Terpolymerization of linear and alicyclic α-olefins with norbornene and ethylene by ansa-metallocene catalysts

Macromolecules

Volumn 44, Issue 4, 2011, Pages 795-804

  Marconi, Roberto ^a,b   Boggioni, Laura ^a   Ravasio, Andrea ^a   Di Colo, Francesco ^a   Tritto, Incoronata ^a   Stehling, Udo M ^c  

^a CNR   (Italy)

^b UNIVERSITY OF PAVIA   (Italy)

^c Topas Advanced Polymers GmbH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

1-OCTENE; ACTIVE CATALYST; ANSA-METALLOCENE; ANSA-METALLOCENE CATALYST; CHAIN TERMINATIONS; END GROUPS; END-GROUP ANALYSIS; H NMR SPECTRA; HIGH YIELD; HIGH-T; HIGHER T; METALLOCENE CATALYST; NORBORNENES; THERMAL PROPERTIES; VINYLCYCLOHEXANE;

ETHYLENE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; TERPOLYMERIZATION; TERPOLYMERS; THERMODYNAMIC PROPERTIES; ZIRCONIUM;

CATALYSTS;

EID: 79951598796     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma102515c     Document Type: Article

References (52)

1. Kaminsky, W.; Noll, A. Polym. Bull. 1993, 31, 175-182
2. Kaminsky, W. Macromol. Chem. Phys. 1996, 197, 3907-3945
3. Kaminsky, W.; Bark, A.; Steiger, R. J. Mol. Catal. 1992, 72, 109-119
4. Kaminsky, W.; Bark, A.; Arndt, M. Makromol. Chem., Macromol. Symp. 1991, 47, 83-93
5. Arndt, M.; Kaminsky, W. Macromol. Symp. 1995, 97, 225-246
6. Arndt, M.; Engehausen, R.; Kaminsky, W.; Zoumis, K. J. Mol. Catal A: Chem. 1995, 101, 171-178
7. Kaminsky, W.; Arndt-Rosenau, M. in Metallocene-based Polyolefins; Scheirs, J.; Kaminsky, W., Eds.; Wiley: Chichester, U.K., 2000; p 89 and references therein.
8. Ruchatz, D.; Fink, G. Macromolecules 1998, 31, 4674-4680
9. Herfert, N.; Montag, P.; Fink, G. Makromol. Chem. 2001, 94, 3167-3182
10. Arndt-Rosenau, M.; Beulich, I. Macromolecules 1999, 32, 7335-7343
11. Arndt, M.; Beulich, I. Macromol. Chem. Phys. 1998, 199, 1221-1232
12. Tritto, I.; Boggioni, L.; Sacchi, M. C.; Locatelli, P. J. Mol. Catal. A: Chem. 1998, 133, 139-150
13. Provasoli, A.; Ferro, D. R.; Tritto, I.; Boggioni, L. Macromolecules 1999, 32, 6697-6706
14. Tritto, I.; Marestin, C.; Boggioni, L.; Zetta, L.; Provasoli, A.; Ferro, D. R. Macromolecules 2000, 33, 8931-8944
15. Tritto, I.; Marestin, C.; Boggioni, L.; Brintzinger, H. H.; Ferro, D. R. Macromolecules 2001, 34, 5770-5777
16. Thorshaug, K.; Mendichi, R.; Tritto, I.; Trinkle, S.; Friedrich, C.; Mülhaupt, R. Macromolecules 2002, 35, 2903-2911
17. Tritto, I.; Boggioni, L.; Ferro, D. R. Macromolecules 2004, 37, 9681-9693
18. Recent reviews: Tritto, I.; Boggioni, L.; Ferro, D. R. Coord. Chem. Rev. 2006, 250, 212-241
19. Li, X.; Hou, Z. M. Coord. Chem. Rev. 2008, 252, 1842-1869
20. Recent progress: Li, X.; Baldamus, J.; Hou, Z. Angew. Chem., Int. Ed. 2005, 44, 962-965
21. Ravasio, A.; Zampa, C.; Boggioni, L.; Tritto, I.; Hitzbleck, J.; Okuda, J. Macromolecules 2008, 41, 9565-9569
22. Marconi, R.; Ravasio, A.; Boggioni, L.; Tritto, I. Macromol. Rapid Commun. 2009, 30, 39-44
23. Terao, H.; Iwashita, A.; Ishii, S.; Tanaka, H.; Yoshida, Y.; Mitani, M.; Fujita, T. Macromolecules 2009, 42, 4359-4361
24. He, L. P.; Liu, J. L.; Li, Y. G.; Liu, S. R.; Li, Y. S. Macromolecules 2009, 42, 8566-8570
25. Yang, X. H.; Wang, Z.; Sun, X. L.; Tang, Y. Dalton Trans. 2009, 8945-8954
26. Wang, B.; Tang, T.; Li, Y.; Cui, D. Dalton Trans. 2009, 8963-8969
27. Lin, Y. C.; Yu, K. H.; Huang, S. L.; Liu, Y. H.; Wang, Y.; Liu, S. T.; Chen, J. T. Dalton Trans 2009, 9058-9067
28. Ravasio, A.; Boggioni, L.; Tritto, I.; DArrigo, C.; Perico, A.; Hitzbleck, J.; Okuda, J. J. Polym. Science Part A: Polym. Chem. 2009, 47, 5709-5719
29. Tritto, I.; Ravasio, A.; Boggioni, L.; Bertini, F.; Hitzbleck, J.; Okuda, J. Macromol. Chem. Phys. 2010, 211, 897-904
30. See http//www.topas.com and Brekner, M.-J.; Osan, F.; Rohrmann, J.; Antberg, M. Process for the preparation of chemically homogeneous cycloolefin copolymers. U.S. Patent 5,324,801, 1994.
31. Kaminsky, W.; Hoff, M.; Derlin, S. Macromol. Chem. Phys. 2007, 208, 1341-1348
32. Ban, H.-T.; Nishii, N.; Tsunogae, Y.; Shiono, T. J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 2765-2773
33. Liu, S.; Yao, Z.; Cao, K.; Li, B.; Zhu, S. Macromol. Rapid Commun. 2009, 30, 548-553
34. Lasarov, H.; Pakkanen, T. T. Macromol. Rapid Commun. 2001, 22, 434
35. Wendt, R. A.; Fink, G. Macromol. Chem. Phys. 2000, 201, 1365
36. Sernetz, F. G.; Mülhaupt, R. J. Polym. Sci., Part A: Polym. Chem. 1997, 35, 2549-2560
37. See for example: Herrmann, W. A.; Rohrmann, J.; Herdtweck, E.; Spaleck, W.; Winter, A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1511-1512
38. Razavi, A.; Atwood, J. L. J. Organomet. Chem. 1993, 459, 117-123
39. Cho, E. S.; Joung, U. G.; Lee, B. Y.; Lee, H.; Park, Y-W.; Lee, C. H.; Shin, D. M. Organometallics 2004, 23, 4693-4699
40. Tritto, I.; Boggioni, L.; Jansen, J. C.; Thorshaug, K.; Sacchi, M. C.; Ferro, D. R. Macromolecules 2002, 35, 616-623
41. Qiu, X-H.; Redwine, D.; Gobbi, G.; Nuamthanom, A.; Rinaldi, P. L. Macromolecules 2007, 40, 6879-6884
42. Liu, W.; Rinaldi, P. L.; McIntosh, L. H.; Quirk, R. P. Macromolecules 2001, 34, 4757-4767
43. Nomura, K.; Itagaki, K. Macromolecules 2005, 38, 8121-8123
44. Yano, A.; Hasegawa, S.; Kaneko, T.; Sone, M.; Sato, M.; Akimoto, A. Macromol. Chem. Phys. 1999, 200, 1542-1553
45. Chirik, P. J.; Bercaw, J. E. Organometallics 2005, 24, 5407-5423
46. Joung, U. G.; Lee, B. Y. Polyhedron 2005, 24, 1256-1261
47. Hong, H.; Zhang, Z.; Chung, T. C. M.; Lee, R. W. J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 639-649
48. Aitola, E.; Hakala, K.; Byman-Fagerholm, H.; Leskela, M.; Repo, T. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 373-382
49. Aitola, E.; Puranen, A.; Setala, H.; Lipponen, S.; Leskela, M.; Repo, T. J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 6569-6574
50. Busico, V.; Cipullo, R.; Friederichs, N.; Linssen, H.; Segre, A.; Castelli, V. V. A.; van der Velden, G. Macromolecules 2005, 38, 6988-6996
51. Ni Bhriain, N.; Brintzinger, H. H.; Ruchatz, D.; Fink, G. Macromolecules 2005, 38, 2056-2063
52. Forsyth, J.; Perena, J. M.; Benavente, R.; Perez, E.; Tritto, I.; Boggioni, L.; Brintzinger, H. H. Macromol. Chem. Phys. 2001, 202, 614-620