Homogeneous, unimolecular gas-phase elimination kinetics of ethyl esters of glyoxylic, 2-oxo-propanoic, and 3-methyl-2-oxo-butanoic acids

International Journal of Chemical Kinetics

Volumn 39, Issue 5, 2007, Pages 268-275

  Reyes, Andreina ^a   Dominguez, Rosa M ^a   Tosta, Maria ^a   Herize, Armando ^a   Chuchani, Gabriel ^a  

^a INSTITUTO VENEZOLANO DE INVESTIGACIONES CIENTÍFICAS   (Venezuela)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLIC ACIDS; ESTERS; PRESSURE EFFECTS;

ARRHENIUS EQUATION; ETHYL ESTERS; RATE COEFFICIENTS; TRANSITION STATES;

REACTION KINETICS;

EID: 34247270287     PISSN: 05388066     EISSN: 10974601     Source Type: Journal    
DOI: 10.1002/kin.20240     Document Type: Article

References (21)

1. Taylor, R. The Chemistry of Functional Group, Supplementary Volume B: Acid Derivatives; Patai, S. (Ed.); Wiley: London, 1979; Ch. 15, pp. 859-914.
2. Holbrook, K. A. The Chemistry of Acid Derivatives, Volume 2: Vapor and Gas phase Reaction of Carboxylic Acids and Their Derivatives; Patai, S. (Ed.); Wiley; London, 1992; Ch. 12, pp. 703-746.
3. Chuchani, G.; Mishima, M.; Notario, R.; Aboud, J. L. Structural Effects on Gas-Phase Reactivities, Volume 2: Advances in Quantitative Structure-Property Relationships; Charton, M.; Charton, B. I. (Eds.); Jai Press: Stamford, CT; 1999, pp. 35-126.
4. (a) Hansch, C.; Leo, A. J. Substituent Constants for Correlation Analysis in Chemistry and Biology; Wiley: New York, 1979;
5. (b) Hansch, C.; Leo, A.; Taft, R. Chem Rev 1991, 91, 165-195.
6. Herize, A.; Domínguez, R. M.; Rotinov, A.; Nuñez, O.; Chuchani, G. J Phys Org Chem 1999, 12, 201-206.
7. Clark, L. J Phys Chem 1961, 65, 659-661.
8. Clark, L. J Phys Chem 1961, 65, 180-182.
9. Clark, L. J Phys Chem 1961, 65, 1651-1652.
10. Lapidus, G.; Barton, D.; Yankwich, P. J Phys Chem 1964, 68, 1863.
11. Taylor, R. Int J Chem Kinet 1987, 19, 709-713.
12. Taylor, R. Int J Chem Kinet 1991, 23, 247-250.
13. Cordova, T.; Rotinov, A.; Chuchani, G. J Phys Org Chem 2004, 17, 148-151.
14. Chacin, E. V.; Tosta, M.; Herize, A.; Dominguez, R. M.; Alvarado, Y.; Chuchani, G. J Phys Org Chem 2005, 18, 539-545.
15. Maccoll, A. J Chem Soc 1955, 965-973.
16. Swinbourne, E. S. Aust J Chem 1958, 11, 314-330.
17. Dominguez, R. M.; Herize, A.; Rotinov, A.; Alvarez-Aular, A.; Visbal, G.; Chuchani, G. J Phys Org Chem 2004, 17, 399-408.
18. Makens, R. F.; Eversole, W. G. J Am Chem Soc 1939, 61, 3203-3206.
19. Taylor, R. Int J Chem Kinet 1987, 19, 709-713.
20. (a) Hansch, C.; Leo, A. J. Substituent Constants for Correlation Analysis in Chemistry and Biology; Wiley: New York, 1979;
21. (b) Hansch, C.; Leo, A.; Taft, R. Chem Rev 1991, 91, 165-195.