Experimental and theoretical study of the homogeneous, unimolecular gas-phase elimination kinetics of methyl oxalyl chloride

Journal of Physical Organic Chemistry

Volumn 17, Issue 2, 2004, Pages 148-151

  Cordova, Tania ^a   Rotinov, Alexandra ^b   Chuchani, Gabriel ^b  

^a FACULTAD DE CIENCIAS   (Venezuela)

^b INSTITUTO VENEZOLANO DE INVESTIGACIONES CIENTÍFICAS   (Venezuela)

Author keywords

Kinetics; Methyl oxalyl chloride; Pyrolysis; Reaction mechanism; Semi empirical and ab initio calculations; Transition state structure; Unimolecular elimination

Indexed keywords

BROMINE COMPOUNDS; CARBON MONOXIDE; CHEMICAL BONDS; CHLORINE COMPOUNDS; FREE RADICALS; NUMERICAL METHODS; OLEFINS; POLARIZATION; PRESSURE; PYROLYSIS; TEMPERATURE; THERMODYNAMIC PROPERTIES;

ALLYL BROMIDE; ARRHENIUS EQUATION; CYCLOHEXENE; METHYL CHLOROFORMATE; METHYL OXALYL CHLORIDE; RATE COEFFICIENTS; UNIMOLECULAR GAS PHASE ELIMINATION;

REACTION KINETICS;

EID: 0442296536     PISSN: 08943230     EISSN: None     Source Type: Journal    
DOI: 10.1002/poc.705     Document Type: Article

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