Benkhof, T. Blochowicz, and E. Rössler, Europhys. Lett. 0295-5075 10.1209/epl/i1997-00518-y 40, 649 (1997).
11. H. Wendt and R. Richert, J. Phys. Chem. A 1089-5639 10.1021/jp981613p 102, 5775 (1998).
12. S. S. N. Murthy and M. Tyagi, J. Chem. Phys. 0021-9606 10.1063/1.1494428 117, 3837 (2002).
13. L. M. Wang and R. Richert, J. Chem. Phys. 0021-9606 10.1063/1.1811072 121, 11170 (2004).
14. L. M. Wang and R. Richert, J. Phys. Chem. B 1089-5647 10.1021/jp051965d 109, 11091 (2005).
15. L. M. Wang and R. Richert, J. Phys. Chem. B 1089-5647 10.1021/jp050342x 109, 8767 (2005).
16. L. M. Wang, S. Shahriari, and R. Richert, J. Phys. Chem. B 1089-5647 10.1021/jp054542k 109, 23255 (2005).
17. H. Huth, L. M. Wang, C. Schick, and R. Richert, J. Chem. Phys. 0021-9606 10.1063/1.2539105 126, 104503 (2007).
18. L. M. Wang, Y. Tian, R. Liu, and R. Richert, J. Chem. Phys. 0021-9606 10.1063/1.2840357 128, 084503 (2008).
19. T. El Goresy and R. Böhmer, J. Chem. Phys. 0021-9606 10.1063/1.2903403 128, 154520 (2008).
20. T. Lyon and T. A. Litovitz, J. Appl. Phys. 0021-8979 10.1063/1.1722331 27, 179 (1956).
21. B. Jakobsen, K. Niss, and N. B. Olsen, J. Chem. Phys. 0021-9606 10.1063/1.2136887 123, 234511 (2005).
22. W. Dannhauser and R. H. Cole, J. Chem. Phys. 0021-9606 10.1063/1.1740576 23, 1762 (1955).
23. S. S. N. Murthy and S. K. Nayak, J. Chem. Phys. 0021-9606 10.1063/1.466187 99, 5362 (1993).
24. R. Wemelle, C. R. Hebd. Seances Acad. Sci. 244, 775 (1957).
25. A. Bondeau, G. Noyel, and J. Huck, C. R. Seances Acad. Sci., Ser. C 286, 273 (1978).
26. T. Christensen and N. B. Olsen, Rev. Sci. Instrum. 0034-6748 10.1063/1.1146126 66, 5019 (1995).
27. B. Igarashi, T. Christensen, E. H. Larsen, N. B. Olsen, I. H. Pedersen, T. Rasmussen, and J. C. Dyre, Rev. Sci. Instrum. 0034-6748 10.1063/1.2903419 79, 045105 (2008).
28. B. Igarashi, T. Christensen, E. H. Larsen, N. B. Olsen, I. H. Pedersen, T. Rasmussen, and J. C. Dyre, Rev. Sci. Instrum. 0034-6748 10.1063/1.2906401 79, 045106 (2008).
29. The full raw data sets [G () and () at the investigated temperatures] can be obtained from the "Glass and Time: Data repository," found online at http://glass.ruc.dk/data.
30. The problem with such approach is discussed in the context of the merging of the alpha and beta process in Ref..
31. K. Niss, B. Jakobsen, and N. B. Olsen, J. Chem. Phys. 0021-9606 10.1063/1.2136886 123, 234510 (2005).
32. N. Menon, S. R. Nagel, and D. C. Venerus, Phys. Rev. Lett. 0031-9007 10.1103/PhysRevLett.73.963 73, 963 (1994).
33. T. Christensen and N. B. Olsen, J. Non-Cryst. Solids 0022-3093 172-174, 357 (1994).
34. R. Zorn, F. I. Mopsik, G. B. McKenna, L. Willner, and D. Richter, J. Chem. Phys. 0021-9606 10.1063/1.474722 107, 3645 (1997).
35. R. D. Deegan, R. L. Leheny, N. Menon, S. R. Nagel, and D. C. Venerus, J. Phys. Chem. B 1089-5647 10.1021/jp983832g 103, 4066 (1999).
36. K. Schröter and E. Donth, J. Chem. Phys. 0021-9606 10.1063/1.1319616 113, 9101 (2000).
37. A loss-peak position of 10-2 Hz corresponds to a relaxation time of ≈10 s, a factor of 10 smaller than the often used 100 s. The choice of relaxation time at the glass-transition temperature is always somewhat arbitrary, and will of course influence the reported glass-transition temperatures. 10-2 Hz has the advantage that equilibrium points close to and even below Tg, and are easily accessible, leading to a more precise determination of Tg.
38. D. J. Plazek and K. L. Ngai, Macromolecules 0024-9297 10.1021/ma00005a044 24, 1222 (1991).
39. R. Böhmer and C. A. Angell, Phys. Rev. B 0163-1829 10.1103/PhysRevB.45.10091 45, 10091 (1992).
40. R. Böhmer, K. L. Ngai, C. A. Angell, and D. J. Plazek, J. Chem. Phys. 0021-9606 10.1063/1.466117 99, 4201 (1993).
41. O. E. Kalinovskaya and J. K. Vij, J. Chem. Phys. 0021-9606 10.1063/1.480909 112, 3262 (2000).
42. C. Maggi, B. Jakobsen, T. Christensen, N. B. Olsen, and J. C. Dyre, J. Phys. Chem. B (in press).
43. N. B. Olsen, T. Christensen, and J. C. Dyre, Phys. Rev. Lett. 0031-9007 10.1103/PhysRevLett.86.1271 86, 1271 (2001).
44. J. C. Dyre, Europhys. Lett. 0295-5075 10.1209/epl/i2005-10122-3 71, 646 (2005).
45. J. C. Dyre, Phys. Rev. E 1063-651X 10.1103/PhysRevE.74.021502 74, 021502 (2006).
46. J. C. Dyre, Phys. Rev. E 1063-651X 10.1103/PhysRevE.76.041508 76, 041508 (2007).
47. N. Saǧlanmak, K. Niss, A. I. Nielsen, J. C. Dyre, and N. B. Olsen (unpublished).