Hydride-shuttling chain-transfer polymerization of methacrylates catalyzed by metallocenium enolate metallacycle-hydridoborate ion pairs

Journal of the American Chemical Society

Volumn 133, Issue 5, 2011, Pages 1572-1588

  Zhang, Yuetao ^a   Caporaso, Lucia ^b   Cavallo, Luigi ^b   Chen, Eugene Y X ^a  

^a Veterinary Dentistry and Oral Surgery   (United States)

^b UNIVERSITY OF SALERNO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; ACTIVATION STEPS; ACTIVE SPECIES; CATALYTIC POLYMERIZATION; CHAIN TRANSFER POLYMERIZATION; CHAIN-TRANSFER MECHANISMS; CHAIN-TRANSFER REACTIONS; COMPUTATIONAL RESULTS; ENOLATES; FIRST ORDER KINETICS; HYDRIDE ABSTRACTION; HYDRIDE ADDITIONS; INTRAMOLECULAR COORDINATION; ION PAIRS; LIGAND SYMMETRY; METALLACYCLES; METALLOCENES; METHYL METHACRYLATES; MMA POLYMERIZATION; NEW HYDRIDES; NUCLEOPHILIC ADDITIONS; POLYMER CHAINS; RESTING STATE; ROOM TEMPERATURE; SOLVENT POLARITY; STEREOSPECIFICITY; STRUCTURAL MODELS; SUBSTITUTION PATTERNS; TERMINAL DOUBLE BONDS; THEORETICAL STUDY; TWO-STEP REACTIONS; WEAKLY COORDINATING ANIONS;

ABSTRACTING; ADDITION REACTIONS; CATALYSTS; CHELATION; CHEMICAL ACTIVATION; CRYSTAL ATOMIC STRUCTURE; ESTERIFICATION; ESTERS; HAFNIUM; LIGANDS; MODEL STRUCTURES; NEGATIVE IONS; ORGANIC POLYMERS; ORGANOMETALLICS; POLYMERIZATION; POLYMERS; POSITIVE IONS; SOLVENTS; STRUCTURAL METALS; TEMPERATURE; THERMODYNAMICS; TITANIUM COMPOUNDS; TOLUENE; ZIRCONIUM; ZIRCONIUM COMPOUNDS;

ACRYLIC MONOMERS;

ANION; BIS(ESTER ENOLATE); BORANE DERIVATIVE; CARBOXYL GROUP; CATION; ENOLATE METALLACYCLE; HYDRIDE; HYDRIDOBORATE; HYDROGEN; LIGAND; METAL COMPLEX; METAL DERIVATIVE; METALLACYCLE; METHACRYLIC ACID; METHACRYLIC ACID DERIVATIVE; METHACRYLIC ACID METHYL ESTER; NUCLEOPHILE; POLYMER; SOLVENT; TITANIUM; TOLUENE; UNCLASSIFIED DRUG; ZIRCONIUM;

ARTICLE; ATOM; CATALYSIS; CATALYST; CHELATION; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; COMPUTATIONAL FLUID DYNAMICS; CONTROLLED STUDY; CROSS LINKING; CYCLOADDITION; HYDRIDE SHUTTLING CHAIN TRANSFER POLYMERIZATION; ION TRANSPORT; KINETICS; LIGAND BINDING; NUCLEOPHILICITY; POLYMERIZATION; RING OPENING; ROOM TEMPERATURE; STEREOCHEMISTRY; STEREOSPECIFICITY; SUBSTITUTION REACTION; THERMODYNAMICS;

EID: 79551700422     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja109775v     Document Type: Article

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