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Volumn 50, Issue 8, 2011, Pages 1841-1844

Switching through coordination-coupled proton transfer

Author keywords

E Z isomerization; hydrazones; metal coordination; proton transfer; rotary switches

Indexed keywords

BIOLOGICAL PROCESS; E/Z ISOMERIZATION; HYDRAZONES; METAL COORDINATION; PHOTOSYNTHETIC BACTERIAS; REACTION CENTER; ROTARY SWITCHES; ZINC COMPLEX;

EID: 79951803604     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201006982     Document Type: Article
Times cited : (82)

References (40)
  • 13
    • 0004240038 scopus 로고    scopus 로고
    • (Ed.: B.L. Feringa), Wiley-VCH, Weinheim
    • Molecular Switches (Ed.:, B.L. Feringa,), Wiley-VCH, Weinheim, 2001
    • (2001) Molecular Switches
  • 21
    • 79951795911 scopus 로고    scopus 로고
    • For examples of electro- and photochemically induced pH modulations, see
    • For examples of electro- and photochemically induced pH modulations, see
  • 32
    • 79951778874 scopus 로고    scopus 로고
    • 2+, see FigureS10
    • 2+, see FigureS10.
  • 33
    • 79951803641 scopus 로고    scopus 로고
    • avalue of this system
    • avalue of this system.
  • 34
    • 79951775944 scopus 로고    scopus 로고
    • note
    • 2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
  • 35
    • 79951776826 scopus 로고    scopus 로고
    • In the crystal structure of Zn(QPH-Z), the dihedral angle between the pyridyl ring and the quinolinyl ring is 12.740(63)°, and the torsion angles of N-N-C-C (pyridyl) and C-N-N-C (quinolinyl) are 178.801(232) and 178.875(235)°, respectively
    • In the crystal structure of Zn(QPH-Z), the dihedral angle between the pyridyl ring and the quinolinyl ring is 12.740(63)°, and the torsion angles of N-N-C-C (pyridyl) and C-N-N-C (quinolinyl) are 178.801(232) and 178.875(235)°, respectively.
  • 36
    • 79951780439 scopus 로고    scopus 로고
    • note
    • 2) value was 0.2125 (all data).
  • 37
    • 79951788279 scopus 로고    scopus 로고
    • Hydrogen atom H7 of one ligand is oriented perpendicularly to the deprotonated hydrazone functional group of the other; hence, it is shielded
    • Hydrogen atom H7 of one ligand is oriented perpendicularly to the deprotonated hydrazone functional group of the other; hence, it is shielded.
  • 38
    • 79951791688 scopus 로고    scopus 로고
    • 2+. We see no evidence of this coordination, thus further supporting the intramolecular pathway. This said, we cannot absolutely rule out intermolecular proton transfer
    • 2+. We see no evidence of this coordination, thus further supporting the intramolecular pathway. This said, we cannot absolutely rule out intermolecular proton transfer.
  • 40


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.