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Volumn 24, Issue 10, 2005, Pages 2466-2472

Model studies of methacrylate chain transfer polymerization mediated by cationic zirconocene tert-butyl enolate

Author keywords

[No Author keywords available]

Indexed keywords

ACETOPHENONE; ISOBUTENE; STOICHIOMETRIC REACTIVITY; THIOPHENOLS;

EID: 18844440939     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050119m     Document Type: Article
Times cited : (24)

References (47)
  • 31
    • 18844378055 scopus 로고    scopus 로고
    • note
    • 8 established that no THF molecule coordinates the metal center in those species.
  • 33
    • 18844438548 scopus 로고    scopus 로고
    • note
    • +".
  • 34
    • 18844452597 scopus 로고    scopus 로고
    • note
    • 2 established the coordination of one THF molecule in both complexes (see Experimental Section).
  • 36
    • 18844371436 scopus 로고    scopus 로고
    • note
    • 8 with 1 or 2 equiv of tBuSH were found to proceed more slowly with the same selectivity.
  • 37
    • 18844409371 scopus 로고    scopus 로고
    • note
    • 2 is consistent with a decomposition pathway involving a "base-free" cationic Zr species, as proposed in Scheme 3; see refs 4n and 12.
  • 40
    • 18844418420 scopus 로고    scopus 로고
    • note
    • + is much more likely in a weakly coordinating solvent such as toluene.
  • 41
    • 18844451178 scopus 로고    scopus 로고
    • note
    • 4]: <1% yield (all other conditions as stated in Table 4). We thank a reviewer for suggesting these experiments.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.