Kinetics of the gas-phase homogeneous unimolecular elimination of selected ethyl esters of 2-oxo-carboxylic acids

Journal of Physical Organic Chemistry

Volumn 24, Issue 1, 2011, Pages 74-82

  Reyes, Andreina ^a   Domínguez, Rosa M ^a   Tosta, Maria ^a   Herize, Armando ^a   Chuchani, Gabriel ^a  

^a INSTITUTO VENEZOLANO DE INVESTIGACIONES CIENTÍFICAS   (Venezuela)

Author keywords

Ethyl benzoyl formate; Ethyl oxalyl chloride; Ethyl piperidineglyoxylate; Gas phase elimination; Kinetics; Mechanism

Indexed keywords

ARRHENIUS EQUATION; ETHYL BENZOYL FORMATE; ETHYL ESTERS; ETHYL PIPERIDINEGLYOXYLATE; FIRST-ORDER RATES; GAS-PHASE ELIMINATION; GASPHASE; KINETIC AND THERMODYNAMIC PARAMETERS; MECHANISTIC PATHWAYS; OXALYL CHLORIDE; RATE COEFFICIENTS; STATIC REACTIONS; TEMPERATURE RANGE; UNIMOLECULAR; UNIMOLECULAR ELIMINATION;

CARBOXYLIC ACIDS; CHLORINE COMPOUNDS; ESTERIFICATION; FREE RADICALS; TOLUENE;

ESTERS;

EID: 78650917586     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1705     Document Type: Article

References (19)

1. R. Taylor, in The Chemistry of Functional Group. Supplementary Volume B, Acid Derivatives, Chapter 15 (Ed.:, S. Patai,), Wiley, London, 1979, pp. 859-914.
2. K. A. Holbrook, The Chemistry of Acid Derivatives. Volume 2. Vapor and Gas Phase Reaction of Carboxylic Acids and their Derivatives, Chapter 12 (Ed.:, S. Patai,) Wiley, London, 1992, pp. 703-746.
3. A. Herize, R. M. Dominguez, A. Rotinov, O. Nuñez, G. Chuchani, J. Phys. Org. Chem. 1999, 12, 201-206.
4. C. Hansch, A. Leo, R. Taft, Chem. Rev. 1991, 91, 165-195.
5. A. Reyes, R. M. Dominguez, M. Tosta, A. Herize, G. Chuchani, Int. J. Chem. Kinet. 2007, 39, 268-275.
6. L. Clark, J. Phys. Chem. 1961, 65, 659-661.
7. L. Clark, J. Phys. Chem. 1961, 65, 180-182.
8. L. Clark, J. Phys. Chem. 1961, 65, 1651-1652.
9. G. Lapidus, D. Barton, P. Yankwich, J. Phys. Chem. 1964, 68, 1863.
10. R. Taylor, Int. J. Chem. Kinet. 1987, 19, 709-7713.
11. R. Taylor, Int. J. Chem. Kinet. 1991, 23, 247-250.
12. T. Cordova, A. Rotinov, G. Chuchani, J. Phys. Org. Chem. 2004, 17, 148-151.
13. E. V. Chacin, M. Tosta, A. Herize, R. M. Dominguez, Y. Alvarado, G. Chuchani, J. Phys. Org. Chem. 2005, 18, 539-545.
14. R. Taylor, Int. J. Chem. Kinet. 1987, 19, 709-713.
15. C. Hansch, A. J. Leo, Substituent Constants for Correlation Analysis in Chemistry and Biology, Wiley, USA, 1979.
16. A. Maccoll, J. Chem. Soc. 1955, 965-973.
17. E. S. Swinbourne, Aust. J. Chem. 1958, 11, 314-330.
18. R. M. Dominguez, A. Herize, A. Rotinov, A. Alvarez-Aular, G. Visbal, G. Chuchani, J. Phys. Org. Chem. 2004, 17, 399-408.
19. F. Rosas, A. Monsalbe, M. Tosta, A. Herize, R. M. Dominguez, D. Brusco, G. Chuchani, Int. J. Chem. Kinet 2005, 37, 383-389.