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Volumn 42, Issue 13, 2009, Pages 4359-4361

Ethylene/norbornene copolymerization behavior of bis(phenoxy-imine)ti complexes combined with MAO

Author keywords

[No Author keywords available]

Indexed keywords

ALTERNATING COPOLYMER; C ATOMS; CATIONIC SPECIES; FI CATALYST; HIGH ACTIVITY; MONODISPERSE; NORBORENE; PHENOXY-IMINE; TI COMPLEXES;

EID: 67650364008     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma900890b     Document Type: Article
Times cited : (48)

References (61)
  • 46
    • 41849116745 scopus 로고    scopus 로고
    • For recent research on FI catalysts and related complexes, see a
    • For recent research on FI catalysts and related complexes, see (a) Edson, J. B.; Wang, Z.; Kramer, E. J.; Coates, G. W. J. Am. Chem. Soc. 2008, 130, 4968.
    • (2008) J. Am. Chem. Soc , vol.130 , pp. 4968
    • Edson, J.B.1    Wang, Z.2    Kramer, E.J.3    Coates, G.W.4
  • 56
    • 67650420826 scopus 로고    scopus 로고
    • Moody, S. L.; Mackenzie, B. P.; Killian, M. C.; Lavoie, G. G.; Ponasik, A. J.; Barrett, M. G. A;. Smith, W. T.; Pearson, C. J. WO Patent 00/50470, 2000.
    • Moody, S. L.; Mackenzie, B. P.; Killian, M. C.; Lavoie, G. G.; Ponasik, A. J.; Barrett, M. G. A;. Smith, W. T.; Pearson, C. J. WO Patent 00/50470, 2000.
  • 57
    • 67650437641 scopus 로고    scopus 로고
    • The amount of the charged complex and polymerization time were controlled in order to make the NB conversion smaller than 10% under homogeneous polymerization conditions
    • The amount of the charged complex and polymerization time were controlled in order to make the NB conversion smaller than 10% under homogeneous polymerization conditions.
  • 58
    • 1942535749 scopus 로고    scopus 로고
    • It should be pointed out that NB insertion, leading to a secondary growing polymer chain, might give rise to a fluxional isomerization between the diastereomeric A and A configurations, which can influence the stereoselectivity of the polymerization, see: (a) Corradini, P, Guerra, G, Cavallo, L. Acc. Chem. Res. 2004, 37, 231
    • It should be pointed out that NB insertion, leading to a secondary growing polymer chain, might give rise to a fluxional isomerization between the diastereomeric A and A configurations, which can influence the stereoselectivity of the polymerization, see: (a) Corradini, P.; Guerra, G.; Cavallo, L. Acc. Chem. Res. 2004, 37, 231.
  • 60
    • 67650431492 scopus 로고    scopus 로고
    • See ref 9b
    • (c) See ref 9b.
  • 61
    • 0038538249 scopus 로고    scopus 로고
    • After our report (ref 10c), a non-fluorinated phenoxy-ketiminetype Ti-FI catalyst was also reported to possess characteristics of living ethylene polymerization; see: Reinartz, S.; Mason, A. F.; Lobkovsky, E. B.; Coates, G. W. Organometallics 2003, 22, 2542.
    • After our report (ref 10c), a non-fluorinated phenoxy-ketiminetype Ti-FI catalyst was also reported to possess characteristics of living ethylene polymerization; see: Reinartz, S.; Mason, A. F.; Lobkovsky, E. B.; Coates, G. W. Organometallics 2003, 22, 2542.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.