Rapid synthesis of hyperbranched aromatic polyetherimides

Macromolecules

Volumn 32, Issue 15, 1999, Pages 4764-4768

  Thompson, D Scott ^a   Markoski, Larry J ^a   Moore, Jeffrey S ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; GEL PERMEATION CHROMATOGRAPHY; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY;

CATALYTIC ARYLATION METHOD; HYPERBRANCHED POLYETHERIMIDE;

POLYETHERIMIDES;

EID: 0033154127     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma982008n     Document Type: Article

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70. -6]= 0.696 The DB value calculated from NMR integrations is within 0.01% of that calculated using the known molar amounts.
71. The degree of branching was calculated several ways using combinations of the integration values shown in Figure 1e. All values calculated fall between 65.4% and 67.5%.
72. A positive error of 2% in the integration of the methyl group protons would result in a change of extent of reaction to 96% and a change in molecular weight to 9.3 kDa. As the extent of reaction approaches 98% and higher, the error in molecular weights becomes exponentially larger (see Table 2).
73. (a) The corressponding linear AB polymer derived from polymerization of 3-tert-butyldimethylsilyloxyphenyl-4-fluorophthalimide has a 10% weight loss of 582 °C. (b) The highest thermal stabilties reported in the hyperbranched polymer literature are listed in Table 3.