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78651336131
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2O as the solvent. Use of strong bases such as NaOH led to quantitative deprotection of the TBS groups
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2O as the solvent. Use of strong bases such as NaOH led to quantitative deprotection of the TBS groups.
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44
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78651323338
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2 and 6 mol%4,4'-di-tert-butyl-2,2'-bipyridine (dtbpy) needed to be added in two portions. See Supporting Information for details
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2 and 6 mol%4,4'-di-tert-butyl-2,2'-bipyridine (dtbpy) needed to be added in two portions. See Supporting Information for details.
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45
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78651331100
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Hydrolysis of the boronate ester was observed in this process that resulted in decreased yield. All the pinacol boronate esters, i.e., 2, 4, 5, and 6, are sufficiently stable to the silica gel flash chromatography conditions that we used, although small amounts of decomposition may occur if a prolonged column chromatography process was applied
-
Hydrolysis of the boronate ester was observed in this process that resulted in decreased yield. All the pinacol boronate esters, i.e., 2, 4, 5, and 6, are sufficiently stable to the silica gel flash chromatography conditions that we used, although small amounts of decomposition may occur if a prolonged column chromatography process was applied.
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58
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78651273336
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n value (16 kDa) corresponds to a DP of 32, despite that the molecular weight of hyperbranched polymers is often underestimated by simply comparing to polystyrene standards in GPC analysis
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n value (16 kDa) corresponds to a DP of 32, despite that the molecular weight of hyperbranched polymers is often underestimated by simply comparing to polystyrene standards in GPC analysis.
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61
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78651292034
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The concentration with respect to the pyrene unit was calculated based on a 100% pyrenyl end-capped HB-PmP with a DP of 50
-
The concentration with respect to the pyrene unit was calculated based on a 100% pyrenyl end-capped HB-PmP with a DP of 50.
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