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Volumn , Issue 3, 2011, Pages 538-546

Asymmetric synthesis and in vivo biological inactivity of the right-hand terpenoid fragment of terpendole e

Author keywords

Cyclization; Inhibitors; Metathesis; Natural products; Radical reactions; Reduction; Terpenoids

Indexed keywords


EID: 78651266068     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.201001104     Document Type: Article
Times cited : (14)

References (55)
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    • For leading references, see
    • For leading references, see
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    • note
    • 2-Mn-TMSCl- collidine system are so far not clear. One possibility is the low quality of Mn metal we used (powder form, Kanto chemical Co., Catalog No. 25051-32, Lot No. 705W2102), although no report has yet pointed out about this issue. In these experiments, we used commercial Mn and Zn metals directly.
  • 39
    • 78651333149 scopus 로고    scopus 로고
    • We had also realized several examples for unfavored I-addition of prenylmetal to sterically hindered neopentylic aldehydes, see
    • We had also realized several examples for unfavored I-addition of prenylmetal to sterically hindered neopentylic aldehydes, see
  • 47
    • 0035902255 scopus 로고    scopus 로고
    • The 4-acetoxybutenyl group is reported to undergo smooth cross-metathesis, see.
    • The 4-acetoxybutenyl group is reported to undergo smooth cross-metathesis, see;, S. BouzBouz, J. Cossy, Org. Lett. 2001, 3, 1451-1454.
    • (2001) Org. Lett. , vol.3 , pp. 1451-1454
    • Bouzbouz, S.1    Cossy, J.2
  • 52
    • 70349850330 scopus 로고    scopus 로고
    • Although rather tedious functional group transformations are required, the asymmetric dihydroxlyation of 22 followed by dehydration of the diol could also afford the epoxide 24 with better diastereoselectivity. For recent examples, see.
    • Although rather tedious functional group transformations are required, the asymmetric dihydroxlyation of 22 followed by dehydration of the diol could also afford the epoxide 24 with better diastereoselectivity. For recent examples, see;, Y. Zhang, J. R. Cusick, P. Ghosh, N. Shangguan, S. Katukojvala, J. Inghrim, T. J. Emge, L. J. Williams, J. Org. Chem. 2009, 74, 7707-7714.
    • (2009) J. Org. Chem. , vol.74 , pp. 7707-7714
    • Zhang, Y.1    Cusick, J.R.2    Ghosh, P.3    Shangguan, N.4    Katukojvala, S.5    Inghrim, J.6    Emge, T.J.7    Williams, L.J.8
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    • Parikh, J.R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.